Sharp size-selective catalysis in a liquid solution over Pd nanoparticles encapsulated in hollow silicalite-1 zeolite crystals

© 2016 The Royal Society of Chemistry. A lab-in-a-shell method was designed to prepare Pd nanoparticles encapsulated in hollow silicalite-1 zeolite crystals for size-selective catalysis in liquid solution. Due to the pore size limitation of the microporous silicalite-1 shell (0.53 × 0.56 nm), the ca...

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Main Authors: Wei, F., Liu, Jian, Zhang, Q., Zhang, Y., Zhang, X., Cao, C., Song, W.
Format: Journal Article
Published: Royal Society of Chemistry 2016
Online Access:http://hdl.handle.net/20.500.11937/72279
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author Wei, F.
Liu, Jian
Zhang, Q.
Zhang, Y.
Zhang, X.
Cao, C.
Song, W.
author_facet Wei, F.
Liu, Jian
Zhang, Q.
Zhang, Y.
Zhang, X.
Cao, C.
Song, W.
author_sort Wei, F.
building Curtin Institutional Repository
collection Online Access
description © 2016 The Royal Society of Chemistry. A lab-in-a-shell method was designed to prepare Pd nanoparticles encapsulated in hollow silicalite-1 zeolite crystals for size-selective catalysis in liquid solution. Due to the pore size limitation of the microporous silicalite-1 shell (0.53 × 0.56 nm), the catalyst showed high activity in the hydrogenation of 3-methyl-2-butenal (0.38 × 0.62 nm) and cinnamaldehyde (0.54 × 0.92 nm), but no activity for 3,3-diphenylacrylaldehyde (0.81 × 1.0 nm).
first_indexed 2025-11-14T10:51:51Z
format Journal Article
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institution Curtin University Malaysia
institution_category Local University
last_indexed 2025-11-14T10:51:51Z
publishDate 2016
publisher Royal Society of Chemistry
recordtype eprints
repository_type Digital Repository
spelling curtin-20.500.11937-722792018-12-13T09:33:38Z Sharp size-selective catalysis in a liquid solution over Pd nanoparticles encapsulated in hollow silicalite-1 zeolite crystals Wei, F. Liu, Jian Zhang, Q. Zhang, Y. Zhang, X. Cao, C. Song, W. © 2016 The Royal Society of Chemistry. A lab-in-a-shell method was designed to prepare Pd nanoparticles encapsulated in hollow silicalite-1 zeolite crystals for size-selective catalysis in liquid solution. Due to the pore size limitation of the microporous silicalite-1 shell (0.53 × 0.56 nm), the catalyst showed high activity in the hydrogenation of 3-methyl-2-butenal (0.38 × 0.62 nm) and cinnamaldehyde (0.54 × 0.92 nm), but no activity for 3,3-diphenylacrylaldehyde (0.81 × 1.0 nm). 2016 Journal Article http://hdl.handle.net/20.500.11937/72279 10.1039/c6ra20789h Royal Society of Chemistry restricted
spellingShingle Wei, F.
Liu, Jian
Zhang, Q.
Zhang, Y.
Zhang, X.
Cao, C.
Song, W.
Sharp size-selective catalysis in a liquid solution over Pd nanoparticles encapsulated in hollow silicalite-1 zeolite crystals
title Sharp size-selective catalysis in a liquid solution over Pd nanoparticles encapsulated in hollow silicalite-1 zeolite crystals
title_full Sharp size-selective catalysis in a liquid solution over Pd nanoparticles encapsulated in hollow silicalite-1 zeolite crystals
title_fullStr Sharp size-selective catalysis in a liquid solution over Pd nanoparticles encapsulated in hollow silicalite-1 zeolite crystals
title_full_unstemmed Sharp size-selective catalysis in a liquid solution over Pd nanoparticles encapsulated in hollow silicalite-1 zeolite crystals
title_short Sharp size-selective catalysis in a liquid solution over Pd nanoparticles encapsulated in hollow silicalite-1 zeolite crystals
title_sort sharp size-selective catalysis in a liquid solution over pd nanoparticles encapsulated in hollow silicalite-1 zeolite crystals
url http://hdl.handle.net/20.500.11937/72279