Synthesis of ZSM-5 monoliths with hierarchical porosity through a steam-assisted crystallization method using sponges as scaffolds

© 2017, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved. Self-supporting ZSM-5 crystals with hierarchical porosity were prepared through a steam-assisted crystallization method using sponges as rigid scaffolds. The synthesized materia...

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Main Authors: Hu, T., Liu, Jian, Cao, C., Song, W.
Format: Journal Article
Published: 2017
Online Access:http://hdl.handle.net/20.500.11937/72023
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author Hu, T.
Liu, Jian
Cao, C.
Song, W.
author_facet Hu, T.
Liu, Jian
Cao, C.
Song, W.
author_sort Hu, T.
building Curtin Institutional Repository
collection Online Access
description © 2017, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved. Self-supporting ZSM-5 crystals with hierarchical porosity were prepared through a steam-assisted crystallization method using sponges as rigid scaffolds. The synthesized materials were characterized by X-ray diffraction, nitrogen sorption, scanning electron microscopy, transmission electron microscopy, solid-state nuclear magnetic resonance spectroscopy and ammonia temperature-programmed desorption. The ZSM-5 monoliths exhibited high crystallinities, hierarchical porous structures and strong acidities. They showed superior catalytic performance in the liquid-phase esterification reaction between benzyl alcohol and hexanoic acid.
first_indexed 2025-11-14T10:50:45Z
format Journal Article
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institution Curtin University Malaysia
institution_category Local University
last_indexed 2025-11-14T10:50:45Z
publishDate 2017
recordtype eprints
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spelling curtin-20.500.11937-720232018-12-13T09:32:59Z Synthesis of ZSM-5 monoliths with hierarchical porosity through a steam-assisted crystallization method using sponges as scaffolds Hu, T. Liu, Jian Cao, C. Song, W. © 2017, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved. Self-supporting ZSM-5 crystals with hierarchical porosity were prepared through a steam-assisted crystallization method using sponges as rigid scaffolds. The synthesized materials were characterized by X-ray diffraction, nitrogen sorption, scanning electron microscopy, transmission electron microscopy, solid-state nuclear magnetic resonance spectroscopy and ammonia temperature-programmed desorption. The ZSM-5 monoliths exhibited high crystallinities, hierarchical porous structures and strong acidities. They showed superior catalytic performance in the liquid-phase esterification reaction between benzyl alcohol and hexanoic acid. 2017 Journal Article http://hdl.handle.net/20.500.11937/72023 10.1016/S1872-2067(17)62828-6 restricted
spellingShingle Hu, T.
Liu, Jian
Cao, C.
Song, W.
Synthesis of ZSM-5 monoliths with hierarchical porosity through a steam-assisted crystallization method using sponges as scaffolds
title Synthesis of ZSM-5 monoliths with hierarchical porosity through a steam-assisted crystallization method using sponges as scaffolds
title_full Synthesis of ZSM-5 monoliths with hierarchical porosity through a steam-assisted crystallization method using sponges as scaffolds
title_fullStr Synthesis of ZSM-5 monoliths with hierarchical porosity through a steam-assisted crystallization method using sponges as scaffolds
title_full_unstemmed Synthesis of ZSM-5 monoliths with hierarchical porosity through a steam-assisted crystallization method using sponges as scaffolds
title_short Synthesis of ZSM-5 monoliths with hierarchical porosity through a steam-assisted crystallization method using sponges as scaffolds
title_sort synthesis of zsm-5 monoliths with hierarchical porosity through a steam-assisted crystallization method using sponges as scaffolds
url http://hdl.handle.net/20.500.11937/72023