Nanopore structure comparison between shale oil and shale gas: examples from the Bakken and Longmaxi Formations

© 2018, The Author(s). In order to analyze and compare the differences in pore structures between shale gas and shale oil formations, a few samples from the Longmaxi and Bakken Formations were collected and studied using X-ray diffraction, LECO TOC measurement, gas adsorption and field-emission scan...

Full description

Bibliographic Details
Main Authors: Liu, K., Wang, L., Ostadhassan, M., Zou, J., Bubach, B., Rezaee, M. Reza
Format: Journal Article
Published: China University of Petroleum 2019
Online Access:http://hdl.handle.net/20.500.11937/71828
_version_ 1848762583684743168
author Liu, K.
Wang, L.
Ostadhassan, M.
Zou, J.
Bubach, B.
Rezaee, M. Reza
author_facet Liu, K.
Wang, L.
Ostadhassan, M.
Zou, J.
Bubach, B.
Rezaee, M. Reza
author_sort Liu, K.
building Curtin Institutional Repository
collection Online Access
description © 2018, The Author(s). In order to analyze and compare the differences in pore structures between shale gas and shale oil formations, a few samples from the Longmaxi and Bakken Formations were collected and studied using X-ray diffraction, LECO TOC measurement, gas adsorption and field-emission scanning electron microscope. The results show that samples from the Bakken Formation have a higher TOC than those from the Longmaxi Formation. The Longmaxi Formation has higher micropore volume and larger micropore surface area and exhibited a smaller average distribution of microsize pores compared to the Bakken Formation. Both formations have similar meso-macropore volume. The Longmaxi Formation has a much larger meso-macropore surface area, which is corresponding to a smaller average meso-macropore size. CO2 adsorption data processing shows that the pore size of the majority of the micropores in the samples from the Longmaxi Formation is less than 1 nm, while the pore size of the most of the micropores in the samples from the Bakken Formation is larger than 1 nm. Both formations have the same number of pore clusters in the 2–20 nm range, but the Bakken Formation has two additional pore size groups with mean pore size diameters larger than 20 nm. Multifractal analysis of pore size distribution curves that was derived from gas adsorption indicates that the samples from the Longmaxi Formation have more significant micropore heterogeneity and less meso-macropore heterogeneity. Abundant micropores as well as meso-macropores exist in the organic matter in the Longmaxi Formation, while the organic matter of the Bakken Formation hosts mainly micropores.
first_indexed 2025-11-14T10:49:53Z
format Journal Article
id curtin-20.500.11937-71828
institution Curtin University Malaysia
institution_category Local University
last_indexed 2025-11-14T10:49:53Z
publishDate 2019
publisher China University of Petroleum
recordtype eprints
repository_type Digital Repository
spelling curtin-20.500.11937-718282019-03-18T06:35:11Z Nanopore structure comparison between shale oil and shale gas: examples from the Bakken and Longmaxi Formations Liu, K. Wang, L. Ostadhassan, M. Zou, J. Bubach, B. Rezaee, M. Reza © 2018, The Author(s). In order to analyze and compare the differences in pore structures between shale gas and shale oil formations, a few samples from the Longmaxi and Bakken Formations were collected and studied using X-ray diffraction, LECO TOC measurement, gas adsorption and field-emission scanning electron microscope. The results show that samples from the Bakken Formation have a higher TOC than those from the Longmaxi Formation. The Longmaxi Formation has higher micropore volume and larger micropore surface area and exhibited a smaller average distribution of microsize pores compared to the Bakken Formation. Both formations have similar meso-macropore volume. The Longmaxi Formation has a much larger meso-macropore surface area, which is corresponding to a smaller average meso-macropore size. CO2 adsorption data processing shows that the pore size of the majority of the micropores in the samples from the Longmaxi Formation is less than 1 nm, while the pore size of the most of the micropores in the samples from the Bakken Formation is larger than 1 nm. Both formations have the same number of pore clusters in the 2–20 nm range, but the Bakken Formation has two additional pore size groups with mean pore size diameters larger than 20 nm. Multifractal analysis of pore size distribution curves that was derived from gas adsorption indicates that the samples from the Longmaxi Formation have more significant micropore heterogeneity and less meso-macropore heterogeneity. Abundant micropores as well as meso-macropores exist in the organic matter in the Longmaxi Formation, while the organic matter of the Bakken Formation hosts mainly micropores. 2019 Journal Article http://hdl.handle.net/20.500.11937/71828 10.1007/s12182-018-0277-3 China University of Petroleum restricted
spellingShingle Liu, K.
Wang, L.
Ostadhassan, M.
Zou, J.
Bubach, B.
Rezaee, M. Reza
Nanopore structure comparison between shale oil and shale gas: examples from the Bakken and Longmaxi Formations
title Nanopore structure comparison between shale oil and shale gas: examples from the Bakken and Longmaxi Formations
title_full Nanopore structure comparison between shale oil and shale gas: examples from the Bakken and Longmaxi Formations
title_fullStr Nanopore structure comparison between shale oil and shale gas: examples from the Bakken and Longmaxi Formations
title_full_unstemmed Nanopore structure comparison between shale oil and shale gas: examples from the Bakken and Longmaxi Formations
title_short Nanopore structure comparison between shale oil and shale gas: examples from the Bakken and Longmaxi Formations
title_sort nanopore structure comparison between shale oil and shale gas: examples from the bakken and longmaxi formations
url http://hdl.handle.net/20.500.11937/71828