One-pot Selective Formylation and Claisen Rearrangement on Calix[4]arenes

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One-pot Selective Formylation and Claisen Rearrangement on Calix[4]arenes

A versatile synthon with formyl and allyl groups at the upper rim of calix[4]arene has been synthesized in two steps. Selective formylation of 25,27-diallyloxy-26,28-dihydroxycalix[4]arene, along with the Claisen rearrangement of the allyl groups, was achieved by reaction with hexamethylenetetraamin...

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Bibliographic Details
Main Authors:	Mocerino, Mauro, Ogden, Mark, Pettersen, Jade, Skelton, B., White, A.
Format:	Journal Article
Published:	Taylor and Francis Ltd 2006
Subjects:	Claisen rearrangement Calixarenes Formylation
Online Access:	http://hdl.handle.net/20.500.11937/7153

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