Synthesis, crystal structure, thermal decomposition, and 11B MAS NMR characterization of Mg(BH4)2(NH3BH 3)2

Synthesis, crystal structure, thermal decomposition, and 11B MAS NMR characterization of Mg(BH4)2(NH3BH 3)2

A metal borohydride-ammonia borane complex, Mg(BH4) 2(NH3BH3)2 was synthesized via a solid-state reaction between Mg(BH4)2 and NH 3BH3. Different mechanochemical reaction mechanisms are observed, since Mg(BH4)2(NH3BH 3)2 is obtained from a-Mg(BH4) 2, whereas a mixture of Mg(BH4)2(NH 3BH3)2, NH3BH3,...

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Bibliographic Details
Main Authors: Jepsen, L., Ban, V., Moller, Kasper, Lee, Y., Cho, Y., Besenbacher, F., Filinchuk, Y., Skibsted, J., Jensen, T.
Format: Journal Article
Published: American Chemical Society 2014
Online Access:http://hdl.handle.net/20.500.11937/71527

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