Perovskite oxide and carbonate composite membrane for carbon dioxide transport

© 2018 Elsevier B.V. A novel La0.6Sr0.4Co0.2Fe0.8O3-d based ternary carbonate composite membrane was developed via melting impregnation. The enhanced carbon dioxide permeability is due to the existence of La0.6Sr0.4Co0.2Fe0.8O3-d, a mixed ionic-electronic conductor, and the carbonate phases. The com...

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Bibliographic Details
Main Authors: Zhuang, S., Han, N., Xing, M., Meng, B., Liu, Shaomin
Format: Journal Article
Published: Elsevier BV 2019
Online Access:http://hdl.handle.net/20.500.11937/71299
Description
Summary:© 2018 Elsevier B.V. A novel La0.6Sr0.4Co0.2Fe0.8O3-d based ternary carbonate composite membrane was developed via melting impregnation. The enhanced carbon dioxide permeability is due to the existence of La0.6Sr0.4Co0.2Fe0.8O3-d, a mixed ionic-electronic conductor, and the carbonate phases. The composite membrane greatly promotes the CO2 surface reaction rate to form CO32- and the subsequent ionic transport rate. To further understand the mechanism, the effect of O2 on carbon dioxide permeability was also analyzed under fuel gas conditions.