Ash cenosphere fragmentation during pulverised pyrite combustion: Importance of cooling

This paper as the first time in the field reports the direct experimental evidence for demonstrating the important role of cooling in ash cenosphere fragmentation using a simple but unique combustion system. The combustion system used pulverised pyrite (38-45 µm) for combustion in drop-tube furnace...

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Main Authors: Wu, Hongwei, Li, Y.
Format: Journal Article
Published: Combustion Institute 2018
Online Access:http://hdl.handle.net/20.500.11937/70239
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author Wu, Hongwei
Li, Y.
author_facet Wu, Hongwei
Li, Y.
author_sort Wu, Hongwei
building Curtin Institutional Repository
collection Online Access
description This paper as the first time in the field reports the direct experimental evidence for demonstrating the important role of cooling in ash cenosphere fragmentation using a simple but unique combustion system. The combustion system used pulverised pyrite (38-45 µm) for combustion in drop-tube furnace under designed conditions (gas temperature: 1000 °C; residence time: 1.2 s), which produced dominantly ash cenosphere particles or fragments. The combustion products were quenched under various cooling conditions (represented by nominal cooling rates of 6400-11,800 °C/s) for sampling. The results show that increasing cooling rate from 6400 to 11,800 °C/s substantially intensifies ash cenosphere fragmentation. Such enhanced ash cenosphere fragmentation leads to a significant shift in the particle size distribution of ash collected in the cyclone (>10 µm) to much smaller sizes. It also produces considerably more particulate matter (PM) with aerodynamic sizes less than 10 µm (i.e., PM10) that consists of dominantly PM with aerodynamic sizes between 1 and 10 µm (i.e., PM1-10) and some PM with aerodynamic sizes less than 1 µm (i.e., PM1). It is further noted that the PM1is mainly PM with aerodynamic sizes between 0.1 and 1 µm (i.e., PM0.1-1) and to a considerably lesser extent PM with aerodynamic sizes less than 0.1 µm (i.e., PM0.1). Chemical analyses further show that both ash and PM samples contain only Fe2O3, indicating that complete consumption of sulphur and full oxidation of iron have been achieved during pulverised pyrite combustion under the conditions.
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spelling curtin-20.500.11937-702392019-01-30T07:39:28Z Ash cenosphere fragmentation during pulverised pyrite combustion: Importance of cooling Wu, Hongwei Li, Y. This paper as the first time in the field reports the direct experimental evidence for demonstrating the important role of cooling in ash cenosphere fragmentation using a simple but unique combustion system. The combustion system used pulverised pyrite (38-45 µm) for combustion in drop-tube furnace under designed conditions (gas temperature: 1000 °C; residence time: 1.2 s), which produced dominantly ash cenosphere particles or fragments. The combustion products were quenched under various cooling conditions (represented by nominal cooling rates of 6400-11,800 °C/s) for sampling. The results show that increasing cooling rate from 6400 to 11,800 °C/s substantially intensifies ash cenosphere fragmentation. Such enhanced ash cenosphere fragmentation leads to a significant shift in the particle size distribution of ash collected in the cyclone (>10 µm) to much smaller sizes. It also produces considerably more particulate matter (PM) with aerodynamic sizes less than 10 µm (i.e., PM10) that consists of dominantly PM with aerodynamic sizes between 1 and 10 µm (i.e., PM1-10) and some PM with aerodynamic sizes less than 1 µm (i.e., PM1). It is further noted that the PM1is mainly PM with aerodynamic sizes between 0.1 and 1 µm (i.e., PM0.1-1) and to a considerably lesser extent PM with aerodynamic sizes less than 0.1 µm (i.e., PM0.1). Chemical analyses further show that both ash and PM samples contain only Fe2O3, indicating that complete consumption of sulphur and full oxidation of iron have been achieved during pulverised pyrite combustion under the conditions. 2018 Journal Article http://hdl.handle.net/20.500.11937/70239 10.1016/j.proci.2018.07.007 Combustion Institute restricted
spellingShingle Wu, Hongwei
Li, Y.
Ash cenosphere fragmentation during pulverised pyrite combustion: Importance of cooling
title Ash cenosphere fragmentation during pulverised pyrite combustion: Importance of cooling
title_full Ash cenosphere fragmentation during pulverised pyrite combustion: Importance of cooling
title_fullStr Ash cenosphere fragmentation during pulverised pyrite combustion: Importance of cooling
title_full_unstemmed Ash cenosphere fragmentation during pulverised pyrite combustion: Importance of cooling
title_short Ash cenosphere fragmentation during pulverised pyrite combustion: Importance of cooling
title_sort ash cenosphere fragmentation during pulverised pyrite combustion: importance of cooling
url http://hdl.handle.net/20.500.11937/70239