Dynamic interfacial tension of nonanoic acid/hexadecane/water system in response to pH adjustment

The ability to accurately model dynamic interfacial tension offers valuable predictive power in non-equilibrium multiphase systems. In this study, a recently-developed technique was employed to experimentally monitor the interfacial tension during neutralization of the adsorbed nonanoic acid at an o...

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Main Authors: Hyde, A., Phan, Chi, Yusa, S.
Format: Journal Article
Published: Elsevier BV 2018
Online Access:http://hdl.handle.net/20.500.11937/69486
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author Hyde, A.
Phan, Chi
Yusa, S.
author_facet Hyde, A.
Phan, Chi
Yusa, S.
author_sort Hyde, A.
building Curtin Institutional Repository
collection Online Access
description The ability to accurately model dynamic interfacial tension offers valuable predictive power in non-equilibrium multiphase systems. In this study, a recently-developed technique was employed to experimentally monitor the interfacial tension during neutralization of the adsorbed nonanoic acid at an oil/water interface. The transient oil/water interfacial tension was successfully obtained during reaction, for more than one hour, by fitting the Young-Laplace equation to the holm meridian. Subsequently, the dynamic data was effectively described by a dynamic model based on the underpinning physical principle: diffusion of hydronium ions. The experimental and modelling methods are applicable to mixtures of alkane/carboxylic acid/water, which are often found in industrial processes.
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institution Curtin University Malaysia
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publishDate 2018
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spelling curtin-20.500.11937-694862020-06-15T03:06:47Z Dynamic interfacial tension of nonanoic acid/hexadecane/water system in response to pH adjustment Hyde, A. Phan, Chi Yusa, S. The ability to accurately model dynamic interfacial tension offers valuable predictive power in non-equilibrium multiphase systems. In this study, a recently-developed technique was employed to experimentally monitor the interfacial tension during neutralization of the adsorbed nonanoic acid at an oil/water interface. The transient oil/water interfacial tension was successfully obtained during reaction, for more than one hour, by fitting the Young-Laplace equation to the holm meridian. Subsequently, the dynamic data was effectively described by a dynamic model based on the underpinning physical principle: diffusion of hydronium ions. The experimental and modelling methods are applicable to mixtures of alkane/carboxylic acid/water, which are often found in industrial processes. 2018 Journal Article http://hdl.handle.net/20.500.11937/69486 10.1016/j.colsurfa.2018.06.002 Elsevier BV restricted
spellingShingle Hyde, A.
Phan, Chi
Yusa, S.
Dynamic interfacial tension of nonanoic acid/hexadecane/water system in response to pH adjustment
title Dynamic interfacial tension of nonanoic acid/hexadecane/water system in response to pH adjustment
title_full Dynamic interfacial tension of nonanoic acid/hexadecane/water system in response to pH adjustment
title_fullStr Dynamic interfacial tension of nonanoic acid/hexadecane/water system in response to pH adjustment
title_full_unstemmed Dynamic interfacial tension of nonanoic acid/hexadecane/water system in response to pH adjustment
title_short Dynamic interfacial tension of nonanoic acid/hexadecane/water system in response to pH adjustment
title_sort dynamic interfacial tension of nonanoic acid/hexadecane/water system in response to ph adjustment
url http://hdl.handle.net/20.500.11937/69486