A surface-modified antiperovskite as an electrocatalyst for water oxidation
An efficient and cost-effective oxygen evolution reaction (OER) electrocatalyst is key for electrochemical energy generation and storage technologies. Here, the rational design and in situ formation of an antiperovskite-based hybrid with a porous conductive Cu1-xNNi3-y(x and y represent defect) core...
| Main Authors: | , , , , , , |
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| Format: | Journal Article |
| Published: |
Macmillan Publishers Limited
2018
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| Online Access: | http://hdl.handle.net/20.500.11937/68874 |
| _version_ | 1848761911422746624 |
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| author | Zhu, Y. Chen, G. Zhong, Yijun Chen, Y. Ma, N. Zhou, W. Shao, Zongping |
| author_facet | Zhu, Y. Chen, G. Zhong, Yijun Chen, Y. Ma, N. Zhou, W. Shao, Zongping |
| author_sort | Zhu, Y. |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | An efficient and cost-effective oxygen evolution reaction (OER) electrocatalyst is key for electrochemical energy generation and storage technologies. Here, the rational design and in situ formation of an antiperovskite-based hybrid with a porous conductive Cu1-xNNi3-y(x and y represent defect) core and amorphous FeNiCu (oxy)hydroxide shell is reported as a promising water oxidation electrocatalyst, showing outstanding performance. Benefiting from the unique advantage of core-shell structure, as well as the synergistic effect of Fe, Ni, and Cu and the highly porous hierarchical structure, the hybrid catalyst exhibits highly efficient and robust OER performance in alkaline environments, outperforming the benchmark IrO2catalyst in several aspects. Our findings demonstrate the application potential of antiperovskite-based materials in the field of electrocatalysis, which may inspire insights into the development of novel materials for energy generation and storage applications. |
| first_indexed | 2025-11-14T10:39:12Z |
| format | Journal Article |
| id | curtin-20.500.11937-68874 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T10:39:12Z |
| publishDate | 2018 |
| publisher | Macmillan Publishers Limited |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-688742018-06-29T12:35:58Z A surface-modified antiperovskite as an electrocatalyst for water oxidation Zhu, Y. Chen, G. Zhong, Yijun Chen, Y. Ma, N. Zhou, W. Shao, Zongping An efficient and cost-effective oxygen evolution reaction (OER) electrocatalyst is key for electrochemical energy generation and storage technologies. Here, the rational design and in situ formation of an antiperovskite-based hybrid with a porous conductive Cu1-xNNi3-y(x and y represent defect) core and amorphous FeNiCu (oxy)hydroxide shell is reported as a promising water oxidation electrocatalyst, showing outstanding performance. Benefiting from the unique advantage of core-shell structure, as well as the synergistic effect of Fe, Ni, and Cu and the highly porous hierarchical structure, the hybrid catalyst exhibits highly efficient and robust OER performance in alkaline environments, outperforming the benchmark IrO2catalyst in several aspects. Our findings demonstrate the application potential of antiperovskite-based materials in the field of electrocatalysis, which may inspire insights into the development of novel materials for energy generation and storage applications. 2018 Journal Article http://hdl.handle.net/20.500.11937/68874 10.1038/s41467-018-04682-y Macmillan Publishers Limited restricted |
| spellingShingle | Zhu, Y. Chen, G. Zhong, Yijun Chen, Y. Ma, N. Zhou, W. Shao, Zongping A surface-modified antiperovskite as an electrocatalyst for water oxidation |
| title | A surface-modified antiperovskite as an electrocatalyst for water oxidation |
| title_full | A surface-modified antiperovskite as an electrocatalyst for water oxidation |
| title_fullStr | A surface-modified antiperovskite as an electrocatalyst for water oxidation |
| title_full_unstemmed | A surface-modified antiperovskite as an electrocatalyst for water oxidation |
| title_short | A surface-modified antiperovskite as an electrocatalyst for water oxidation |
| title_sort | surface-modified antiperovskite as an electrocatalyst for water oxidation |
| url | http://hdl.handle.net/20.500.11937/68874 |