Tert-Butyldimethylsilyl Amine (TBDMS-NH2): A Mild and Green Reagent for the Protection of Benzyl Alcohols, Phenols, and Carboxylic Acids under Solvent-Free Conditions
© The Authors 2016. Herein, we present the use of the tert-butyldimethylsilyl amine (TBDMS-NH2) as a silylating reagent for phenols, benzyl alcohols, and carboxylic acids. Unlike other silyl protection reactions, this reported process with TBDMS-NH2 does not involve the formation of HCl. Importantly...
| Main Authors: | Duczynski, J., Fuller, Rebecca, Stewart, S. |
|---|---|
| Format: | Journal Article |
| Published: |
CSIRO Publishing
2016
|
| Online Access: | http://hdl.handle.net/20.500.11937/68534 |
Similar Items
(N-Benzyl-N-ethyldithiocarbamato)di-tert-butylchloridotin(IV).
by: Abdul Mutalib, Amirah Faizah, et al.
Published: (2011)
by: Abdul Mutalib, Amirah Faizah, et al.
Published: (2011)
Carbon dioxide as a reagent and solvent
by: Streng, Emilia S.
Published: (2017)
by: Streng, Emilia S.
Published: (2017)
Ethyl 1-tert-butyl-2-(4-methoxyphenyl)-1H-benzimidazole-5-carboxylate
by: Arumugam, Natarajan, et al.
Published: (2010)
by: Arumugam, Natarajan, et al.
Published: (2010)
9-Benzyl-6-benzylsulfanyl-9H-purin-2-amine
by: Hariono, Maywan, et al.
Published: (2014)
by: Hariono, Maywan, et al.
Published: (2014)
Catalytic reductive N-alkylation of amines using carboxylic acids
by: Andrews, Keith Gordon, et al.
Published: (2015)
by: Andrews, Keith Gordon, et al.
Published: (2015)
The simulation of intermolecular interactions of carboxylic and amine groups with calcium carbonate
by: Abu Zar, Che Azimi, et al.
Published: (2023)
by: Abu Zar, Che Azimi, et al.
Published: (2023)
Synthesis of benzylated amine-substituted xanthone derivatives and their antioxidant and anti-inflammatory activities
by: Wong, Ka Woong, et al.
Published: (2022)
by: Wong, Ka Woong, et al.
Published: (2022)
Synthesis and pharmacological profiling of analogues of benzyl quinolone carboxylic acid (BQCA) as allosteric modulators of the M1 muscarinic receptor
by: Mistry, Shailesh N., et al.
Published: (2013)
by: Mistry, Shailesh N., et al.
Published: (2013)
Asymmetric Amine-Carboxylic Acid Organic-Inorganic Hybrid Wells Dawson Polyoxometalates
by: Alnahdi, Noor
Published: (2023)
by: Alnahdi, Noor
Published: (2023)
Molecular interaction of carboxylic and amine group with calcium and iron for solid scale dissolution
by: M. H., Sulaiman, et al.
Published: (2018)
by: M. H., Sulaiman, et al.
Published: (2018)
Solvent free benzyl alcohol oxidation by AuPd/TiO₂ catalysts
by: Mohd Jamjam, Norasidah
Published: (2017)
by: Mohd Jamjam, Norasidah
Published: (2017)
Immobilization of candida rugosa lipase on aminated polyvinyl benzyl chloride-grafted nylon-6 microfibers
by: Abd Halin, Nur Iilani, et al.
Published: (2019)
by: Abd Halin, Nur Iilani, et al.
Published: (2019)
Free solvent oxidation of molecular benzyl alcohol by newly synthesized AuPd/titania catalysts
by: Mohd JamJam, Norasidah, et al.
Published: (2019)
by: Mohd JamJam, Norasidah, et al.
Published: (2019)
Reagent Degradation in the Synergistic Solvent Extraction System LIX®63/Versatic™10/Nonyl-4PC
by: Hutton-Ashkenny, M., et al.
Published: (2016)
by: Hutton-Ashkenny, M., et al.
Published: (2016)
Synthesis and Applications of tert-Alkylphosphines
by: Barber, Thomas
Published: (2021)
by: Barber, Thomas
Published: (2021)
Characterisation of degraded solvents from the amine scrubbing process
by: Lewis, Rachel V.
Published: (2017)
by: Lewis, Rachel V.
Published: (2017)
Solvent free oxidation of benzyl alcohol to produce benzaldehyde using bimetallic Au-Pd supported catalysts
by: Sarhan, Sanaa Tareq
Published: (2018)
by: Sarhan, Sanaa Tareq
Published: (2018)
Reagent selection for recovery of nickel and cobalt from nitric acid nickel laterite leach solutions by solvent extraction
by: Hutton-Ashkenny, M., et al.
Published: (2015)
by: Hutton-Ashkenny, M., et al.
Published: (2015)
Energy efficient, clean and solvent free photochemical benzylic bromination using NBS in concentrated solar radiation (CSR)
by: Deshpande, S., et al.
Published: (2015)
by: Deshpande, S., et al.
Published: (2015)
Immobilized lipase-catalysed synthesis of fructose oleate ester in ionic liquid [Bmim][TfO] and tert-butanol solvent systems
by: Abdul Rahman, Mohd Basyaruddin, et al.
Published: (2023)
by: Abdul Rahman, Mohd Basyaruddin, et al.
Published: (2023)
trans–cis S-Benzyl dithiocarbazate
by: Shanmuga Sundara Raj, S., et al.
Published: (2000)
by: Shanmuga Sundara Raj, S., et al.
Published: (2000)
4-tert-Butylamino-3-nitrobenzoic acid
by: Narendra Babu, Shivanagere Nagojappa, et al.
Published: (2009)
by: Narendra Babu, Shivanagere Nagojappa, et al.
Published: (2009)
Synthesis of highly porous poly(tert-butyl acrylate)-b-polysulfone-b-poly(tert-butyl acrylate) asymmetric membranes
by: Xie, Y., et al.
Published: (2016)
by: Xie, Y., et al.
Published: (2016)
Benzyl 3-(2-methylphenyl)dithiocarbazate.
by: Tayamon, Shahedeh, et al.
Published: (2012)
by: Tayamon, Shahedeh, et al.
Published: (2012)
Devulcanization of waste tire rubber using Amine Based Solvents and Ultrasonic Energy
by: Walvekar, Rashmi, et al.
Published: (2018)
by: Walvekar, Rashmi, et al.
Published: (2018)
Studies On Prospect Of Curcumin As An Analytical Reagent For Aluminium.
by: Zhu, Qing Gong
Published: (2009)
by: Zhu, Qing Gong
Published: (2009)
Decolourisation of reactive dyestuff using Fenton's reagent
by: Aris, Azmi, et al.
Published: (2005)
by: Aris, Azmi, et al.
Published: (2005)
Glyceryl ether (mono-tert-butoxypropanediol) in emulsion system
by: Yusrabbil Amiyati Yusof,, et al.
Published: (2018)
by: Yusrabbil Amiyati Yusof,, et al.
Published: (2018)
Electrochemical Deoxygenation of Benzylic Alcohols and Electrosynthesis of Spirocycles
by: Edmonds, Alex
Published: (2024)
by: Edmonds, Alex
Published: (2024)
(N-Benzyl-N-isopropyldithiocarbamato)-chloridodiphenyltin(IV)
by: Abdul Muthalib, Amirah Faizah, et al.
Published: (2010)
by: Abdul Muthalib, Amirah Faizah, et al.
Published: (2010)
The impact of hydrogen peroxide as an oxidant for solvent-free liquid phase oxidation of benzyl alcohol using Au-Pd supported carbon and titanium catalysts
by: Tareq, Sarhan Sanaa, et al.
Published: (2018)
by: Tareq, Sarhan Sanaa, et al.
Published: (2018)
Crystal structure of tert-butyl 2-(hydroxymethyl)-5-{4-[(methoxycarbonyl)amino]phenyl}-2,5-dihydro-1H-pyrrole-1-carboxylate, C18H24N2O5
by: Caracelli, Ignez, et al.
Published: (2020)
by: Caracelli, Ignez, et al.
Published: (2020)
Di-tert-butylchlorido(N,N-dibenzyldithiocarbamato)tin(IV).
by: Abdul Muthalib, Amirah Faizah, et al.
Published: (2011)
by: Abdul Muthalib, Amirah Faizah, et al.
Published: (2011)
Photoacoustic study of silica-silane coupling reagent interactions
by: Abu-Zeid, M.E, et al.
Published: (1981)
by: Abu-Zeid, M.E, et al.
Published: (1981)
Novel Synthesis Methods Using Phosphorus and Silicon Reagents
by: Thornton, Edward Alexander
Published: (2020)
by: Thornton, Edward Alexander
Published: (2020)
Natural products as novel reagents for the detection of latent fingermarks
by: Jelly, Renee Michelle
Published: (2010)
by: Jelly, Renee Michelle
Published: (2010)
Industrial detergent wastewater treatment via fenton reagent
by: Mohd Zairie, Mohd Yusuff
Published: (2010)
by: Mohd Zairie, Mohd Yusuff
Published: (2010)
Seed treatment reagent for direct seeding paddy rice.
by: Syed Rastan, Syed Omar, et al.
Published: (2007)
by: Syed Rastan, Syed Omar, et al.
Published: (2007)
Removal Of Colour, Cod And Nh3-N From Semi-Aerobic Sanitary Landfill Leachate Using Sulfonic Acid And
Quaternary Amine Functional Group Resins
by: Bashir, Mohammed J. K.
Published: (2011)
by: Bashir, Mohammed J. K.
Published: (2011)
Crystal structure of tert-butyl (1S,2R,5R)-2-(hydroxymethyl)-4-(4-methoxyphenyl)-6-oxa-3-azabicyclo[3.1.0]hexane-3-carboxylate, C17H23NO5
by: Caracelli, Ignez, et al.
Published: (2020)
by: Caracelli, Ignez, et al.
Published: (2020)
Similar Items
-
(N-Benzyl-N-ethyldithiocarbamato)di-tert-butylchloridotin(IV).
by: Abdul Mutalib, Amirah Faizah, et al.
Published: (2011) -
Carbon dioxide as a reagent and solvent
by: Streng, Emilia S.
Published: (2017) -
Ethyl 1-tert-butyl-2-(4-methoxyphenyl)-1H-benzimidazole-5-carboxylate
by: Arumugam, Natarajan, et al.
Published: (2010) -
9-Benzyl-6-benzylsulfanyl-9H-purin-2-amine
by: Hariono, Maywan, et al.
Published: (2014) -
Catalytic reductive N-alkylation of amines using carboxylic acids
by: Andrews, Keith Gordon, et al.
Published: (2015)