Solution phase and solid state studies of lanthanoid-calixarene bottlebrush clusters
The conditions required for formation of unusual bottlebrush-shaped lanthanoid coordination clusters were investigated. The known clusters are supported by tetrazole-functionalised p-t-butylcalixarenes, and carboxylate co-ligands. It was confirmed that the lighter lanthanoids form mononuclear comple...
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| Format: | Thesis |
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Curtin University
2018
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| Online Access: | http://hdl.handle.net/20.500.11937/68324 |
| _version_ | 1848761791048318976 |
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| author | Phe, Rene Zhi Hui |
| author_facet | Phe, Rene Zhi Hui |
| author_sort | Phe, Rene Zhi Hui |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | The conditions required for formation of unusual bottlebrush-shaped lanthanoid coordination clusters were investigated. The known clusters are supported by tetrazole-functionalised p-t-butylcalixarenes, and carboxylate co-ligands. It was confirmed that the lighter lanthanoids form mononuclear complexes, and heavier lanthanoids form bottlebrush clusters. Changing the carboxylate co-ligand had little impact on the complexes formed. Altering the structure of the calixarene had a significant impact. When the t-butyl group was replaced with hydrogen or allyl groups, mononuclear complexes formed. |
| first_indexed | 2025-11-14T10:37:17Z |
| format | Thesis |
| id | curtin-20.500.11937-68324 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T10:37:17Z |
| publishDate | 2018 |
| publisher | Curtin University |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-683242018-07-02T13:58:13Z Solution phase and solid state studies of lanthanoid-calixarene bottlebrush clusters Phe, Rene Zhi Hui The conditions required for formation of unusual bottlebrush-shaped lanthanoid coordination clusters were investigated. The known clusters are supported by tetrazole-functionalised p-t-butylcalixarenes, and carboxylate co-ligands. It was confirmed that the lighter lanthanoids form mononuclear complexes, and heavier lanthanoids form bottlebrush clusters. Changing the carboxylate co-ligand had little impact on the complexes formed. Altering the structure of the calixarene had a significant impact. When the t-butyl group was replaced with hydrogen or allyl groups, mononuclear complexes formed. 2018 Thesis http://hdl.handle.net/20.500.11937/68324 Curtin University fulltext |
| spellingShingle | Phe, Rene Zhi Hui Solution phase and solid state studies of lanthanoid-calixarene bottlebrush clusters |
| title | Solution phase and solid state studies of lanthanoid-calixarene bottlebrush clusters |
| title_full | Solution phase and solid state studies of lanthanoid-calixarene bottlebrush clusters |
| title_fullStr | Solution phase and solid state studies of lanthanoid-calixarene bottlebrush clusters |
| title_full_unstemmed | Solution phase and solid state studies of lanthanoid-calixarene bottlebrush clusters |
| title_short | Solution phase and solid state studies of lanthanoid-calixarene bottlebrush clusters |
| title_sort | solution phase and solid state studies of lanthanoid-calixarene bottlebrush clusters |
| url | http://hdl.handle.net/20.500.11937/68324 |