Silicon (100) electrodes resistant to oxidation in aqueous solutions: An unexpected benefit of surface acetylene moieties

QR Code

Silicon (100) electrodes resistant to oxidation in aqueous solutions: An unexpected benefit of surface acetylene moieties

Here we report on the functionalization of alkyne-terminated alkyl monolayers on highly doped Si(100) using "click" reactions to immobilize ferrocene derivatives. The reaction of hydrogen-terminated silicon surfaces with a diyne species was shown to afford very robust functional surfaces w...

Full description

Bibliographic Details
Main Authors:	Ciampi, Simone, Eggers, P., Le Saux, G., James, M., Harper, J., Gooding, J.
Format:	Journal Article
Published:	American Chemical Society 2009
Online Access:	http://hdl.handle.net/20.500.11937/6817

Similar Items

Optimization of click chemistry of ferrocene derivatives on acetylene-functionalized silicon(100) surfaces
by: Ciampi, Simone, et al.
Published: (2008)

Tandem "click" reactions at acetylene-terminated Si(100) monolayers
by: Ciampi, Simone, et al.
Published: (2011)

Preparation of thiol-terminated monolayers on silicon(100) surfaces using thioacetyl-protected alkynethiol
by: Ng, C., et al.
Published: (2010)

Antifouling behaviour of silicon surfaces modified with self-assembled monolayers containing both ethylene glycol and charged moieties
by: Ng, C., et al.
Published: (2010)

Comparing the reactivity of alkynes and alkenes on silicon 100 surfaces
by: Ng, A., et al.
Published: (2009)

Direct electrochemistry of cytochrome c at modified Si(100) electrodes
by: Ciampi, Simone, et al.
Published: (2010)

Oxidative acetylenic coupling reactions as a surface chemistry tool
by: Ciampi, S., et al.
Published: (2011)

Silicon (100) surfaces modified by osmium bipyridine complexes
by: Ciampi, Simone, et al.
Published: (2010)

Electrochemical behavior of gold colloidal alkyl modified silicon surfaces
by: Le Saux, G., et al.
Published: (2009)

Electrochemical "switching" of Si(100) modular assemblies
by: Ciampi, Simone, et al.
Published: (2012)

Wet chemical routes to the assembly of organic monolayers on silicon surfaces via the formation of Si-C bonds: Surface preparation, passivation and functionalization
by: Ciampi, Simone, et al.
Published: (2010)

Stability of Chemically Passivated Silicon Electrodes in Aqueous Solutions: Interplay between Bias Voltage and Hydration of the Electrolyte
by: Gonçales, V., et al.
Published: (2016)

The detailed characterization of electrochemically switchable molecular assemblies on silicon electrodes
by: Ciampi, S., et al.
Published: (2013)

A robust DNA interface on a silicon electrode
by: Michaels, P., et al.
Published: (2014)

Silicon–SAM–AuNP electrodes: Electrochemical “switching” and stability
by: Kashi, M., et al.
Published: (2016)

Probing the effect of the solution environment around redox-active moieties using rigid anthraquinone terminated molecular rulers
by: Darwish, Nadim, et al.
Published: (2012)

Click chemistry in mesoporous materials: Functionalization of porous silicon rugate filters
by: Ciampi, Simone, et al.
Published: (2008)

Forming Ferrocenyl Self-Assembled Monolayers on Si(100) Electrodes with Different Alkyl Chain Lengths for Electron Transfer Studies
by: Ahmad, S., et al.
Published: (2019)

Single-molecule electrical contacts on silicon electrodes under ambient conditions
by: Aragones, A., et al.
Published: (2017)

Bubbles pinned on electrodes: Friends or foes of aqueous electrochemistry?
by: Ciampi, Simone, et al.
Published: (2022)

The impact of surface coverage on the kinetics of electron transfer through redox monolayers on a silicon electrode surface
by: Ciampi, Simone, et al.
Published: (2015)

Forming ferrocenyl self‐assembled monolayers on Si(100) electrodes with different alkyl chain lengths for electron transfer studies
by: A. Ahmad, Shahrul A., et al.
Published: (2019)

The impact of surface coverage on the kinetics of electron transfer through redox monolayers on a silicon electrode surface
by: Ciampi, S., et al.
Published: (2015)

Light-addressable electrochemistry at semiconductor electrodes: Redox imaging, mask-free lithography and spatially resolved chemical and biological sensing
by: Vogel, Yan, et al.
Published: (2019)

Depth-resolved chemical modification of porous silicon by wavelength-tuned irradiation
by: Guan, B., et al.
Published: (2012)

Harnessing silicon facet-dependent conductivity to enhance the direct-current produced by a sliding Schottky diode triboelectric nanogenerator
by: Ferrie, S., et al.
Published: (2020)

Light Activated Electrochemistry: Light Intensity and pH Dependence on Electrochemical Performance of Anthraquinone Derivatized Silicon
by: Yang, Y., et al.
Published: (2016)

Synthesis of carbon nanotubes for acetylene detection
by: Md.Yasin, Faizah, et al.
Published: (2008)

TEMPO Monolayers on Si(100) Electrodes: Electrostatic Effects by the Electrolyte and Semiconductor Space-Charge on the Electroactivity of a Persistent Radical.
by: Zhang, L., et al.
Published: (2016)

Expect the unexpected
by: Sutherland, Janet
Published: (2012)

Different functionalization of the internal and external surfaces in mesoporous materials for biosensing applications using "click" chemistry
by: Guan, B., et al.
Published: (2011)

Connecting electrodes with light: One wire, many electrodes
by: Choudhury, M., et al.
Published: (2015)

Antibody modified porous silicon microparticles for the selective capture of cells
by: Guan, B., et al.
Published: (2014)

Hydrogen evolution during the electrodeposition of gold nanoparticles at Si(100) photoelectrodes impairs the analysis of current-time transients
by: Vogel, Yan, et al.
Published: (2017)

Development and evaluation of compact acetylene frequency standards
by: Edwards, C., et al.
Published: (2012)

Effects of carbon dioxide on flammability limits of acetylene
by: Nur Fitriah, Mohd Jaafar
Published: (2012)

Study the effect of pressure on flammability limits of acetylene
by: Nurul Bazlinda, Bazalan
Published: (2012)

Common Background Signals in Voltammograms of Crystalline Silicon Electrodes are Reversible Silica-Silicon Redox Chemistry at Highly Conductive Surface Sites
by: Zhang, S., et al.
Published: (2021)

Redox-active monolayers in mesoporous silicon
by: Ciampi, S., et al.
Published: (2012)

One-pot synthesis of colloidal silicon quantum dots and surface functionalization via thiol-ene click chemistry
by: Cheng, X., et al.
Published: (2012)

Cannot write session to /tmp/vufind_sessions/sess_jkfslv29rkcjdc38vohfhiqd65