Polycaprolactone-starch blends with corn-based coupling agent: Physical properties and in vitro analysis

In an attempt to improve properties of polycaprolcatone-starch blend, this study uses zein as coupling agent in preparing the blend through a single-step process. Zein, which has affinity to both polar and non-polar groups, is expected to improve miscibility between the blends' constituents and...

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Main Authors: Nor, F., Kurniawan, Denni, Seo, Y., Park, J., Lee, H., Lim, J.
Format: Journal Article
Published: Sage Publications 2012
Online Access:http://hdl.handle.net/20.500.11937/68153
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author Nor, F.
Kurniawan, Denni
Seo, Y.
Park, J.
Lee, H.
Lim, J.
author_facet Nor, F.
Kurniawan, Denni
Seo, Y.
Park, J.
Lee, H.
Lim, J.
author_sort Nor, F.
building Curtin Institutional Repository
collection Online Access
description In an attempt to improve properties of polycaprolcatone-starch blend, this study uses zein as coupling agent in preparing the blend through a single-step process. Zein, which has affinity to both polar and non-polar groups, is expected to improve miscibility between the blends' constituents and its overall biocompatibility. Mechanical properties of the blend were tested and further characterizations (Fourier transform infrared spectroscopy, thermal properties) were performed to analyze the effect of zein as an addition to the blend's physical properties. The blend's biocompatibility was examined by indirect methods (contact angle and weight gain after immersion in simulated body fluid) and in vitro analysis. No significant effect on the blend's strength and stiffness was caused by adding zein. Hydrophilicity and cell affinity were improved when zein was added. Zein did not perform as a coupling agent that improved miscibility between polycaprolactone and starch, but its addition improved the blend's biocompatibility. © 2012 IMechE.
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institution Curtin University Malaysia
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publishDate 2012
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spelling curtin-20.500.11937-681532018-05-18T08:07:31Z Polycaprolactone-starch blends with corn-based coupling agent: Physical properties and in vitro analysis Nor, F. Kurniawan, Denni Seo, Y. Park, J. Lee, H. Lim, J. In an attempt to improve properties of polycaprolcatone-starch blend, this study uses zein as coupling agent in preparing the blend through a single-step process. Zein, which has affinity to both polar and non-polar groups, is expected to improve miscibility between the blends' constituents and its overall biocompatibility. Mechanical properties of the blend were tested and further characterizations (Fourier transform infrared spectroscopy, thermal properties) were performed to analyze the effect of zein as an addition to the blend's physical properties. The blend's biocompatibility was examined by indirect methods (contact angle and weight gain after immersion in simulated body fluid) and in vitro analysis. No significant effect on the blend's strength and stiffness was caused by adding zein. Hydrophilicity and cell affinity were improved when zein was added. Zein did not perform as a coupling agent that improved miscibility between polycaprolactone and starch, but its addition improved the blend's biocompatibility. © 2012 IMechE. 2012 Journal Article http://hdl.handle.net/20.500.11937/68153 10.1177/0954411912452988 Sage Publications restricted
spellingShingle Nor, F.
Kurniawan, Denni
Seo, Y.
Park, J.
Lee, H.
Lim, J.
Polycaprolactone-starch blends with corn-based coupling agent: Physical properties and in vitro analysis
title Polycaprolactone-starch blends with corn-based coupling agent: Physical properties and in vitro analysis
title_full Polycaprolactone-starch blends with corn-based coupling agent: Physical properties and in vitro analysis
title_fullStr Polycaprolactone-starch blends with corn-based coupling agent: Physical properties and in vitro analysis
title_full_unstemmed Polycaprolactone-starch blends with corn-based coupling agent: Physical properties and in vitro analysis
title_short Polycaprolactone-starch blends with corn-based coupling agent: Physical properties and in vitro analysis
title_sort polycaprolactone-starch blends with corn-based coupling agent: physical properties and in vitro analysis
url http://hdl.handle.net/20.500.11937/68153