Indirect contributions to electron-impact ionization of Li+ (1s2s S1 3) ions: Role of intermediate double- K -vacancy states

Fine details of the cross section for electron-impact ionization of metastable two-electron Li+ (1s2s 3S1) ions are scrutinized by both experiment and theory. Beyond direct knockoff ionization, indirect ionization mechanisms proceeding via formation of intermediate double-K-vacancy (hollow) states e...

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Main Authors: Müller, A., Borovik, A., Huber, K., Schippers, S., Fursa, Dmitry, Bray, Igor
Format: Journal Article
Published: 2018
Online Access:http://hdl.handle.net/20.500.11937/68032
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author Müller, A.
Borovik, A.
Huber, K.
Schippers, S.
Fursa, Dmitry
Bray, Igor
author_facet Müller, A.
Borovik, A.
Huber, K.
Schippers, S.
Fursa, Dmitry
Bray, Igor
author_sort Müller, A.
building Curtin Institutional Repository
collection Online Access
description Fine details of the cross section for electron-impact ionization of metastable two-electron Li+ (1s2s 3S1) ions are scrutinized by both experiment and theory. Beyond direct knockoff ionization, indirect ionization mechanisms proceeding via formation of intermediate double-K-vacancy (hollow) states either in a Li+ ion or in a neutral lithium atom and subsequent emission of one or two electrons, respectively, can contribute to the net production of Li2+ ions. The partial cross sections for such contributions are less than 4% of the total single-ionization cross section. The characteristic steps, resonances, and interference phenomena in the indirect ionization contribution are measured with an experimental energy spread of less than 0.9 eV and with a statistical relative uncertainty of the order of 1.7%, requiring a level of statistical uncertainty in the total single-ionization cross section of better than 0.05%. The measurements are accompanied by convergent-close-coupling calculations performed on a fine energy grid. Theory and experiment are in remarkable agreement concerning the fine details of the ionization cross section. Comparison with previous R-matrix results is less favorable.
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spelling curtin-20.500.11937-680322018-12-04T05:25:18Z Indirect contributions to electron-impact ionization of Li+ (1s2s S1 3) ions: Role of intermediate double- K -vacancy states Müller, A. Borovik, A. Huber, K. Schippers, S. Fursa, Dmitry Bray, Igor Fine details of the cross section for electron-impact ionization of metastable two-electron Li+ (1s2s 3S1) ions are scrutinized by both experiment and theory. Beyond direct knockoff ionization, indirect ionization mechanisms proceeding via formation of intermediate double-K-vacancy (hollow) states either in a Li+ ion or in a neutral lithium atom and subsequent emission of one or two electrons, respectively, can contribute to the net production of Li2+ ions. The partial cross sections for such contributions are less than 4% of the total single-ionization cross section. The characteristic steps, resonances, and interference phenomena in the indirect ionization contribution are measured with an experimental energy spread of less than 0.9 eV and with a statistical relative uncertainty of the order of 1.7%, requiring a level of statistical uncertainty in the total single-ionization cross section of better than 0.05%. The measurements are accompanied by convergent-close-coupling calculations performed on a fine energy grid. Theory and experiment are in remarkable agreement concerning the fine details of the ionization cross section. Comparison with previous R-matrix results is less favorable. 2018 Journal Article http://hdl.handle.net/20.500.11937/68032 10.1103/PhysRevA.97.022709 restricted
spellingShingle Müller, A.
Borovik, A.
Huber, K.
Schippers, S.
Fursa, Dmitry
Bray, Igor
Indirect contributions to electron-impact ionization of Li+ (1s2s S1 3) ions: Role of intermediate double- K -vacancy states
title Indirect contributions to electron-impact ionization of Li+ (1s2s S1 3) ions: Role of intermediate double- K -vacancy states
title_full Indirect contributions to electron-impact ionization of Li+ (1s2s S1 3) ions: Role of intermediate double- K -vacancy states
title_fullStr Indirect contributions to electron-impact ionization of Li+ (1s2s S1 3) ions: Role of intermediate double- K -vacancy states
title_full_unstemmed Indirect contributions to electron-impact ionization of Li+ (1s2s S1 3) ions: Role of intermediate double- K -vacancy states
title_short Indirect contributions to electron-impact ionization of Li+ (1s2s S1 3) ions: Role of intermediate double- K -vacancy states
title_sort indirect contributions to electron-impact ionization of li+ (1s2s s1 3) ions: role of intermediate double- k -vacancy states
url http://hdl.handle.net/20.500.11937/68032