The influence of Carbon Disulfide on Hydroxyl Free Radicals in Phenanthroline Chemiluminescence System

Objective: To clarify the effects of carbon disulfide (CS2) on hydroxyl free radical (*OH) generation in phenanthroline chemiluminescence system (Phen-system). Methods: The dynamic curve of various concentrations of CS2, the quenching effect of thiourea on chemiluminescence intensity and the influen...

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Main Author: Jian, Le
Format: Journal Article
Published: Tianjin shi lao dong wei sheng yan jiu suo ; Tianjin shi lao dong wei sheng huan jing yi xue hui 2001
Subjects:
Online Access:http://eng.med.wanfangdata.com.cn/PaperDetail.aspx?qkid=zhldwszyb&qcode=zhldwszyb200102010
http://hdl.handle.net/20.500.11937/6794
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author Jian, Le
author_facet Jian, Le
author_sort Jian, Le
building Curtin Institutional Repository
collection Online Access
description Objective: To clarify the effects of carbon disulfide (CS2) on hydroxyl free radical (*OH) generation in phenanthroline chemiluminescence system (Phen-system). Methods: The dynamic curve of various concentrations of CS2, the quenching effect of thiourea on chemiluminescence intensity and the influence of CS2 on Phen-system without CuSO4 and Vit C were observed with phenanthroline chemiluminescence system. Results: CS2 could enhance the emission intensity of chemiluminescence and advance the peak time. It had dose-effect relationship between CS2 concentrations (0,10,40,80,120,160 mg/ml) and chemiluminescence peak (r=0.955,R2=0.913,P=0.003), as well as CS2 concentrations and peak time (r=-0.927,R2=0.860,P=0.008). The enhanced chemiluminescence induced by CS2 could be quenched by thiourea but the inhibition rate of it reduced along with the increasing of CS2 concentration (r=-0.816, R2=0.666, P=0.048). When the system were free of CuSO4 and Vit C, CS2 could also induce the emission of luminous intensity. Conclusion: CS2 could induce the generation of hydroxyl free radicals and advance the peak time in Phen-system.
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publisher Tianjin shi lao dong wei sheng yan jiu suo ; Tianjin shi lao dong wei sheng huan jing yi xue hui
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spelling curtin-20.500.11937-67942017-01-30T10:55:37Z The influence of Carbon Disulfide on Hydroxyl Free Radicals in Phenanthroline Chemiluminescence System Jian, Le Carbon disulfide Phenanthroline chemiluminescence system hydroxyl free radical thiourea Objective: To clarify the effects of carbon disulfide (CS2) on hydroxyl free radical (*OH) generation in phenanthroline chemiluminescence system (Phen-system). Methods: The dynamic curve of various concentrations of CS2, the quenching effect of thiourea on chemiluminescence intensity and the influence of CS2 on Phen-system without CuSO4 and Vit C were observed with phenanthroline chemiluminescence system. Results: CS2 could enhance the emission intensity of chemiluminescence and advance the peak time. It had dose-effect relationship between CS2 concentrations (0,10,40,80,120,160 mg/ml) and chemiluminescence peak (r=0.955,R2=0.913,P=0.003), as well as CS2 concentrations and peak time (r=-0.927,R2=0.860,P=0.008). The enhanced chemiluminescence induced by CS2 could be quenched by thiourea but the inhibition rate of it reduced along with the increasing of CS2 concentration (r=-0.816, R2=0.666, P=0.048). When the system were free of CuSO4 and Vit C, CS2 could also induce the emission of luminous intensity. Conclusion: CS2 could induce the generation of hydroxyl free radicals and advance the peak time in Phen-system. 2001 Journal Article http://hdl.handle.net/20.500.11937/6794 http://eng.med.wanfangdata.com.cn/PaperDetail.aspx?qkid=zhldwszyb&qcode=zhldwszyb200102010 Tianjin shi lao dong wei sheng yan jiu suo ; Tianjin shi lao dong wei sheng huan jing yi xue hui restricted
spellingShingle Carbon disulfide
Phenanthroline chemiluminescence system
hydroxyl free radical
thiourea
Jian, Le
The influence of Carbon Disulfide on Hydroxyl Free Radicals in Phenanthroline Chemiluminescence System
title The influence of Carbon Disulfide on Hydroxyl Free Radicals in Phenanthroline Chemiluminescence System
title_full The influence of Carbon Disulfide on Hydroxyl Free Radicals in Phenanthroline Chemiluminescence System
title_fullStr The influence of Carbon Disulfide on Hydroxyl Free Radicals in Phenanthroline Chemiluminescence System
title_full_unstemmed The influence of Carbon Disulfide on Hydroxyl Free Radicals in Phenanthroline Chemiluminescence System
title_short The influence of Carbon Disulfide on Hydroxyl Free Radicals in Phenanthroline Chemiluminescence System
title_sort influence of carbon disulfide on hydroxyl free radicals in phenanthroline chemiluminescence system
topic Carbon disulfide
Phenanthroline chemiluminescence system
hydroxyl free radical
thiourea
url http://eng.med.wanfangdata.com.cn/PaperDetail.aspx?qkid=zhldwszyb&qcode=zhldwszyb200102010
http://hdl.handle.net/20.500.11937/6794