Optimization of SnO2 Nanoparticles Confined in a Carbon Matrix towards Applications as High‐Capacity Anodes in Sodium‐Ion Batteries

SnO2/carbon composites including amorphous carbon and graphene or carbon nanotubes are synthesized by a gas‐liquid interfacial approach and subsequent annealing process. The effect of the carbon source and the conductive additive on the electrochemical performance is investigated by galvanostatic ch...

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Main Authors: Wei, S., Chu, S., Lu, Q., Zhou, W., Cai, R., Shao, Zongping
Format: Journal Article
Published: Wiley - V C H Verlag GmbH & Co. KGaA 2018
Online Access:http://hdl.handle.net/20.500.11937/67760
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author Wei, S.
Chu, S.
Lu, Q.
Zhou, W.
Cai, R.
Shao, Zongping
author_facet Wei, S.
Chu, S.
Lu, Q.
Zhou, W.
Cai, R.
Shao, Zongping
author_sort Wei, S.
building Curtin Institutional Repository
collection Online Access
description SnO2/carbon composites including amorphous carbon and graphene or carbon nanotubes are synthesized by a gas‐liquid interfacial approach and subsequent annealing process. The effect of the carbon source and the conductive additive on the electrochemical performance is investigated by galvanostatic charge‐discharge tests. SnO2@Glucose/Graphene (SnO2@Glu/G) composites as anodes of sodium‐ion batteries show the best electrochemical performance, delivering 306 mA h g−1 after 100 cycles at 0.1 A g−1 between 0.01‐3 V, while exhibiting 278 and 226 mA h g−1 at 1 and 2 A g−1, respectively. The mechanism of improved electrochemical performance for graphene is researched in detail. The results reveal a porous structure with fine SnO2 particles due to the introduction of graphene oxide, and an effective electron charge transfer network from the graphene increases its reversible capacity, rate performance and cycling performance.
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institution Curtin University Malaysia
institution_category Local University
last_indexed 2025-11-14T10:35:03Z
publishDate 2018
publisher Wiley - V C H Verlag GmbH & Co. KGaA
recordtype eprints
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spelling curtin-20.500.11937-677602018-08-24T00:23:22Z Optimization of SnO2 Nanoparticles Confined in a Carbon Matrix towards Applications as High‐Capacity Anodes in Sodium‐Ion Batteries Wei, S. Chu, S. Lu, Q. Zhou, W. Cai, R. Shao, Zongping SnO2/carbon composites including amorphous carbon and graphene or carbon nanotubes are synthesized by a gas‐liquid interfacial approach and subsequent annealing process. The effect of the carbon source and the conductive additive on the electrochemical performance is investigated by galvanostatic charge‐discharge tests. SnO2@Glucose/Graphene (SnO2@Glu/G) composites as anodes of sodium‐ion batteries show the best electrochemical performance, delivering 306 mA h g−1 after 100 cycles at 0.1 A g−1 between 0.01‐3 V, while exhibiting 278 and 226 mA h g−1 at 1 and 2 A g−1, respectively. The mechanism of improved electrochemical performance for graphene is researched in detail. The results reveal a porous structure with fine SnO2 particles due to the introduction of graphene oxide, and an effective electron charge transfer network from the graphene increases its reversible capacity, rate performance and cycling performance. 2018 Journal Article http://hdl.handle.net/20.500.11937/67760 10.1002/slct.201800411 Wiley - V C H Verlag GmbH & Co. KGaA restricted
spellingShingle Wei, S.
Chu, S.
Lu, Q.
Zhou, W.
Cai, R.
Shao, Zongping
Optimization of SnO2 Nanoparticles Confined in a Carbon Matrix towards Applications as High‐Capacity Anodes in Sodium‐Ion Batteries
title Optimization of SnO2 Nanoparticles Confined in a Carbon Matrix towards Applications as High‐Capacity Anodes in Sodium‐Ion Batteries
title_full Optimization of SnO2 Nanoparticles Confined in a Carbon Matrix towards Applications as High‐Capacity Anodes in Sodium‐Ion Batteries
title_fullStr Optimization of SnO2 Nanoparticles Confined in a Carbon Matrix towards Applications as High‐Capacity Anodes in Sodium‐Ion Batteries
title_full_unstemmed Optimization of SnO2 Nanoparticles Confined in a Carbon Matrix towards Applications as High‐Capacity Anodes in Sodium‐Ion Batteries
title_short Optimization of SnO2 Nanoparticles Confined in a Carbon Matrix towards Applications as High‐Capacity Anodes in Sodium‐Ion Batteries
title_sort optimization of sno2 nanoparticles confined in a carbon matrix towards applications as high‐capacity anodes in sodium‐ion batteries
url http://hdl.handle.net/20.500.11937/67760