Effect of Gd2O3 doping on structure and boron volatility of borosilicate glass sealants in solid oxide fuel cells—A study on the La0.6Sr0.4Co0.2Fe0.8O3-δ (LSCF) cathode
Boron volatility is one of the most important properties of borosilicate-based glass sealants in solid oxide fuel cells (SOFCs), as boron contaminants react with lanthanum-containing cathodes, forming LaBO3 and degrading the activity of SOFCs. Here, we report that the reaction between the volatile b...
| Main Authors: | , , , , , , , |
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| Format: | Journal Article |
| Published: |
Elsevier SA
2018
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| Online Access: | http://purl.org/au-research/grants/arc/DP150102025 http://hdl.handle.net/20.500.11937/67613 |
| Summary: | Boron volatility is one of the most important properties of borosilicate-based glass sealants in solid oxide fuel cells (SOFCs), as boron contaminants react with lanthanum-containing cathodes, forming LaBO3 and degrading the activity of SOFCs. Here, we report that the reaction between the volatile boron and a La0.6Sr0.4Co0.2Fe0.8O3-δ (LSCF) cathode during polarization can be significantly reduced by doping aluminoborosilicate glass with Gd2O3. Specifically, the Gd cations in glass with 2 mol.% Gd2O3 dissolve preferentially in the borate-rich environment to form more Gd-metaborate structures and promote the formation of calcium metaborate (CaB2O4); they also condense the B–O network after heat treatment, which suppresses poisoning by boron contaminants on the LSCF cathode. The results provide insights into design and development of a reliable sealing glass for SOFC applications. |
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