Impurity removal from petroleum coke

© The Minerals, Metals & Materials Society 2016. The question of treating high-impurity coke to enable use in anodes was examined. A mineralogical analysis of different cokes demonstrated that more than 99 % of the particles contained the expected concentrations of sulfur, nickel, and vanadium...

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Main Authors: Gagnon, A., Backhouse, N., Darmstadt, H., Ryan, E., Dyer, Laurence, Dixon, D.
Format: Conference Paper
Published: 2016
Online Access:http://hdl.handle.net/20.500.11937/67483
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author Gagnon, A.
Backhouse, N.
Darmstadt, H.
Ryan, E.
Dyer, Laurence
Dixon, D.
author_facet Gagnon, A.
Backhouse, N.
Darmstadt, H.
Ryan, E.
Dyer, Laurence
Dixon, D.
author_sort Gagnon, A.
building Curtin Institutional Repository
collection Online Access
description © The Minerals, Metals & Materials Society 2016. The question of treating high-impurity coke to enable use in anodes was examined. A mineralogical analysis of different cokes demonstrated that more than 99 % of the particles contained the expected concentrations of sulfur, nickel, and vanadium while a small number of particles contained inclusions of other impurities. A number of potential treatment options were identified and investigated, with thermal desulfurization being studied further. The initial sulfur concentration, residence time and calcination temperature had the highest influence. 45 % sulfur removal was achieved but with significant bulk density loss. Acceptable pilot anode quality was not achievable even with the fines fraction substituted with desulfurized material. Therefore while sulfur removal during calcining is possible, the resulting coke, even in the most promising scenario, is not suitable for anode manufacturing. At this time, an industrial process to remove sulfur and other impurities from petroleum coke is unlikely to be viable.
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spelling curtin-20.500.11937-674832018-05-18T08:06:04Z Impurity removal from petroleum coke Gagnon, A. Backhouse, N. Darmstadt, H. Ryan, E. Dyer, Laurence Dixon, D. © The Minerals, Metals & Materials Society 2016. The question of treating high-impurity coke to enable use in anodes was examined. A mineralogical analysis of different cokes demonstrated that more than 99 % of the particles contained the expected concentrations of sulfur, nickel, and vanadium while a small number of particles contained inclusions of other impurities. A number of potential treatment options were identified and investigated, with thermal desulfurization being studied further. The initial sulfur concentration, residence time and calcination temperature had the highest influence. 45 % sulfur removal was achieved but with significant bulk density loss. Acceptable pilot anode quality was not achievable even with the fines fraction substituted with desulfurized material. Therefore while sulfur removal during calcining is possible, the resulting coke, even in the most promising scenario, is not suitable for anode manufacturing. At this time, an industrial process to remove sulfur and other impurities from petroleum coke is unlikely to be viable. 2016 Conference Paper http://hdl.handle.net/20.500.11937/67483 10.1007/978-3-319-65136-1_178 restricted
spellingShingle Gagnon, A.
Backhouse, N.
Darmstadt, H.
Ryan, E.
Dyer, Laurence
Dixon, D.
Impurity removal from petroleum coke
title Impurity removal from petroleum coke
title_full Impurity removal from petroleum coke
title_fullStr Impurity removal from petroleum coke
title_full_unstemmed Impurity removal from petroleum coke
title_short Impurity removal from petroleum coke
title_sort impurity removal from petroleum coke
url http://hdl.handle.net/20.500.11937/67483