Cascade applications of robust MIL-96 metal organic frameworks in environmental remediation: Proof of concept
In this paper, we demonstrate a cascade application of functional materials in adsorption and catalysis. Metal organic frameworks, MIL-96, were synthesized by a single solvent (water), and methanol (MIL-96-Me) or ethanol (MIL-96-Et) modulated method. Methanol modulation results in a change in porous...
| Main Authors: | , , , , , |
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| Format: | Journal Article |
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Elsevier BV
2018
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| Online Access: | http://purl.org/au-research/grants/arc/DP150103026 http://hdl.handle.net/20.500.11937/67145 |
| _version_ | 1848761487146876928 |
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| author | Azhar, M. Abid, H. Tade, Moses Periasamy, V. Sun, Hongqi Wang, Shaobin |
| author_facet | Azhar, M. Abid, H. Tade, Moses Periasamy, V. Sun, Hongqi Wang, Shaobin |
| author_sort | Azhar, M. |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | In this paper, we demonstrate a cascade application of functional materials in adsorption and catalysis. Metal organic frameworks, MIL-96, were synthesized by a single solvent (water), and methanol (MIL-96-Me) or ethanol (MIL-96-Et) modulated method. Methanol modulation results in a change in porous structure and better CO 2 adsorption and selectivity. After gas-phase adsorption of CO 2 , the MIL-96 can be reused for liquid-phase removal of water contaminants, demonstrating high capacities of para-hydroxybenzoic acid (p-HBA). Then, a transformation of the used MIL-96 by pyrolysis was employed to produce a metal oxide/C composite for catalytic activation of peroxymonosulfate (PMS) to degrade an organic pollutant, methyl orange. The composite exhibited excellent performance in the dye degradation. This study presents a proof of concept of integrated utilization of robust and functional nanomaterials for multiple applications without producing solid wastes after each use. |
| first_indexed | 2025-11-14T10:32:27Z |
| format | Journal Article |
| id | curtin-20.500.11937-67145 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T10:32:27Z |
| publishDate | 2018 |
| publisher | Elsevier BV |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-671452022-10-26T07:17:55Z Cascade applications of robust MIL-96 metal organic frameworks in environmental remediation: Proof of concept Azhar, M. Abid, H. Tade, Moses Periasamy, V. Sun, Hongqi Wang, Shaobin In this paper, we demonstrate a cascade application of functional materials in adsorption and catalysis. Metal organic frameworks, MIL-96, were synthesized by a single solvent (water), and methanol (MIL-96-Me) or ethanol (MIL-96-Et) modulated method. Methanol modulation results in a change in porous structure and better CO 2 adsorption and selectivity. After gas-phase adsorption of CO 2 , the MIL-96 can be reused for liquid-phase removal of water contaminants, demonstrating high capacities of para-hydroxybenzoic acid (p-HBA). Then, a transformation of the used MIL-96 by pyrolysis was employed to produce a metal oxide/C composite for catalytic activation of peroxymonosulfate (PMS) to degrade an organic pollutant, methyl orange. The composite exhibited excellent performance in the dye degradation. This study presents a proof of concept of integrated utilization of robust and functional nanomaterials for multiple applications without producing solid wastes after each use. 2018 Journal Article http://hdl.handle.net/20.500.11937/67145 10.1016/j.cej.2018.02.030 http://purl.org/au-research/grants/arc/DP150103026 Elsevier BV restricted |
| spellingShingle | Azhar, M. Abid, H. Tade, Moses Periasamy, V. Sun, Hongqi Wang, Shaobin Cascade applications of robust MIL-96 metal organic frameworks in environmental remediation: Proof of concept |
| title | Cascade applications of robust MIL-96 metal organic frameworks in environmental remediation: Proof of concept |
| title_full | Cascade applications of robust MIL-96 metal organic frameworks in environmental remediation: Proof of concept |
| title_fullStr | Cascade applications of robust MIL-96 metal organic frameworks in environmental remediation: Proof of concept |
| title_full_unstemmed | Cascade applications of robust MIL-96 metal organic frameworks in environmental remediation: Proof of concept |
| title_short | Cascade applications of robust MIL-96 metal organic frameworks in environmental remediation: Proof of concept |
| title_sort | cascade applications of robust mil-96 metal organic frameworks in environmental remediation: proof of concept |
| url | http://purl.org/au-research/grants/arc/DP150103026 http://hdl.handle.net/20.500.11937/67145 |