Pulsed thermal treatment of carbon up to 3000 °C using an atomic absorption spectrometer

An atomic absorption spectrometer unit fitted with a graphite furnace module is used to perform high temperature treatment on three carbonized polymers: polyvinyl chloride (PVC), polyvinylidene chloride (PVDC) and polyacrylonitrile (PAN). Using short pulses up to 45 s, we heat small samples to a max...

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Main Authors: Putman, Kate, Sofianos, M., Rowles, Matthew, Harris, P., Buckley, C., Marks, Nigel, Suarez-Martinez, Irene
Format: Journal Article
Published: Pergamon 2018
Online Access:http://purl.org/au-research/grants/arc/DP150103487
http://hdl.handle.net/20.500.11937/66557
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author Putman, Kate
Sofianos, M.
Rowles, Matthew
Harris, P.
Buckley, C.
Marks, Nigel
Suarez-Martinez, Irene
author_facet Putman, Kate
Sofianos, M.
Rowles, Matthew
Harris, P.
Buckley, C.
Marks, Nigel
Suarez-Martinez, Irene
author_sort Putman, Kate
building Curtin Institutional Repository
collection Online Access
description An atomic absorption spectrometer unit fitted with a graphite furnace module is used to perform high temperature treatment on three carbonized polymers: polyvinyl chloride (PVC), polyvinylidene chloride (PVDC) and polyacrylonitrile (PAN). Using short pulses up to 45 s, we heat small samples to a maximum of 3000 °C. High-resolution transmission electron microscopy and X-ray diffractometry are used to track the growth of crystallites in the materials as a function of the heating temperature. We observe the well-known behaviour of large crystalline graphite growth in PVC-derived samples and the formation of curved graphitic layers in PVDC- and PAN-derived samples. This graphite furnace atomic absorption spectrometer approach is an attractive alternative to conventional laboratory-scale graphite furnaces in research of high temperature treatment of carbon and other refractory materials.
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format Journal Article
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institution Curtin University Malaysia
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last_indexed 2025-11-14T10:30:17Z
publishDate 2018
publisher Pergamon
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spelling curtin-20.500.11937-665572022-09-06T02:30:34Z Pulsed thermal treatment of carbon up to 3000 °C using an atomic absorption spectrometer Putman, Kate Sofianos, M. Rowles, Matthew Harris, P. Buckley, C. Marks, Nigel Suarez-Martinez, Irene An atomic absorption spectrometer unit fitted with a graphite furnace module is used to perform high temperature treatment on three carbonized polymers: polyvinyl chloride (PVC), polyvinylidene chloride (PVDC) and polyacrylonitrile (PAN). Using short pulses up to 45 s, we heat small samples to a maximum of 3000 °C. High-resolution transmission electron microscopy and X-ray diffractometry are used to track the growth of crystallites in the materials as a function of the heating temperature. We observe the well-known behaviour of large crystalline graphite growth in PVC-derived samples and the formation of curved graphitic layers in PVDC- and PAN-derived samples. This graphite furnace atomic absorption spectrometer approach is an attractive alternative to conventional laboratory-scale graphite furnaces in research of high temperature treatment of carbon and other refractory materials. 2018 Journal Article http://hdl.handle.net/20.500.11937/66557 10.1016/j.carbon.2018.03.060 http://purl.org/au-research/grants/arc/DP150103487 http://purl.org/au-research/grants/arc/FT140100191 Pergamon fulltext
spellingShingle Putman, Kate
Sofianos, M.
Rowles, Matthew
Harris, P.
Buckley, C.
Marks, Nigel
Suarez-Martinez, Irene
Pulsed thermal treatment of carbon up to 3000 °C using an atomic absorption spectrometer
title Pulsed thermal treatment of carbon up to 3000 °C using an atomic absorption spectrometer
title_full Pulsed thermal treatment of carbon up to 3000 °C using an atomic absorption spectrometer
title_fullStr Pulsed thermal treatment of carbon up to 3000 °C using an atomic absorption spectrometer
title_full_unstemmed Pulsed thermal treatment of carbon up to 3000 °C using an atomic absorption spectrometer
title_short Pulsed thermal treatment of carbon up to 3000 °C using an atomic absorption spectrometer
title_sort pulsed thermal treatment of carbon up to 3000 °c using an atomic absorption spectrometer
url http://purl.org/au-research/grants/arc/DP150103487
http://purl.org/au-research/grants/arc/DP150103487
http://hdl.handle.net/20.500.11937/66557