Electrochemical and Electrostatic Cleavage of Alkoxyamines
© 2017 American Chemical Society. Alkoxyamines are heat-labile molecules, widely used as an in situ source of nitroxides in polymer and materials sciences. Here we show that the one-electron oxidation of an alkoxyamine leads to a cation radical intermediate that even at room temperature rapidly frag...
| Main Authors: | Zhang, L., Laborda, E., Darwish, Nadim, Noble, B., Tyrell, J., Pluczyk, S., Le Brun, A., Wallace, G., Gonzalez, J., Coote, M., Ciampi, Simone |
|---|---|
| Format: | Journal Article |
| Published: |
American Chemical Society
2018
|
| Online Access: | http://purl.org/au-research/grants/arc/DE160100732 http://hdl.handle.net/20.500.11937/65431 |
Similar Items
Effect of Chemical Structure on the Electrochemical Cleavage of Alkoxyamines
by: Hammill, C.L., et al.
Published: (2019)
by: Hammill, C.L., et al.
Published: (2019)
Mechanism of Oxidative Alkoxyamine Cleavage: The Surprising Role of the Solvent and Supporting Electrolyte
by: Noble, B.B., et al.
Published: (2019)
by: Noble, B.B., et al.
Published: (2019)
Reproducible flaws unveil electrostatic aspects of semiconductor electrochemistry
by: Vogel, Y., et al.
Published: (2017)
by: Vogel, Y., et al.
Published: (2017)
Harnessing electrostatic catalysis in single molecule, electrochemical and chemical systems: a rapidly growing experimental tool box.
by: Ciampi, S., et al.
Published: (2018)
by: Ciampi, S., et al.
Published: (2018)
TEMPO Monolayers on Si(100) Electrodes: Electrostatic Effects by the Electrolyte and Semiconductor Space-Charge on the Electroactivity of a Persistent Radical.
by: Zhang, L., et al.
Published: (2016)
by: Zhang, L., et al.
Published: (2016)
Electrostatic catalysis of a Diels-Alder reaction
by: Aragonès, A., et al.
Published: (2016)
by: Aragonès, A., et al.
Published: (2016)
Electrostatics and Electrochemistry: Mechanism and Scope of Charge-Transfer Reactions on the Surface of Tribocharged Insulators
by: Zhang, J., et al.
Published: (2021)
by: Zhang, J., et al.
Published: (2021)
Switchable Interfaces: Redox Monolayers on Si(100) by Electrochemical Trapping of Alcohol Nucleophiles
by: Zhang, L., et al.
Published: (2018)
by: Zhang, L., et al.
Published: (2018)
Electrostatic Regulation of TEMPO Oxidation by Distal Molecular Charges
by: Zhang, L., et al.
Published: (2020)
by: Zhang, L., et al.
Published: (2020)
Spontaneous Grafting of OH-Terminated Molecules on Si−H Surfaces via Si–O–C Covalent Bonding
by: Dief, Essam, et al.
Published: (2021)
by: Dief, Essam, et al.
Published: (2021)
Static Electrification of Plastics under Friction: The Position of Engineering-Grade Polyethylene Terephthalate in the Triboelectric Series
by: Zhang, Jinyang, et al.
Published: (2020)
by: Zhang, Jinyang, et al.
Published: (2020)
The detailed characterization of electrochemically switchable molecular assemblies on silicon electrodes
by: Ciampi, S., et al.
Published: (2013)
by: Ciampi, S., et al.
Published: (2013)
Electrochemically Generated Luminescence of Luminol and Luciferin in Ionic Liquids
by: Belotti, Mattia, et al.
Published: (2023)
by: Belotti, Mattia, et al.
Published: (2023)
The rise of self-assembled monolayers for fabricating electrochemical biosensors-an interfacial perspective
by: Gooding, J., et al.
Published: (2012)
by: Gooding, J., et al.
Published: (2012)
Schottky Diode Leakage Current Fluctuations: Electrostatically Induced Flexoelectricity in Silicon
by: Hurtado, C., et al.
Published: (2024)
by: Hurtado, C., et al.
Published: (2024)
Electrochemical behavior of gold colloidal alkyl modified silicon surfaces
by: Le Saux, G., et al.
Published: (2009)
by: Le Saux, G., et al.
Published: (2009)
Absence of a Relationship between Surface Conductivity and Electrochemical Rates: Redox-Active Monolayers on Si(211), Si(111), and Si(110)
by: Zhang, Song, et al.
Published: (2021)
by: Zhang, Song, et al.
Published: (2021)
Irreproducibility in the triboelectric charging of insulators: evidence of a non-monotonic charge versus contact time relationship.
by: Zhang, Jinyang, et al.
Published: (2020)
by: Zhang, Jinyang, et al.
Published: (2020)
Electrochemical Microscopy Based on Spatial Light Modulators: A Projection System to Spatially Address Electrochemical Reactions at Semiconductors
by: Ciampi, Simone
Published: (2018)
by: Ciampi, Simone
Published: (2018)
Harnessing silicon facet-dependent conductivity to enhance the direct-current produced by a sliding Schottky diode triboelectric nanogenerator
by: Ferrie, S., et al.
Published: (2020)
by: Ferrie, S., et al.
Published: (2020)
Spatiotemporal Control of Electrochemiluminescence Guided by a Visible Light Stimulus
by: Vogel, Yan, et al.
Published: (2020)
by: Vogel, Yan, et al.
Published: (2020)
Switching of Current Rectification Ratios within a Single Nanocrystal by Facet-Resolved Electrical Wiring
by: Vogel, Yan, et al.
Published: (2018)
by: Vogel, Yan, et al.
Published: (2018)
Decoloration rates of a photomerocyanine dye as a visual probe into hydrogen bonding interactions
by: Ciampi, S., et al.
Published: (2015)
by: Ciampi, S., et al.
Published: (2015)
The impact of surface coverage on the kinetics of electron transfer through redox monolayers on a silicon electrode surface
by: Ciampi, S., et al.
Published: (2015)
by: Ciampi, S., et al.
Published: (2015)
Electrochemical "switching" of Si(100) modular assemblies
by: Ciampi, Simone, et al.
Published: (2012)
by: Ciampi, Simone, et al.
Published: (2012)
The impact of surface coverage on the kinetics of electron transfer through redox monolayers on a silicon electrode surface
by: Ciampi, Simone, et al.
Published: (2015)
by: Ciampi, Simone, et al.
Published: (2015)
Electrostatics and metal oxide wettability
by: Hanly, G., et al.
Published: (2011)
by: Hanly, G., et al.
Published: (2011)
The corona of a surface bubble promotes electrochemical reactions
by: Vogel, Yan, et al.
Published: (2020)
by: Vogel, Yan, et al.
Published: (2020)
A multimodal optical and electrochemical device for monitoring surface reactions: Redox active surfaces in porous silicon Rugate filters
by: Ciampi, S., et al.
Published: (2012)
by: Ciampi, S., et al.
Published: (2012)
Metal-Single-Molecule-Semiconductor Junctions Formed by a Radical Reaction Bridging Gold and Silicon Electrodes.
by: Peiris, Chandramalika R, et al.
Published: (2019)
by: Peiris, Chandramalika R, et al.
Published: (2019)
The decline of cleavage politics in Australia revisited
by: Charnock, David
Published: (2003)
by: Charnock, David
Published: (2003)
Non-Ideal Cyclic Voltammetry of Redox Monolayers on Silicon Electrodes: Peak Splitting is Caused by Heterogeneous Photocurrents and Not by Molecular Disorder
by: Zhang, S., et al.
Published: (2022)
by: Zhang, S., et al.
Published: (2022)
Spontaneous S-Si bonding of alkanethiols to Si(111)-H: Towards Si-molecule-Si circuits
by: Peiris, Chandramalika, et al.
Published: (2020)
by: Peiris, Chandramalika, et al.
Published: (2020)
Hydrogen evolution during the electrodeposition of gold nanoparticles at Si(100) photoelectrodes impairs the analysis of current-time transients
by: Vogel, Yan, et al.
Published: (2017)
by: Vogel, Yan, et al.
Published: (2017)
Target DNA recognition using electrochemical impedance spectroscopy
by: Michaels, P., et al.
Published: (2010)
by: Michaels, P., et al.
Published: (2010)
Covalent Linkages of Molecules and Proteins to Si-H Surfaces Formed by Disulfide Reduction
by: Dief, Essam, et al.
Published: (2020)
by: Dief, Essam, et al.
Published: (2020)
Direct-current output of silicon–organic monolayer–platinum Schottky TENGs: Elusive friction-output relationship
by: Lyu, Xin, et al.
Published: (2023)
by: Lyu, Xin, et al.
Published: (2023)
Electrostatic phase separation: a review
by: Mhatre, S., et al.
Published: (2015)
by: Mhatre, S., et al.
Published: (2015)
Pre-Lightning Strikes and Aircraft Electrostatics
by: Fisher, J., et al.
Published: (2017)
by: Fisher, J., et al.
Published: (2017)
Development of an electrostatically assisted solvent extraction column
by: Steffens, Marc J.
Published: (2011)
by: Steffens, Marc J.
Published: (2011)
Similar Items
-
Effect of Chemical Structure on the Electrochemical Cleavage of Alkoxyamines
by: Hammill, C.L., et al.
Published: (2019) -
Mechanism of Oxidative Alkoxyamine Cleavage: The Surprising Role of the Solvent and Supporting Electrolyte
by: Noble, B.B., et al.
Published: (2019) -
Reproducible flaws unveil electrostatic aspects of semiconductor electrochemistry
by: Vogel, Y., et al.
Published: (2017) -
Harnessing electrostatic catalysis in single molecule, electrochemical and chemical systems: a rapidly growing experimental tool box.
by: Ciampi, S., et al.
Published: (2018) -
TEMPO Monolayers on Si(100) Electrodes: Electrostatic Effects by the Electrolyte and Semiconductor Space-Charge on the Electroactivity of a Persistent Radical.
by: Zhang, L., et al.
Published: (2016)