Contamination of silica surfaces: impact on water-CO2-quartz and glass contact angle measurements

CO2-wettability of sandstones is a key variable which determines structural and residual trapping capacities and strongly influences multi-phase fluid dynamics in the rock. An increasing number of researchers has now estimated this wettability by conducting contact angle measurements on quartz, howe...

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Main Authors: Iglauer, Stefan, Salamah, Abdulsalam, Sarmadivaleh, Mohammad, Liu, Keyu, Phan, Chi
Format: Journal Article
Published: Elsevier 2014
Subjects:
Online Access:http://hdl.handle.net/20.500.11937/6501
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author Iglauer, Stefan
Salamah, Abdulsalam
Sarmadivaleh, Mohammad
Liu, Keyu
Phan, Chi
author_facet Iglauer, Stefan
Salamah, Abdulsalam
Sarmadivaleh, Mohammad
Liu, Keyu
Phan, Chi
author_sort Iglauer, Stefan
building Curtin Institutional Repository
collection Online Access
description CO2-wettability of sandstones is a key variable which determines structural and residual trapping capacities and strongly influences multi-phase fluid dynamics in the rock. An increasing number of researchers has now estimated this wettability by conducting contact angle measurements on quartz, however, there is a large uncertainty associated with the reported data. We demonstrate clearly that the main factor which leads to this broad data spread is due to surface contamination. It is clear that typically inappropriate cleaning methods were used which resulted in artificially high contact angle measurements. We used surface cleaning methods typically prescribed in the surface chemistry community and found that the water contact angle θ on a clean quartz substrate is low, 0–30°, and that θ increases with pressure. We conclude that quartz is strongly water-wet at high pressure conditions.
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institution Curtin University Malaysia
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publishDate 2014
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spelling curtin-20.500.11937-65012019-02-19T04:26:59Z Contamination of silica surfaces: impact on water-CO2-quartz and glass contact angle measurements Iglauer, Stefan Salamah, Abdulsalam Sarmadivaleh, Mohammad Liu, Keyu Phan, Chi CO2 wettability contact angle surface contamination CO2-wettability of sandstones is a key variable which determines structural and residual trapping capacities and strongly influences multi-phase fluid dynamics in the rock. An increasing number of researchers has now estimated this wettability by conducting contact angle measurements on quartz, however, there is a large uncertainty associated with the reported data. We demonstrate clearly that the main factor which leads to this broad data spread is due to surface contamination. It is clear that typically inappropriate cleaning methods were used which resulted in artificially high contact angle measurements. We used surface cleaning methods typically prescribed in the surface chemistry community and found that the water contact angle θ on a clean quartz substrate is low, 0–30°, and that θ increases with pressure. We conclude that quartz is strongly water-wet at high pressure conditions. 2014 Journal Article http://hdl.handle.net/20.500.11937/6501 Elsevier fulltext
spellingShingle CO2 wettability
contact angle
surface contamination
Iglauer, Stefan
Salamah, Abdulsalam
Sarmadivaleh, Mohammad
Liu, Keyu
Phan, Chi
Contamination of silica surfaces: impact on water-CO2-quartz and glass contact angle measurements
title Contamination of silica surfaces: impact on water-CO2-quartz and glass contact angle measurements
title_full Contamination of silica surfaces: impact on water-CO2-quartz and glass contact angle measurements
title_fullStr Contamination of silica surfaces: impact on water-CO2-quartz and glass contact angle measurements
title_full_unstemmed Contamination of silica surfaces: impact on water-CO2-quartz and glass contact angle measurements
title_short Contamination of silica surfaces: impact on water-CO2-quartz and glass contact angle measurements
title_sort contamination of silica surfaces: impact on water-co2-quartz and glass contact angle measurements
topic CO2 wettability
contact angle
surface contamination
url http://hdl.handle.net/20.500.11937/6501