Facile low-temperature polyol process for LiFePO4 nanoplate and carbon nanotube composite

Crystalline LiFePO4 nanoplates were incorporated with 5 wt.% multi-walled carbon nanotubes (CNTs) via a facile low temperature polyol process, in one single step without any post heat treatment. The CNTs were embedded into the LiFePO4 particles to form a network to enhance the electrochemical perfor...

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Main Authors: Wu, G., Zhou, Y., Gao, X., Shao, Zongping
Format: Journal Article
Published: Elsevier 2013
Subjects:
Online Access:http://hdl.handle.net/20.500.11937/6441
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author Wu, G.
Zhou, Y.
Gao, X.
Shao, Zongping
author_facet Wu, G.
Zhou, Y.
Gao, X.
Shao, Zongping
author_sort Wu, G.
building Curtin Institutional Repository
collection Online Access
description Crystalline LiFePO4 nanoplates were incorporated with 5 wt.% multi-walled carbon nanotubes (CNTs) via a facile low temperature polyol process, in one single step without any post heat treatment. The CNTs were embedded into the LiFePO4 particles to form a network to enhance the electrochemical performance of LiFePO4 electrode for lithium-ion battery applications. The structural and morphological characters of the LiFePO4-CNT composites were investigated by X-ray diffraction, Fourier Transform infrared spectroscopy, Raman spectroscopy, scanning electron microscopy and transmission electron microscopy. The electrochemical properties were analyzed by cyclic voltammetry, electrochemical impedance spectroscopy and charge/discharge tests. Primary results showed that well crystallized olivine-type structure without any impurity phases was developed, and the LiFePO4-CNT composites exhibited good electrochemical performance, with a reversible specific capacity of 155 mAh g-1 at the current rate of 10 mA g-1, and a capacity retention ratio close to 100% after 100 cycles.
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institution Curtin University Malaysia
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publishDate 2013
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spelling curtin-20.500.11937-64412017-02-28T01:30:44Z Facile low-temperature polyol process for LiFePO4 nanoplate and carbon nanotube composite Wu, G. Zhou, Y. Gao, X. Shao, Zongping Lithium-ion battery Polyol process Carbon nanotube Lithium iron phosphate Crystalline LiFePO4 nanoplates were incorporated with 5 wt.% multi-walled carbon nanotubes (CNTs) via a facile low temperature polyol process, in one single step without any post heat treatment. The CNTs were embedded into the LiFePO4 particles to form a network to enhance the electrochemical performance of LiFePO4 electrode for lithium-ion battery applications. The structural and morphological characters of the LiFePO4-CNT composites were investigated by X-ray diffraction, Fourier Transform infrared spectroscopy, Raman spectroscopy, scanning electron microscopy and transmission electron microscopy. The electrochemical properties were analyzed by cyclic voltammetry, electrochemical impedance spectroscopy and charge/discharge tests. Primary results showed that well crystallized olivine-type structure without any impurity phases was developed, and the LiFePO4-CNT composites exhibited good electrochemical performance, with a reversible specific capacity of 155 mAh g-1 at the current rate of 10 mA g-1, and a capacity retention ratio close to 100% after 100 cycles. 2013 Journal Article http://hdl.handle.net/20.500.11937/6441 Elsevier restricted
spellingShingle Lithium-ion battery
Polyol process
Carbon nanotube
Lithium iron phosphate
Wu, G.
Zhou, Y.
Gao, X.
Shao, Zongping
Facile low-temperature polyol process for LiFePO4 nanoplate and carbon nanotube composite
title Facile low-temperature polyol process for LiFePO4 nanoplate and carbon nanotube composite
title_full Facile low-temperature polyol process for LiFePO4 nanoplate and carbon nanotube composite
title_fullStr Facile low-temperature polyol process for LiFePO4 nanoplate and carbon nanotube composite
title_full_unstemmed Facile low-temperature polyol process for LiFePO4 nanoplate and carbon nanotube composite
title_short Facile low-temperature polyol process for LiFePO4 nanoplate and carbon nanotube composite
title_sort facile low-temperature polyol process for lifepo4 nanoplate and carbon nanotube composite
topic Lithium-ion battery
Polyol process
Carbon nanotube
Lithium iron phosphate
url http://hdl.handle.net/20.500.11937/6441