Enhanced emissions in Tb3+-doped oxyfluoride scintillating glass ceramics containing BaF2 nanocrystals

Transparent Tb3+-doped glass ceramics containing BaF2 nanocrystals were prepared by melt-quenching method with subsequent heat treatment. The XRD and EDS results showed the precipitated crystalline phase in the glass matrix was BaF2. Under 376 nm light, Tb3+ doped oxyfluoride glass ceramics containi...

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Main Authors: Huang, L., Jia, S., Li, Y., Zhao, S., Deng, D., Wang, H., Jia, Guohua, Hua, Y., Xu, S.
Format: Journal Article
Published: Elsevier 2015
Online Access:http://hdl.handle.net/20.500.11937/62722
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author Huang, L.
Jia, S.
Li, Y.
Zhao, S.
Deng, D.
Wang, H.
Jia, Guohua
Hua, Y.
Xu, S.
author_facet Huang, L.
Jia, S.
Li, Y.
Zhao, S.
Deng, D.
Wang, H.
Jia, Guohua
Hua, Y.
Xu, S.
author_sort Huang, L.
building Curtin Institutional Repository
collection Online Access
description Transparent Tb3+-doped glass ceramics containing BaF2 nanocrystals were prepared by melt-quenching method with subsequent heat treatment. The XRD and EDS results showed the precipitated crystalline phase in the glass matrix was BaF2. Under 376 nm light, Tb3+ doped oxyfluoride glass ceramics containing BaF2 nanocrystals showed more intense green emission than the as-made glass, and the emission intensity increased with increasing heat treatment temperature and time. The lifetimes of 541 nm emission of Tb3+ doped oxyfluoride glass ceramics were longer than that of as-made glass, which are in the range from 3.00 ms to 3.55 ms. Under X-ray excitation, the green emission was enhanced in the glass ceramics compared to the as-made glass. The results indicate Tb3+ doped oxyfluoride glass ceramics containing BaF2 nanocrystals could be a material candidate for X-ray glass scintillator for slow event detection.
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institution Curtin University Malaysia
institution_category Local University
last_indexed 2025-11-14T10:23:10Z
publishDate 2015
publisher Elsevier
recordtype eprints
repository_type Digital Repository
spelling curtin-20.500.11937-627222018-04-19T04:08:36Z Enhanced emissions in Tb3+-doped oxyfluoride scintillating glass ceramics containing BaF2 nanocrystals Huang, L. Jia, S. Li, Y. Zhao, S. Deng, D. Wang, H. Jia, Guohua Hua, Y. Xu, S. Transparent Tb3+-doped glass ceramics containing BaF2 nanocrystals were prepared by melt-quenching method with subsequent heat treatment. The XRD and EDS results showed the precipitated crystalline phase in the glass matrix was BaF2. Under 376 nm light, Tb3+ doped oxyfluoride glass ceramics containing BaF2 nanocrystals showed more intense green emission than the as-made glass, and the emission intensity increased with increasing heat treatment temperature and time. The lifetimes of 541 nm emission of Tb3+ doped oxyfluoride glass ceramics were longer than that of as-made glass, which are in the range from 3.00 ms to 3.55 ms. Under X-ray excitation, the green emission was enhanced in the glass ceramics compared to the as-made glass. The results indicate Tb3+ doped oxyfluoride glass ceramics containing BaF2 nanocrystals could be a material candidate for X-ray glass scintillator for slow event detection. 2015 Journal Article http://hdl.handle.net/20.500.11937/62722 10.1016/j.nima.2015.03.084 Elsevier restricted
spellingShingle Huang, L.
Jia, S.
Li, Y.
Zhao, S.
Deng, D.
Wang, H.
Jia, Guohua
Hua, Y.
Xu, S.
Enhanced emissions in Tb3+-doped oxyfluoride scintillating glass ceramics containing BaF2 nanocrystals
title Enhanced emissions in Tb3+-doped oxyfluoride scintillating glass ceramics containing BaF2 nanocrystals
title_full Enhanced emissions in Tb3+-doped oxyfluoride scintillating glass ceramics containing BaF2 nanocrystals
title_fullStr Enhanced emissions in Tb3+-doped oxyfluoride scintillating glass ceramics containing BaF2 nanocrystals
title_full_unstemmed Enhanced emissions in Tb3+-doped oxyfluoride scintillating glass ceramics containing BaF2 nanocrystals
title_short Enhanced emissions in Tb3+-doped oxyfluoride scintillating glass ceramics containing BaF2 nanocrystals
title_sort enhanced emissions in tb3+-doped oxyfluoride scintillating glass ceramics containing baf2 nanocrystals
url http://hdl.handle.net/20.500.11937/62722