An Exploratory Investigation of the Photophysical and Photochemical Properties of Rhenium(I) N-Heterocyclic Carbene Tricarbonyl Complexes
Functionalised N-heterocyclic carbene (NHC) ligands were synthesised, characterised and coordinated to a rhenium metal centre. The resulting rhenium(I) NHC tricarbonyl complexes were emissive when irradiated with UV light. These photophysical properties were analysed and quantified. During this anal...
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| Format: | Thesis |
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Curtin University
2017
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| Online Access: | http://hdl.handle.net/20.500.11937/59646 |
| _version_ | 1848760531362512896 |
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| author | Vaughan, Jamila Glorian |
| author_facet | Vaughan, Jamila Glorian |
| author_sort | Vaughan, Jamila Glorian |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | Functionalised N-heterocyclic carbene (NHC) ligands were synthesised, characterised and coordinated to a rhenium metal centre. The resulting rhenium(I) NHC tricarbonyl complexes were emissive when irradiated with UV light. These photophysical properties were analysed and quantified. During this analysis it was noted that some of the complexes exhibited photochemically activated ligand substitution reactions dependent of the functionality of the ligand. The unique mechanism of these reactions was investigated using synthetic and spectroscopic techniques. |
| first_indexed | 2025-11-14T10:17:15Z |
| format | Thesis |
| id | curtin-20.500.11937-59646 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T10:17:15Z |
| publishDate | 2017 |
| publisher | Curtin University |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-596462017-12-18T02:40:47Z An Exploratory Investigation of the Photophysical and Photochemical Properties of Rhenium(I) N-Heterocyclic Carbene Tricarbonyl Complexes Vaughan, Jamila Glorian Functionalised N-heterocyclic carbene (NHC) ligands were synthesised, characterised and coordinated to a rhenium metal centre. The resulting rhenium(I) NHC tricarbonyl complexes were emissive when irradiated with UV light. These photophysical properties were analysed and quantified. During this analysis it was noted that some of the complexes exhibited photochemically activated ligand substitution reactions dependent of the functionality of the ligand. The unique mechanism of these reactions was investigated using synthetic and spectroscopic techniques. 2017 Thesis http://hdl.handle.net/20.500.11937/59646 Curtin University fulltext |
| spellingShingle | Vaughan, Jamila Glorian An Exploratory Investigation of the Photophysical and Photochemical Properties of Rhenium(I) N-Heterocyclic Carbene Tricarbonyl Complexes |
| title | An Exploratory Investigation of the Photophysical and Photochemical Properties of Rhenium(I) N-Heterocyclic Carbene Tricarbonyl Complexes |
| title_full | An Exploratory Investigation of the Photophysical and Photochemical Properties of Rhenium(I) N-Heterocyclic Carbene Tricarbonyl Complexes |
| title_fullStr | An Exploratory Investigation of the Photophysical and Photochemical Properties of Rhenium(I) N-Heterocyclic Carbene Tricarbonyl Complexes |
| title_full_unstemmed | An Exploratory Investigation of the Photophysical and Photochemical Properties of Rhenium(I) N-Heterocyclic Carbene Tricarbonyl Complexes |
| title_short | An Exploratory Investigation of the Photophysical and Photochemical Properties of Rhenium(I) N-Heterocyclic Carbene Tricarbonyl Complexes |
| title_sort | exploratory investigation of the photophysical and photochemical properties of rhenium(i) n-heterocyclic carbene tricarbonyl complexes |
| url | http://hdl.handle.net/20.500.11937/59646 |