Efficient separation scheme for binary mixture of CO2 and H2S using aromatic components

Separating a mixture of CO 2 and H 2 S into two products through distillation is both difficult and complicated because of similar relative volatility between the two gasses, particularly when a CO 2 concentration exceeds 80%. Therefore, the separation process can involve many separating stages. H...

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Main Authors: Alnili, F., Barifcani, Ahmed
Format: Journal Article
Published: Taylor & Francis Inc. 2017
Online Access:http://hdl.handle.net/20.500.11937/59347
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author Alnili, F.
Barifcani, Ahmed
author_facet Alnili, F.
Barifcani, Ahmed
author_sort Alnili, F.
building Curtin Institutional Repository
collection Online Access
description Separating a mixture of CO 2 and H 2 S into two products through distillation is both difficult and complicated because of similar relative volatility between the two gasses, particularly when a CO 2 concentration exceeds 80%. Therefore, the separation process can involve many separating stages. However, adding a solvent (agent) to the distillation column during the separation process makes this procedure easier. In this study, different solvents (ethylbenzene, o-xylene, m-xylene, and toluene) and operating conditions (temperature, pressure, and reflux ratio) for separating CO 2 from H 2 S have been simulated through distillation using Aspen HYSYS software. Furthermore, four different aromatic compounds (solvents) for different concentrations (from 0 to 40 mol%) have been evaluated to increase the CO 2 /H 2 S relative volatility, reducing the quantity of the solvent required and energy consumption. m-xylene was found to be the best solvent for separating CO 2 from H 2 S because of the significant effect on relative volatility, the low quantity required for high CO 2 recovery, and the low energy for generating the solvent.
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spelling curtin-20.500.11937-593472018-10-03T05:13:14Z Efficient separation scheme for binary mixture of CO2 and H2S using aromatic components Alnili, F. Barifcani, Ahmed Separating a mixture of CO 2 and H 2 S into two products through distillation is both difficult and complicated because of similar relative volatility between the two gasses, particularly when a CO 2 concentration exceeds 80%. Therefore, the separation process can involve many separating stages. However, adding a solvent (agent) to the distillation column during the separation process makes this procedure easier. In this study, different solvents (ethylbenzene, o-xylene, m-xylene, and toluene) and operating conditions (temperature, pressure, and reflux ratio) for separating CO 2 from H 2 S have been simulated through distillation using Aspen HYSYS software. Furthermore, four different aromatic compounds (solvents) for different concentrations (from 0 to 40 mol%) have been evaluated to increase the CO 2 /H 2 S relative volatility, reducing the quantity of the solvent required and energy consumption. m-xylene was found to be the best solvent for separating CO 2 from H 2 S because of the significant effect on relative volatility, the low quantity required for high CO 2 recovery, and the low energy for generating the solvent. 2017 Journal Article http://hdl.handle.net/20.500.11937/59347 10.1080/01496395.2017.1377243 Taylor & Francis Inc. fulltext
spellingShingle Alnili, F.
Barifcani, Ahmed
Efficient separation scheme for binary mixture of CO2 and H2S using aromatic components
title Efficient separation scheme for binary mixture of CO2 and H2S using aromatic components
title_full Efficient separation scheme for binary mixture of CO2 and H2S using aromatic components
title_fullStr Efficient separation scheme for binary mixture of CO2 and H2S using aromatic components
title_full_unstemmed Efficient separation scheme for binary mixture of CO2 and H2S using aromatic components
title_short Efficient separation scheme for binary mixture of CO2 and H2S using aromatic components
title_sort efficient separation scheme for binary mixture of co2 and h2s using aromatic components
url http://hdl.handle.net/20.500.11937/59347