Using absorbance as a measure of turbidity in highly caustic solutions

This note shows that the dissolution of kaolin and its subsequent re-crystallization as DSP can be monitored using a simple UV–vis method that measures the turbidity of the system. The method is shown to be accurate, reproducible and sensitive. The dissolution of kaolin can be accurately determined...

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Main Authors: Radomirovic, Tomoko, Smith, P., Jones, Franca
Format: Journal Article
Published: Elsevier 2013
Subjects:
Online Access:http://hdl.handle.net/20.500.11937/5896
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author Radomirovic, Tomoko
Smith, P.
Jones, Franca
author_facet Radomirovic, Tomoko
Smith, P.
Jones, Franca
author_sort Radomirovic, Tomoko
building Curtin Institutional Repository
collection Online Access
description This note shows that the dissolution of kaolin and its subsequent re-crystallization as DSP can be monitored using a simple UV–vis method that measures the turbidity of the system. The method is shown to be accurate, reproducible and sensitive. The dissolution of kaolin can be accurately determined by way of a solids calibration curve and this is supported by simultaneous measurements of the dissolved silicate by an inductively coupled plasma (ICP) technique. Additionally, turbidity is often used to measure induction times of nucleation thus the method can monitor dissolution and nucleation simultaneously. It must be remembered, however, that turbidity will show different behaviour to ICP when phenomena such as settling and aggregation occur thus these processes must be considered when interpreting data. Finally, the size limit of the turbidimetric technique must be determined as this, too, can influence the interpretation of data.
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institution Curtin University Malaysia
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publishDate 2013
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spelling curtin-20.500.11937-58962017-09-13T14:40:29Z Using absorbance as a measure of turbidity in highly caustic solutions Radomirovic, Tomoko Smith, P. Jones, Franca Desilication products Bayer crystallization dissolution kaolin This note shows that the dissolution of kaolin and its subsequent re-crystallization as DSP can be monitored using a simple UV–vis method that measures the turbidity of the system. The method is shown to be accurate, reproducible and sensitive. The dissolution of kaolin can be accurately determined by way of a solids calibration curve and this is supported by simultaneous measurements of the dissolved silicate by an inductively coupled plasma (ICP) technique. Additionally, turbidity is often used to measure induction times of nucleation thus the method can monitor dissolution and nucleation simultaneously. It must be remembered, however, that turbidity will show different behaviour to ICP when phenomena such as settling and aggregation occur thus these processes must be considered when interpreting data. Finally, the size limit of the turbidimetric technique must be determined as this, too, can influence the interpretation of data. 2013 Journal Article http://hdl.handle.net/20.500.11937/5896 10.1016/j.minpro.2012.11.005 Elsevier fulltext
spellingShingle Desilication products
Bayer
crystallization
dissolution
kaolin
Radomirovic, Tomoko
Smith, P.
Jones, Franca
Using absorbance as a measure of turbidity in highly caustic solutions
title Using absorbance as a measure of turbidity in highly caustic solutions
title_full Using absorbance as a measure of turbidity in highly caustic solutions
title_fullStr Using absorbance as a measure of turbidity in highly caustic solutions
title_full_unstemmed Using absorbance as a measure of turbidity in highly caustic solutions
title_short Using absorbance as a measure of turbidity in highly caustic solutions
title_sort using absorbance as a measure of turbidity in highly caustic solutions
topic Desilication products
Bayer
crystallization
dissolution
kaolin
url http://hdl.handle.net/20.500.11937/5896