Removal of arsenic from gold processing circuits by use of novel magnetic nanoparticles

© 2017 Canadian Institute of Mining, Metallurgy and Petroleum Arsenic adversely affects gold mining operations by interfering with the extraction of gold, as well as posing a significant health and environmental hazard. While a number of technologies are available for removing arsenic, none of them...

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Main Authors: Feng, C., Aldrich, C., Eksteen, J., Arrigan, Damien
Format: Journal Article
Published: Maney Publishing 2017
Online Access:http://hdl.handle.net/20.500.11937/57913
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author Feng, C.
Aldrich, C.
Eksteen, J.
Arrigan, Damien
author_facet Feng, C.
Aldrich, C.
Eksteen, J.
Arrigan, Damien
author_sort Feng, C.
building Curtin Institutional Repository
collection Online Access
description © 2017 Canadian Institute of Mining, Metallurgy and Petroleum Arsenic adversely affects gold mining operations by interfering with the extraction of gold, as well as posing a significant health and environmental hazard. While a number of technologies are available for removing arsenic, none of them is effective under all conditions. Although adsorption is a promising approach, most methods focus on the purification of water under neutral or acidic conditions and tend to be less effective in gold mining process waters, operating under highly alkaline conditions. In this study, the removal of As(III) and As(V) from both arsenic-only solutions and simulated process waters using composite magnetic nanoparticles was investigated. The nanoparticles consisted of magnetite (Fe 3 O 4 ) or maghemite (?-Fe 2 O 3 ) cores covered by various metal oxides with Langmuir adsorption capacities of As(III) and As(V) ranging from 31.4 to 79.1 mg g -1 and 10.2 to 25.5 mg g -1 , respectively, in arsenic-only solutions at pH 9. The adsorption capacities were further characterised by adsorption tests conducted in simulated process waters. The ability to remove As(III) is of particular importance as it is harder to remove it from alkaline solutions than As(V). The magnetic cores allow simple and efficient magnetic recovery of the As-loaded nanoparticles.
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institution Curtin University Malaysia
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spelling curtin-20.500.11937-579132017-11-20T08:58:25Z Removal of arsenic from gold processing circuits by use of novel magnetic nanoparticles Feng, C. Aldrich, C. Eksteen, J. Arrigan, Damien © 2017 Canadian Institute of Mining, Metallurgy and Petroleum Arsenic adversely affects gold mining operations by interfering with the extraction of gold, as well as posing a significant health and environmental hazard. While a number of technologies are available for removing arsenic, none of them is effective under all conditions. Although adsorption is a promising approach, most methods focus on the purification of water under neutral or acidic conditions and tend to be less effective in gold mining process waters, operating under highly alkaline conditions. In this study, the removal of As(III) and As(V) from both arsenic-only solutions and simulated process waters using composite magnetic nanoparticles was investigated. The nanoparticles consisted of magnetite (Fe 3 O 4 ) or maghemite (?-Fe 2 O 3 ) cores covered by various metal oxides with Langmuir adsorption capacities of As(III) and As(V) ranging from 31.4 to 79.1 mg g -1 and 10.2 to 25.5 mg g -1 , respectively, in arsenic-only solutions at pH 9. The adsorption capacities were further characterised by adsorption tests conducted in simulated process waters. The ability to remove As(III) is of particular importance as it is harder to remove it from alkaline solutions than As(V). The magnetic cores allow simple and efficient magnetic recovery of the As-loaded nanoparticles. 2017 Journal Article http://hdl.handle.net/20.500.11937/57913 10.1080/00084433.2017.1391737 Maney Publishing restricted
spellingShingle Feng, C.
Aldrich, C.
Eksteen, J.
Arrigan, Damien
Removal of arsenic from gold processing circuits by use of novel magnetic nanoparticles
title Removal of arsenic from gold processing circuits by use of novel magnetic nanoparticles
title_full Removal of arsenic from gold processing circuits by use of novel magnetic nanoparticles
title_fullStr Removal of arsenic from gold processing circuits by use of novel magnetic nanoparticles
title_full_unstemmed Removal of arsenic from gold processing circuits by use of novel magnetic nanoparticles
title_short Removal of arsenic from gold processing circuits by use of novel magnetic nanoparticles
title_sort removal of arsenic from gold processing circuits by use of novel magnetic nanoparticles
url http://hdl.handle.net/20.500.11937/57913