Mechanical stretching-induced electron transfer reactions and conductance switching in single molecules

QR Code

Mechanical stretching-induced electron transfer reactions and conductance switching in single molecules

A central idea in electron-transfer theories is the coupling of the electronic state of a molecule to its structure. Here we show experimentally that fine changes to molecular structures by mechanically stretching a single metal complex molecule via changing the metal–ligand bond length can shift it...

Full description

Bibliographic Details
Main Authors:	Li, Y., Haworth, N., Xiang, L., Ciampi, Simone, Coote, M., Tao, N.
Format:	Journal Article
Published:	American Chemical Society 2017
Online Access:	https://openresearch-repository.anu.edu.au/handle/1885/209115 http://hdl.handle.net/20.500.11937/57287

Similar Items

Mechanical stretching-induced electron transfer reactions and conductance switching in single molecules
by: Tao, N.J., et al.
Published: (2018)

Multi-responsive photo- and chemo-electrical single-molecule switches
by: Darwish, Nadim, et al.
Published: (2014)

Chemically and Mechanically Controlled Single-Molecule Switches Using Spiropyrans
by: Walkey, M.C., et al.
Published: (2019)

Electrostatics and Electrochemistry: Mechanism and Scope of Charge-Transfer Reactions on the Surface of Tribocharged Insulators
by: Zhang, J., et al.
Published: (2021)

Metal-Single-Molecule-Semiconductor Junctions Formed by a Radical Reaction Bridging Gold and Silicon Electrodes.
by: Peiris, Chandramalika R, et al.
Published: (2019)

Single molecular switches: Electrochemical gating of a single anthraquinone-based norbornylogous bridge molecule
by: Darwish, Nadim, et al.
Published: (2012)

Stop-frame filming and discovery of reactions at the single-molecule level by transmission electron microscopy
by: Chamberlain, Thomas W., et al.
Published: (2017)

Fine-Tuning of Single-Molecule Conductance by Tweaking Both Electronic Structure and Conformation of Side Substituents
by: Aragonès, A., et al.
Published: (2015)

Harnessing electrostatic catalysis in single molecule, electrochemical and chemical systems: a rapidly growing experimental tool box.
by: Ciampi, S., et al.
Published: (2018)

Control over Near-Ballistic Electron Transport through Formation of Parallel Pathways in a Single-Molecule Wire
by: Aragonès, A., et al.
Published: (2019)

Electrostatic catalysis of a Diels-Alder reaction
by: Aragonès, A., et al.
Published: (2016)

Single-molecule electrical contacts on silicon electrodes under ambient conditions
by: Aragones, A., et al.
Published: (2017)

Highly conductive single-molecule wires with controlled orientation by coordination of metalloporphyrins
by: Aragonès, A., et al.
Published: (2014)

Imaging and analysis of single atoms and molecules by transmission electron microscopy
by: Cardillo-Zallo, Ian T. B.
Published: (2025)

Solvent-induced on/off switching of intramolecular electron transfer in a cyanide-bridged trigonal bipyramidal complex
by: Wei, Rong Jia, et al.
Published: (2016)

Switching of Current Rectification Ratios within a Single Nanocrystal by Facet-Resolved Electrical Wiring
by: Vogel, Yan, et al.
Published: (2018)

Surface-bound norbornylogous bridges as molecular rulers for investigating interfacial electrochemistry and as single molecule switches
by: Darwish, Nadim, et al.
Published: (2014)

The spontaneous formation of single-molecule junctions via terminal alkynes
by: Pla-Vilanova, P., et al.
Published: (2015)

Single molecule fluorescence spectroscopy
by: White,, JD, et al.
Published: (2002)

Stagnation point flow and mass transfer with chemical reaction past a stretching/shrinking cylinder
by: Mohd Najib, Najwa, et al.
Published: (2014)

Single molecule interactions in biological systems
by: Tessmer, Ingrid
Published: (2003)

Flow and heat transfer of hybrid nanofluid induced by an exponentially stretching/shrinking curved surface
by: Wahid, Nur Syahirah, et al.
Published: (2021)

Observation of electrochemically controlled quantum interference in a single anthraquinone-based norbornylogous bridge molecule
by: Darwish, Nadim, et al.
Published: (2012)

Stagnation-point flow and mass transfer with chemical reaction past a permeable stretching/shrinking sheet
by: Mohd Najib, Najwa, et al.
Published: (2013)

Electrochemical Microscopy Based on Spatial Light Modulators: A Projection System to Spatially Address Electrochemical Reactions at Semiconductors
by: Ciampi, Simone
Published: (2018)

Forming Ferrocenyl Self-Assembled Monolayers on Si(100) Electrodes with Different Alkyl Chain Lengths for Electron Transfer Studies
by: Ahmad, S., et al.
Published: (2019)

Irradiation induced reactions in carbon nanomaterials in transmission electron microscopy
by: Skowron, Stephen T.
Published: (2016)

MHD stagnation-point flow and heat transfer towards stretching sheet with induced magnetic field
by: Md. Ali, Fadzilah, et al.
Published: (2011)

Electronic and photoelectron spectroscopy of substituted benzene molecules
by: Tuttle, William Duncan
Published: (2018)

Electron and positron scattering from diatomic molecules
by: Zammit, Mark Christian
Published: (2015)

Photoemission electron microscopy of electron donor and aceptor molecules for organic photovoltaics
by: Kose, Sinan
Published: (2017)

Complete Solution of Electronic Excitation and Ionization in Electron-Hydrogen Molecule Scattering
by: Zammit, Mark, et al.
Published: (2016)

A carbon conductive filament-induced robust resistance switching behavior for brain-inspired computing
by: Yu, Tianqi, et al.
Published: (2024)

Nanoscale Silicon Oxide Reduces Electron Transfer Kinetics of Surface-Bound Ferrocene Monolayers on Silicon
by: Li, Tiexin, et al.
Published: (2021)

A single battery bank, three-phase cascaded multilevel inverter with the least number of conducting switches
by: Mohamad, Ahmad Syukri, et al.
Published: (2018)

Analytical Proton Transfer Amplitude for Heavy Ion Induced Nuclear Reactions
by: Rajesh Kumar, P., et al.
Published: (2011)

g-Jitter Induced Mixed Convection Flow of Heat and Mass Transfer Past an Inclined Stretching Sheet
by: Noraihan Afiqah, Rawi, et al.
Published: (2014)

MHD boundary layer flow and heat transfer over a stretching sheet with induced magnetic field.
by: Md.Ali, Fadzilah, et al.
Published: (2011)

Facet-resolved electrochemistry: From single particles to macroscopic crystals
by: Zhang, Song, et al.
Published: (2022)

Stagnation-point flow and mass transfer with chemical reaction past a permeable stretching/shrinking sheet in a nanofluid
by: Natalia C. Rosca,, et al.
Published: (2012)

Cannot write session to /tmp/vufind_sessions/sess_bu6bbdangsnj668982nc1ask7u