Cr(OH)3-NPs-CNC hybrid nanocomposite: a sorbent for adsorptive removal of methylene blue and malachite green from solutions

© 2017 Springer-Verlag GmbH Germany In this article, Cr(OH) 3 nanoparticle-modified cellulose nanocrystal (CNC) as a novel hybrid nanocomposite (Cr(OH) 3 -NPs-CNC) was prepared by a simple procedure and used as a sorbent for adsorptive removal of methylene blue (MB) and malachite green (MG) from aq...

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Main Authors: Nekouei, F., Nekouei, S., Keshtpour, F., Noorizadeh, H., Wang, Shaobin
Format: Journal Article
Published: Springer 2017
Online Access:http://hdl.handle.net/20.500.11937/57259
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author Nekouei, F.
Nekouei, S.
Keshtpour, F.
Noorizadeh, H.
Wang, Shaobin
author_facet Nekouei, F.
Nekouei, S.
Keshtpour, F.
Noorizadeh, H.
Wang, Shaobin
author_sort Nekouei, F.
building Curtin Institutional Repository
collection Online Access
description © 2017 Springer-Verlag GmbH Germany In this article, Cr(OH) 3 nanoparticle-modified cellulose nanocrystal (CNC) as a novel hybrid nanocomposite (Cr(OH) 3 -NPs-CNC) was prepared by a simple procedure and used as a sorbent for adsorptive removal of methylene blue (MB) and malachite green (MG) from aqueous solution. Different kinetic models were tested, and the pseudo-second-order kinetic model was found more suitable for the MB and MG adsorption processes. The BET and Langmuir models were more suitable for the adsorption processes of MB and MG. Thermodynamic studies suggested that the adsorption of MB and MG onto Cr(OH) 3 -NPs-CNC nanocomposite was a spontaneous and endothermic process. The maximum adsorption capacities for MB and MG were reached 106 and 104 mg/g, respectively, which were almost two times higher than unmodified CNC. The chemical stability and leaching tests of the Cr(OH) 3 -NPs-CNC hybrid nanocomposite showed that only small amounts of chromium were leached into the solution.
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institution Curtin University Malaysia
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publishDate 2017
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spelling curtin-20.500.11937-572592023-08-02T06:39:09Z Cr(OH)3-NPs-CNC hybrid nanocomposite: a sorbent for adsorptive removal of methylene blue and malachite green from solutions Nekouei, F. Nekouei, S. Keshtpour, F. Noorizadeh, H. Wang, Shaobin © 2017 Springer-Verlag GmbH Germany In this article, Cr(OH) 3 nanoparticle-modified cellulose nanocrystal (CNC) as a novel hybrid nanocomposite (Cr(OH) 3 -NPs-CNC) was prepared by a simple procedure and used as a sorbent for adsorptive removal of methylene blue (MB) and malachite green (MG) from aqueous solution. Different kinetic models were tested, and the pseudo-second-order kinetic model was found more suitable for the MB and MG adsorption processes. The BET and Langmuir models were more suitable for the adsorption processes of MB and MG. Thermodynamic studies suggested that the adsorption of MB and MG onto Cr(OH) 3 -NPs-CNC nanocomposite was a spontaneous and endothermic process. The maximum adsorption capacities for MB and MG were reached 106 and 104 mg/g, respectively, which were almost two times higher than unmodified CNC. The chemical stability and leaching tests of the Cr(OH) 3 -NPs-CNC hybrid nanocomposite showed that only small amounts of chromium were leached into the solution. 2017 Journal Article http://hdl.handle.net/20.500.11937/57259 10.1007/s11356-017-0111-2 Springer restricted
spellingShingle Nekouei, F.
Nekouei, S.
Keshtpour, F.
Noorizadeh, H.
Wang, Shaobin
Cr(OH)3-NPs-CNC hybrid nanocomposite: a sorbent for adsorptive removal of methylene blue and malachite green from solutions
title Cr(OH)3-NPs-CNC hybrid nanocomposite: a sorbent for adsorptive removal of methylene blue and malachite green from solutions
title_full Cr(OH)3-NPs-CNC hybrid nanocomposite: a sorbent for adsorptive removal of methylene blue and malachite green from solutions
title_fullStr Cr(OH)3-NPs-CNC hybrid nanocomposite: a sorbent for adsorptive removal of methylene blue and malachite green from solutions
title_full_unstemmed Cr(OH)3-NPs-CNC hybrid nanocomposite: a sorbent for adsorptive removal of methylene blue and malachite green from solutions
title_short Cr(OH)3-NPs-CNC hybrid nanocomposite: a sorbent for adsorptive removal of methylene blue and malachite green from solutions
title_sort cr(oh)3-nps-cnc hybrid nanocomposite: a sorbent for adsorptive removal of methylene blue and malachite green from solutions
url http://hdl.handle.net/20.500.11937/57259