Performance and durability of a layered proton conducting solid oxide fuel cell fueled by the dry reforming of methane

© 2017 The Royal Society of Chemistry. Catalyst layers derived from La 2 NiO 4 , LaNiO 3 and Ni/La 2 O 3 precursors were applied to a conventional Ni-based anode in a proton conducting solid oxide fuel cell (H + -SOFC) for the dry reforming of methane with CO 2 . The phase structures, microstructu...

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Main Authors: Guo, Y., Wan, T., Zhu, A., Shi, T., Zhang, G., Wang, C., Yu, H., Shao, Zongping
Format: Journal Article
Published: Royal Society of Chemistry 2017
Online Access:http://hdl.handle.net/20.500.11937/57248
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author Guo, Y.
Wan, T.
Zhu, A.
Shi, T.
Zhang, G.
Wang, C.
Yu, H.
Shao, Zongping
author_facet Guo, Y.
Wan, T.
Zhu, A.
Shi, T.
Zhang, G.
Wang, C.
Yu, H.
Shao, Zongping
author_sort Guo, Y.
building Curtin Institutional Repository
collection Online Access
description © 2017 The Royal Society of Chemistry. Catalyst layers derived from La 2 NiO 4 , LaNiO 3 and Ni/La 2 O 3 precursors were applied to a conventional Ni-based anode in a proton conducting solid oxide fuel cell (H + -SOFC) for the dry reforming of methane with CO 2 . The phase structures, microstructures and catalytic activities of catalysts from the different precursors were systematically investigated. The cell performance and durability of a H + -SOFC with a catalyst layer (layered H + -SOFC) were examined. The layered H + -SOFC had higher cell performances than the conventional H + -SOFC. However, catalyst deactivation and degradation of the cell performance were observed as carbon deposition occurred on the catalyst layer due to CO disproportionation in exhaust gas at a high partial pressure of CO. The structure of carbon deposited on the catalysts was also investigated.
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institution Curtin University Malaysia
institution_category Local University
last_indexed 2025-11-14T10:09:19Z
publishDate 2017
publisher Royal Society of Chemistry
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spelling curtin-20.500.11937-572482017-10-30T08:35:19Z Performance and durability of a layered proton conducting solid oxide fuel cell fueled by the dry reforming of methane Guo, Y. Wan, T. Zhu, A. Shi, T. Zhang, G. Wang, C. Yu, H. Shao, Zongping © 2017 The Royal Society of Chemistry. Catalyst layers derived from La 2 NiO 4 , LaNiO 3 and Ni/La 2 O 3 precursors were applied to a conventional Ni-based anode in a proton conducting solid oxide fuel cell (H + -SOFC) for the dry reforming of methane with CO 2 . The phase structures, microstructures and catalytic activities of catalysts from the different precursors were systematically investigated. The cell performance and durability of a H + -SOFC with a catalyst layer (layered H + -SOFC) were examined. The layered H + -SOFC had higher cell performances than the conventional H + -SOFC. However, catalyst deactivation and degradation of the cell performance were observed as carbon deposition occurred on the catalyst layer due to CO disproportionation in exhaust gas at a high partial pressure of CO. The structure of carbon deposited on the catalysts was also investigated. 2017 Journal Article http://hdl.handle.net/20.500.11937/57248 10.1039/c7ra07710f Royal Society of Chemistry unknown
spellingShingle Guo, Y.
Wan, T.
Zhu, A.
Shi, T.
Zhang, G.
Wang, C.
Yu, H.
Shao, Zongping
Performance and durability of a layered proton conducting solid oxide fuel cell fueled by the dry reforming of methane
title Performance and durability of a layered proton conducting solid oxide fuel cell fueled by the dry reforming of methane
title_full Performance and durability of a layered proton conducting solid oxide fuel cell fueled by the dry reforming of methane
title_fullStr Performance and durability of a layered proton conducting solid oxide fuel cell fueled by the dry reforming of methane
title_full_unstemmed Performance and durability of a layered proton conducting solid oxide fuel cell fueled by the dry reforming of methane
title_short Performance and durability of a layered proton conducting solid oxide fuel cell fueled by the dry reforming of methane
title_sort performance and durability of a layered proton conducting solid oxide fuel cell fueled by the dry reforming of methane
url http://hdl.handle.net/20.500.11937/57248