Nebula sulfidation and evidence for migration of "free-floating" refractory metal nuggets revealed by atom probe microscopy

Disk models have been proposed that imply particles migrate rapidly in a protoplanetary disk. However, the only physical constraints on these processes from meteorites are observations of refractory inclusions in cometary material from the NASA Stardust mission. Atom probe microscopy (APM) of sub-mi...

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Main Authors: Daly, L., Bland, Phil, Saxey, David, Reddy, Steven, Fougerouse, Denis, Rickard, William, Forman, Lucy
Format: Journal Article
Published: Geological Society of America 2017
Online Access:http://hdl.handle.net/20.500.11937/56891
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author Daly, L.
Bland, Phil
Saxey, David
Reddy, Steven
Fougerouse, Denis
Rickard, William
Forman, Lucy
author_facet Daly, L.
Bland, Phil
Saxey, David
Reddy, Steven
Fougerouse, Denis
Rickard, William
Forman, Lucy
author_sort Daly, L.
building Curtin Institutional Repository
collection Online Access
description Disk models have been proposed that imply particles migrate rapidly in a protoplanetary disk. However, the only physical constraints on these processes from meteorites are observations of refractory inclusions in cometary material from the NASA Stardust mission. Atom probe microscopy (APM) of sub-micrometer refractory metal nuggets (RMNs) contained within a Sc-Zr-rich ultrarefractory inclusion (URI) from the ALH 77307 carbonaceous Ornans (CO) 3.0 meteorite revealed the presence of sulfur at 0.06-1.00 atomic percent (at%) abundances within RMNs. The mineralogical assemblage, petrographic texture, and flat chondrite-normalized highly siderophile element ratios indicate S exposure was unlikely to have occurred after the RMNs were incorporated into the URI. APM analyses suggest these RMNs were likely "free floating" when they were exposed to a S-condensing gas. This requires early, rapid migrat ion of RMNs to cooler regions of the disk to incorporate S and then cycling back to the Ca-Al-rich inclusion (CAI)-forming region for incorporation in the URI, or conditions in the CAI-forming region that promote the incorporation of S into RMNs.
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spelling curtin-20.500.11937-568912018-02-05T07:26:55Z Nebula sulfidation and evidence for migration of "free-floating" refractory metal nuggets revealed by atom probe microscopy Daly, L. Bland, Phil Saxey, David Reddy, Steven Fougerouse, Denis Rickard, William Forman, Lucy Disk models have been proposed that imply particles migrate rapidly in a protoplanetary disk. However, the only physical constraints on these processes from meteorites are observations of refractory inclusions in cometary material from the NASA Stardust mission. Atom probe microscopy (APM) of sub-micrometer refractory metal nuggets (RMNs) contained within a Sc-Zr-rich ultrarefractory inclusion (URI) from the ALH 77307 carbonaceous Ornans (CO) 3.0 meteorite revealed the presence of sulfur at 0.06-1.00 atomic percent (at%) abundances within RMNs. The mineralogical assemblage, petrographic texture, and flat chondrite-normalized highly siderophile element ratios indicate S exposure was unlikely to have occurred after the RMNs were incorporated into the URI. APM analyses suggest these RMNs were likely "free floating" when they were exposed to a S-condensing gas. This requires early, rapid migrat ion of RMNs to cooler regions of the disk to incorporate S and then cycling back to the Ca-Al-rich inclusion (CAI)-forming region for incorporation in the URI, or conditions in the CAI-forming region that promote the incorporation of S into RMNs. 2017 Journal Article http://hdl.handle.net/20.500.11937/56891 10.1130/G39075.1 Geological Society of America restricted
spellingShingle Daly, L.
Bland, Phil
Saxey, David
Reddy, Steven
Fougerouse, Denis
Rickard, William
Forman, Lucy
Nebula sulfidation and evidence for migration of "free-floating" refractory metal nuggets revealed by atom probe microscopy
title Nebula sulfidation and evidence for migration of "free-floating" refractory metal nuggets revealed by atom probe microscopy
title_full Nebula sulfidation and evidence for migration of "free-floating" refractory metal nuggets revealed by atom probe microscopy
title_fullStr Nebula sulfidation and evidence for migration of "free-floating" refractory metal nuggets revealed by atom probe microscopy
title_full_unstemmed Nebula sulfidation and evidence for migration of "free-floating" refractory metal nuggets revealed by atom probe microscopy
title_short Nebula sulfidation and evidence for migration of "free-floating" refractory metal nuggets revealed by atom probe microscopy
title_sort nebula sulfidation and evidence for migration of "free-floating" refractory metal nuggets revealed by atom probe microscopy
url http://hdl.handle.net/20.500.11937/56891