Selection of electrode area for electrochemical noise measurements to monitor localized CO2 corrosion

The simultaneous fluctuations of potential noise and current noise between two nominally identical X-65 mild steel electrodes were recorded using a ZRA (Zero Resistance Ammeter) to monitor localized CO 2 corrosion in CO 2 -saturated 1 wt% NaCl solution at 80°C. Electrochemical noise (EN) was obtain...

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Main Authors: Jiang, X., Nešic, S., Huet, F., Kinsella, Brian, Brown, B., Young, D.
Format: Journal Article
Published: The Electrochemical Society, Inc 2012
Online Access:http://hdl.handle.net/20.500.11937/56230
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author Jiang, X.
Nešic, S.
Huet, F.
Kinsella, Brian
Brown, B.
Young, D.
author_facet Jiang, X.
Nešic, S.
Huet, F.
Kinsella, Brian
Brown, B.
Young, D.
author_sort Jiang, X.
building Curtin Institutional Repository
collection Online Access
description The simultaneous fluctuations of potential noise and current noise between two nominally identical X-65 mild steel electrodes were recorded using a ZRA (Zero Resistance Ammeter) to monitor localized CO 2 corrosion in CO 2 -saturated 1 wt% NaCl solution at 80°C. Electrochemical noise (EN) was obtained from both 11.6 cm 2 and 1 cm 2 specimens to understand how the surface area affects EN signals. Linear polarization resistance (LPR) measurements were conducted to investigate the general CO 2 corrosion behavior. Surface morphologies and pit depths were observed by scanning electron microscopy (SEM) and infinite focus microscopy (IFM) for 3D optical analysis. The results showed that the electrode area significantly influenced the EN signals of localized CO 2 corrosion. Transients related to metastable pitting were best observed with 1 cm 2 specimens but not clearly obtained for 11.6 cm 2 specimens. © 2012 The Electrochemical Society.
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publisher The Electrochemical Society, Inc
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spelling curtin-20.500.11937-562302023-08-02T06:39:09Z Selection of electrode area for electrochemical noise measurements to monitor localized CO2 corrosion Jiang, X. Nešic, S. Huet, F. Kinsella, Brian Brown, B. Young, D. The simultaneous fluctuations of potential noise and current noise between two nominally identical X-65 mild steel electrodes were recorded using a ZRA (Zero Resistance Ammeter) to monitor localized CO 2 corrosion in CO 2 -saturated 1 wt% NaCl solution at 80°C. Electrochemical noise (EN) was obtained from both 11.6 cm 2 and 1 cm 2 specimens to understand how the surface area affects EN signals. Linear polarization resistance (LPR) measurements were conducted to investigate the general CO 2 corrosion behavior. Surface morphologies and pit depths were observed by scanning electron microscopy (SEM) and infinite focus microscopy (IFM) for 3D optical analysis. The results showed that the electrode area significantly influenced the EN signals of localized CO 2 corrosion. Transients related to metastable pitting were best observed with 1 cm 2 specimens but not clearly obtained for 11.6 cm 2 specimens. © 2012 The Electrochemical Society. 2012 Journal Article http://hdl.handle.net/20.500.11937/56230 10.1149/2.007207jes The Electrochemical Society, Inc restricted
spellingShingle Jiang, X.
Nešic, S.
Huet, F.
Kinsella, Brian
Brown, B.
Young, D.
Selection of electrode area for electrochemical noise measurements to monitor localized CO2 corrosion
title Selection of electrode area for electrochemical noise measurements to monitor localized CO2 corrosion
title_full Selection of electrode area for electrochemical noise measurements to monitor localized CO2 corrosion
title_fullStr Selection of electrode area for electrochemical noise measurements to monitor localized CO2 corrosion
title_full_unstemmed Selection of electrode area for electrochemical noise measurements to monitor localized CO2 corrosion
title_short Selection of electrode area for electrochemical noise measurements to monitor localized CO2 corrosion
title_sort selection of electrode area for electrochemical noise measurements to monitor localized co2 corrosion
url http://hdl.handle.net/20.500.11937/56230