Three-dimensional porous vanadium nitride nanoribbon aerogels as Pt-free counter electrode for high-performance dye-sensitized solar cells

© 2017 Elsevier B.V. Three-dimensional (3D) porous vanadium nitride nanoribbon aerogels (PVNNRAs) are prepared by hydrothermal synthesis and subsequent nitridation in ammonia/argon atmosphere and investigated as Pt-free counter electrode in dye-sensitized solar cells (DSCs). 3D porous nanoribbon aer...

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Main Authors: Wang, G., Hou, S., Yan, C., Lin, Y., Liu, Shaomin
Format: Journal Article
Published: Elsevier BV 2017
Online Access:http://hdl.handle.net/20.500.11937/55913
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author Wang, G.
Hou, S.
Yan, C.
Lin, Y.
Liu, Shaomin
author_facet Wang, G.
Hou, S.
Yan, C.
Lin, Y.
Liu, Shaomin
author_sort Wang, G.
building Curtin Institutional Repository
collection Online Access
description © 2017 Elsevier B.V. Three-dimensional (3D) porous vanadium nitride nanoribbon aerogels (PVNNRAs) are prepared by hydrothermal synthesis and subsequent nitridation in ammonia/argon atmosphere and investigated as Pt-free counter electrode in dye-sensitized solar cells (DSCs). 3D porous nanoribbon aerogel can simultaneously offer more electrocatalytic active sites, a fast electron-transport pathway, and a favorable electrolyte diffusion channel, which endows the PVNNRA electrode with high electrocatalytic activity for the reduction of I 3 - . Under full-sun illumination (AM 1.5, 100 mW cm -2 ), the DSC fabricated with PVNNRA counter electrode achieves a conversion efficiency of 7.05%, which is comparable to that of DSCs fabricated with Pt counter electrode. In addition, the PVNNRA electrode exhibits good stability in I - /I 3 - redox electrolyte. Thus, 3D PVNNRAs can be considered as a cost-effective alternative to Pt as the counter electrode of DSCs.
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institution Curtin University Malaysia
institution_category Local University
last_indexed 2025-11-14T10:04:39Z
publishDate 2017
publisher Elsevier BV
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spelling curtin-20.500.11937-559132017-10-02T02:28:22Z Three-dimensional porous vanadium nitride nanoribbon aerogels as Pt-free counter electrode for high-performance dye-sensitized solar cells Wang, G. Hou, S. Yan, C. Lin, Y. Liu, Shaomin © 2017 Elsevier B.V. Three-dimensional (3D) porous vanadium nitride nanoribbon aerogels (PVNNRAs) are prepared by hydrothermal synthesis and subsequent nitridation in ammonia/argon atmosphere and investigated as Pt-free counter electrode in dye-sensitized solar cells (DSCs). 3D porous nanoribbon aerogel can simultaneously offer more electrocatalytic active sites, a fast electron-transport pathway, and a favorable electrolyte diffusion channel, which endows the PVNNRA electrode with high electrocatalytic activity for the reduction of I 3 - . Under full-sun illumination (AM 1.5, 100 mW cm -2 ), the DSC fabricated with PVNNRA counter electrode achieves a conversion efficiency of 7.05%, which is comparable to that of DSCs fabricated with Pt counter electrode. In addition, the PVNNRA electrode exhibits good stability in I - /I 3 - redox electrolyte. Thus, 3D PVNNRAs can be considered as a cost-effective alternative to Pt as the counter electrode of DSCs. 2017 Journal Article http://hdl.handle.net/20.500.11937/55913 10.1016/j.cej.2017.04.066 Elsevier BV restricted
spellingShingle Wang, G.
Hou, S.
Yan, C.
Lin, Y.
Liu, Shaomin
Three-dimensional porous vanadium nitride nanoribbon aerogels as Pt-free counter electrode for high-performance dye-sensitized solar cells
title Three-dimensional porous vanadium nitride nanoribbon aerogels as Pt-free counter electrode for high-performance dye-sensitized solar cells
title_full Three-dimensional porous vanadium nitride nanoribbon aerogels as Pt-free counter electrode for high-performance dye-sensitized solar cells
title_fullStr Three-dimensional porous vanadium nitride nanoribbon aerogels as Pt-free counter electrode for high-performance dye-sensitized solar cells
title_full_unstemmed Three-dimensional porous vanadium nitride nanoribbon aerogels as Pt-free counter electrode for high-performance dye-sensitized solar cells
title_short Three-dimensional porous vanadium nitride nanoribbon aerogels as Pt-free counter electrode for high-performance dye-sensitized solar cells
title_sort three-dimensional porous vanadium nitride nanoribbon aerogels as pt-free counter electrode for high-performance dye-sensitized solar cells
url http://hdl.handle.net/20.500.11937/55913