Structure-induced spreading of liquid in micropillar arrays

Contact angle measurements on micropillar arrays were used to determine the conditions that trigger spontaneous penetration of liquids into surface structures. Square micropillars (20 µm) were fabricated in photoresist or quartz and modified chemically to alter the inherent contact angle (i.e., for...

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Main Authors: Priest, C., Forsberg, P., Sedev, Rossen, Ralston, J.
Format: Conference Paper
Published: 2012
Online Access:http://hdl.handle.net/20.500.11937/54998
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author Priest, C.
Forsberg, P.
Sedev, Rossen
Ralston, J.
author_facet Priest, C.
Forsberg, P.
Sedev, Rossen
Ralston, J.
author_sort Priest, C.
building Curtin Institutional Repository
collection Online Access
description Contact angle measurements on micropillar arrays were used to determine the conditions that trigger spontaneous penetration of liquids into surface structures. Square micropillars (20 µm) were fabricated in photoresist or quartz and modified chemically to alter the inherent contact angle (i.e., for a flat surface). The lattice spacing of the pillar array and pillar height was also adjusted to investigate the influence of geometry on the wetting behavior. A critical inherent contact angle, 9 0 , was observed below 90°, at which enhanced hydrophobicity switches to enhanced hydrophilicity. This differs from Wenzel's prediction of ? 0 = 90°. The transition is not a Cassie-Wenzel state transition. Above the critical angle, the static advancing contact angle increased with pillar coverage due to pinning. Below the critical angle, liquid spreads ahead of the droplet between the pillars to form a stable film. An example of chemical detection and the implications for multiphase microfluidics is discussed. © Springer-Verlag 2011.
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spelling curtin-20.500.11937-549982017-09-13T15:49:49Z Structure-induced spreading of liquid in micropillar arrays Priest, C. Forsberg, P. Sedev, Rossen Ralston, J. Contact angle measurements on micropillar arrays were used to determine the conditions that trigger spontaneous penetration of liquids into surface structures. Square micropillars (20 µm) were fabricated in photoresist or quartz and modified chemically to alter the inherent contact angle (i.e., for a flat surface). The lattice spacing of the pillar array and pillar height was also adjusted to investigate the influence of geometry on the wetting behavior. A critical inherent contact angle, 9 0 , was observed below 90°, at which enhanced hydrophobicity switches to enhanced hydrophilicity. This differs from Wenzel's prediction of ? 0 = 90°. The transition is not a Cassie-Wenzel state transition. Above the critical angle, the static advancing contact angle increased with pillar coverage due to pinning. Below the critical angle, liquid spreads ahead of the droplet between the pillars to form a stable film. An example of chemical detection and the implications for multiphase microfluidics is discussed. © Springer-Verlag 2011. 2012 Conference Paper http://hdl.handle.net/20.500.11937/54998 10.1007/s00542-011-1341-8 restricted
spellingShingle Priest, C.
Forsberg, P.
Sedev, Rossen
Ralston, J.
Structure-induced spreading of liquid in micropillar arrays
title Structure-induced spreading of liquid in micropillar arrays
title_full Structure-induced spreading of liquid in micropillar arrays
title_fullStr Structure-induced spreading of liquid in micropillar arrays
title_full_unstemmed Structure-induced spreading of liquid in micropillar arrays
title_short Structure-induced spreading of liquid in micropillar arrays
title_sort structure-induced spreading of liquid in micropillar arrays
url http://hdl.handle.net/20.500.11937/54998