Influence of pH and citrate on the formation of oxalate layers on calcite revealed by in situ nanoscale imaging

QR Code

Influence of pH and citrate on the formation of oxalate layers on calcite revealed by in situ nanoscale imaging

The influence of pH and citrate concentration on the replacement of calcite by calcium oxalate has been investigated by in situ nanoscale observations in flow-through experiments performed using atomic force microscopy (AFM). Significant changes in the morphology of the precipitated whewellite (CaC...

Full description

Bibliographic Details
Main Authors:	Burgos-Cara, A., Putnis, Christine, Ortega-Huertas, M., Ruiz-Agudo, E.
Format:	Journal Article
Published:	The Royal Society of Chemistry 2017
Online Access:	http://hdl.handle.net/20.500.11937/54903

Similar Items

Direct Nanoscale Imaging Reveals the Growth of Calcite Crystals via Amorphous Nanoparticles
by: Rodriguez-Navarro, C., et al.
Published: (2016)

Interactions of arsenic with calcite surfaces revealed by in situ nanoscale imaging
by: Renard, F., et al.
Published: (2015)

Hydration effects on gypsum dissolution revealed by in situ nanoscale atomic force microscopy observations
by: Burgos-Cara, A., et al.
Published: (2016)

Sequestration of selenium on calcite surfaces revealed by nanoscale imaging
by: Putnis, Christine, et al.
Published: (2013)

Boron incorporation into calcite during growth: Implications for the use of boron in carbonates as a pH proxy
by: Ruiz-Agudo, E., et al.
Published: (2012)

Influence of chemical and structural factors on the calcite-calcium oxalate transformation
by: Ruiz-Agudo, E., et al.
Published: (2013)

Posner's cluster revisited: Direct imaging of nucleation and growth of nanoscale calcium phosphate clusters at the calcite-water interface
by: Wang, L., et al.
Published: (2012)

In situ nanoscale observations of the dissolution of {101¯4} dolomite cleavage surfaces
by: Urosevic, M., et al.
Published: (2012)

Effect of pH on calcite growth at constant aCa2+/aCO32- ratio and supersaturation
by: Ruiz-Agudo, E., et al.
Published: (2011)

Macro- to nanoscale study of the effect of aqueous sulphate on calcite growth
by: Vavouraki, A., et al.
Published: (2008)

Visualizing Organophosphate Precipitation at the Calcite-Water Interface by in Situ Atomic-Force Microscopy
by: Wang, L., et al.
Published: (2016)

The role of background electrolytes on the kinetics and mechanism of calcite dissolution
by: Ruiz-Agudo, E., et al.
Published: (2010)

Direct observations of mineral-fluid reactions using atomic force microscopy: The specific example of calcite
by: Ruiz-Agudo, E., et al.
Published: (2012)

Direct nanoscale observations of the coupled dissolution of calcite and dolomite and the precipitation of gypsum
by: Offeddu, F., et al.
Published: (2014)

Sequestration of Antimony on Calcite Observed by Time-Resolved Nanoscale Imaging
by: Renard, F., et al.
Published: (2018)

Specific effects of background electrolytes on the kinetics of step propagation during calcite growth
by: Ruiz-Agudo, E., et al.
Published: (2011)

The influence of pH on barite nucleation and growth
by: Ruiz-Agudo, C., et al.
Published: (2015)

Porosity generated during the fluid-mediated replacement of calcite by fluorite
by: Pedrosa, E., et al.
Published: (2016)

Direct observations of the modification of calcite growth morphology by Li+ through selectively stabilizing an energetically unfavourable face
by: Wang, L., et al.
Published: (2011)

Experimental study of the replacement of calcite by calcium sulphates
by: Ruiz-Agudo, E., et al.
Published: (2015)

Template-assisted crystallization of sulfates onto calcite: Implications for the prevention of salt damage
by: Ruiz-Agudo, E., et al.
Published: (2013)

In Situ Nanoscale Imaging of Struvite Formation during the Dissolution of Natural Brucite: Implications for Phosphorus Recovery from Wastewaters
by: Hoevelmann, J., et al.
Published: (2016)

Selenium incorporation into calcite and its effect on crystal growth: An atomic force microscopy study
by: Renard, F., et al.
Published: (2013)

Hydration effects on the stability of calcium carbonate pre-nucleation species
by: Burgos-Cara, A., et al.
Published: (2017)

Kinetics of calcium phosphate nucleation and growth on calcite: Implications for predicting the fate of dissolved phosphate species in alkaline soils
by: Wang, L., et al.
Published: (2012)

Direct nanoscale observations of CO2 sequestration during brucite [Mg(OH)2] dissolution
by: Hövelmann, J., et al.
Published: (2012)

An atomic force microscopy study of calcite dissolution in saline solutions: The role of magnesium ions
by: Ruiz-Agudo, E., et al.
Published: (2009)

An atomic force microscopy study of the dissolution of calcite in the presence of phosphate ions
by: Klasa, J., et al.
Published: (2013)

In situ imaging of interfacial precipitation of phosphate on goethite
by: Wang, L., et al.
Published: (2015)

Mechanism of leached layer formation during chemical weathering of silicate minerals
by: Ruiz-Agudo, E., et al.
Published: (2012)

Siderite dissolution coupled to iron oxyhydroxide precipitation in the presence of arsenic revealed by nanoscale imaging
by: Renard, F., et al.
Published: (2017)

Interactions between organophosphonate-bearing solutions and (1014) calcite surfaces: An atomic force microscopy and first-principles molecular dynamics study
by: Ruiz-Agudo, E., et al.
Published: (2010)

Effect of ferrous iron on the nucleation and growth of CaCO3 in slightly basic aqueous solutions
by: Di Lorenzo, F., et al.
Published: (2017)

Forming Cohesive Calcium Oxalate Layers on Marble Surfaces for Stone Conservation
by: King, H., et al.
Published: (2014)

Exploring the effect of poly(acrylic acid) on pre- and post-nucleation BaSO4 species: New insights into the mechanisms of crystallization control by polyelectrolytes
by: Ruiz-Agudo, C., et al.
Published: (2016)

The effect of fluid composition on the mechanism of the aragonite to calcite transition
by: Perdikouri, C., et al.
Published: (2008)

An Atomic Force Microscopy study of the growth of calcite in the presence of sodium sulfate
by: Vavouraki, A., et al.
Published: (2008)

Mechanistic Principles of Barite Formation: From Nanoparticles to Micron-Sized Crystals
by: Ruiz-Agudo, C., et al.
Published: (2015)

Imaging Organophosphate and Pyrophosphate Sequestration on Brucite by in Situ Atomic Force Microscopy.
by: Wang, L., et al.
Published: (2016)

The mineral-water interface: Where minerals react with the environment
by: Putnis, Christine, et al.
Published: (2013)

Cannot write session to /tmp/vufind_sessions/sess_1fod9hc0f5t1i2q0ijm30hl9sc