Systematic study of aqueous monoethanolamine-based CO2 capture process: model development and process improvement

In this paper, we present improvements to postcombustion capture (PCC) processes based on aqueous monoethanolamine (MEA). First, a rigorous, rate-based model of the carbon dioxide (CO2) capture process from flue gas by aqueous MEA was developed using Aspen Plus, and validated against results from th...

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Main Authors: Li, K., Cousins, A., Yu, H., Feron, P., Tade, Moses, Luo, W., Chen, J.
Format: Journal Article
Published: WILEY 2016
Online Access:http://hdl.handle.net/20.500.11937/54628
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author Li, K.
Cousins, A.
Yu, H.
Feron, P.
Tade, Moses
Luo, W.
Chen, J.
author_facet Li, K.
Cousins, A.
Yu, H.
Feron, P.
Tade, Moses
Luo, W.
Chen, J.
author_sort Li, K.
building Curtin Institutional Repository
collection Online Access
description In this paper, we present improvements to postcombustion capture (PCC) processes based on aqueous monoethanolamine (MEA). First, a rigorous, rate-based model of the carbon dioxide (CO2) capture process from flue gas by aqueous MEA was developed using Aspen Plus, and validated against results from the PCC pilot plant trials located at the coal-fired Tarong power station in Queensland, Australia. The model satisfactorily predicted the comprehensive experimental results from CO2 absorption and CO2 stripping process. The model was then employed to guide the systematic study of the MEA-based CO2 capture process for the reduction in regeneration energy penalty through parameter optimization and process modification. Important process parameters such as MEA concentration, lean CO2 loading, lean temperature, and stripper pressure were optimized. The process modifications were investigated, which included the absorber intercooling, rich-split, and stripper interheating processes. The minimum regeneration energy obtained from the combined parameter optimization and process modification was 3.1 MJ/kg CO2. This study suggests that the combination of a validated rate-based model and process simulation can be used as an effective tool to guide sophisticated process plant, equipment design and process improvement.
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spelling curtin-20.500.11937-546282017-11-10T03:55:57Z Systematic study of aqueous monoethanolamine-based CO2 capture process: model development and process improvement Li, K. Cousins, A. Yu, H. Feron, P. Tade, Moses Luo, W. Chen, J. In this paper, we present improvements to postcombustion capture (PCC) processes based on aqueous monoethanolamine (MEA). First, a rigorous, rate-based model of the carbon dioxide (CO2) capture process from flue gas by aqueous MEA was developed using Aspen Plus, and validated against results from the PCC pilot plant trials located at the coal-fired Tarong power station in Queensland, Australia. The model satisfactorily predicted the comprehensive experimental results from CO2 absorption and CO2 stripping process. The model was then employed to guide the systematic study of the MEA-based CO2 capture process for the reduction in regeneration energy penalty through parameter optimization and process modification. Important process parameters such as MEA concentration, lean CO2 loading, lean temperature, and stripper pressure were optimized. The process modifications were investigated, which included the absorber intercooling, rich-split, and stripper interheating processes. The minimum regeneration energy obtained from the combined parameter optimization and process modification was 3.1 MJ/kg CO2. This study suggests that the combination of a validated rate-based model and process simulation can be used as an effective tool to guide sophisticated process plant, equipment design and process improvement. 2016 Journal Article http://hdl.handle.net/20.500.11937/54628 10.1002/ese3.101 http://creativecommons.org/licenses/by/4.0/ WILEY fulltext
spellingShingle Li, K.
Cousins, A.
Yu, H.
Feron, P.
Tade, Moses
Luo, W.
Chen, J.
Systematic study of aqueous monoethanolamine-based CO2 capture process: model development and process improvement
title Systematic study of aqueous monoethanolamine-based CO2 capture process: model development and process improvement
title_full Systematic study of aqueous monoethanolamine-based CO2 capture process: model development and process improvement
title_fullStr Systematic study of aqueous monoethanolamine-based CO2 capture process: model development and process improvement
title_full_unstemmed Systematic study of aqueous monoethanolamine-based CO2 capture process: model development and process improvement
title_short Systematic study of aqueous monoethanolamine-based CO2 capture process: model development and process improvement
title_sort systematic study of aqueous monoethanolamine-based co2 capture process: model development and process improvement
url http://hdl.handle.net/20.500.11937/54628