Electron- and positron-molecule scattering: Development of the molecular convergent close-coupling method

Starting from first principles, this tutorial describes the development of the adiabatic-nuclei convergent close-coupling (CCC) method and its application to electron and (single-centre) positron scattering from diatomic molecules. We give full details of the single-centre expansion CCC method, name...

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Main Authors: Zammit, M., Fursa, Dmitry, Savage, J., Bray, Igor
Format: Journal Article
Published: Institute of Physics Publishing Ltd. 2017
Online Access:http://hdl.handle.net/20.500.11937/54621
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author Zammit, M.
Fursa, Dmitry
Savage, J.
Bray, Igor
author_facet Zammit, M.
Fursa, Dmitry
Savage, J.
Bray, Igor
author_sort Zammit, M.
building Curtin Institutional Repository
collection Online Access
description Starting from first principles, this tutorial describes the development of the adiabatic-nuclei convergent close-coupling (CCC) method and its application to electron and (single-centre) positron scattering from diatomic molecules. We give full details of the single-centre expansion CCC method, namely the formulation of the molecular target structure; solving the momentum-space coupled-channel Lippmann-Schwinger equation; deriving adiabatic-nuclei cross sections and calculating V-matrix elements. Selected results are presented for electron and positron scattering from molecular hydrogen H2 and electron scattering from the vibrationally excited molecular hydrogen ion and its isotopologues (D2+, , HD+, HT+ and TD+). Convergence in both the close-coupling (target state) and projectile partial-wave expansions of fixed-nuclei electron- and positron-molecule scattering calculations is demonstrated over a broad energy-range and discussed in detail. In general, the CCC results are in good agreement with experiments.
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spelling curtin-20.500.11937-546212018-03-01T05:25:55Z Electron- and positron-molecule scattering: Development of the molecular convergent close-coupling method Zammit, M. Fursa, Dmitry Savage, J. Bray, Igor Starting from first principles, this tutorial describes the development of the adiabatic-nuclei convergent close-coupling (CCC) method and its application to electron and (single-centre) positron scattering from diatomic molecules. We give full details of the single-centre expansion CCC method, namely the formulation of the molecular target structure; solving the momentum-space coupled-channel Lippmann-Schwinger equation; deriving adiabatic-nuclei cross sections and calculating V-matrix elements. Selected results are presented for electron and positron scattering from molecular hydrogen H2 and electron scattering from the vibrationally excited molecular hydrogen ion and its isotopologues (D2+, , HD+, HT+ and TD+). Convergence in both the close-coupling (target state) and projectile partial-wave expansions of fixed-nuclei electron- and positron-molecule scattering calculations is demonstrated over a broad energy-range and discussed in detail. In general, the CCC results are in good agreement with experiments. 2017 Journal Article http://hdl.handle.net/20.500.11937/54621 10.1088/1361-6455/aa6e74 Institute of Physics Publishing Ltd. restricted
spellingShingle Zammit, M.
Fursa, Dmitry
Savage, J.
Bray, Igor
Electron- and positron-molecule scattering: Development of the molecular convergent close-coupling method
title Electron- and positron-molecule scattering: Development of the molecular convergent close-coupling method
title_full Electron- and positron-molecule scattering: Development of the molecular convergent close-coupling method
title_fullStr Electron- and positron-molecule scattering: Development of the molecular convergent close-coupling method
title_full_unstemmed Electron- and positron-molecule scattering: Development of the molecular convergent close-coupling method
title_short Electron- and positron-molecule scattering: Development of the molecular convergent close-coupling method
title_sort electron- and positron-molecule scattering: development of the molecular convergent close-coupling method
url http://hdl.handle.net/20.500.11937/54621