3,4-Ethylenedioxythiophene functionalizationed with tetrathiafulvalene: Synthesis and selective esterification
3,4-(Hydroxymethyl-ethylenedioxy)thiophene (4) and 3,4-(2'-hydroxypropylenedioxy)thiophene (4'') were synthesized from dimethyl 3,4-dihydroxythiophene-2,5-dicarboxylate (1), which were isomers and difficult to separate. When they were esterified with tetrathiafulvalene carried carboxy...
| Main Authors: | , , , , |
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| Format: | Journal Article |
| Published: |
John Wiley & Sons
2015
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| Online Access: | http://hdl.handle.net/20.500.11937/53921 |
| _version_ | 1848759260086796288 |
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| author | Zhang, L. Wu, Changzhi Wang, C. Zuo, H. Shen, Y. |
| author_facet | Zhang, L. Wu, Changzhi Wang, C. Zuo, H. Shen, Y. |
| author_sort | Zhang, L. |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | 3,4-(Hydroxymethyl-ethylenedioxy)thiophene (4) and 3,4-(2'-hydroxypropylenedioxy)thiophene (4'') were synthesized from dimethyl 3,4-dihydroxythiophene-2,5-dicarboxylate (1), which were isomers and difficult to separate. When they were esterified with tetrathiafulvalene carried carboxylic acid group, only 3,4-(hydroxymethyl-ethylenedioxy)thiophene (4) could be esterified. No such selectivity was observed when the isomers were esterified by lauric acid and benzoic acid, respectively. |
| first_indexed | 2025-11-14T09:57:03Z |
| format | Journal Article |
| id | curtin-20.500.11937-53921 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T09:57:03Z |
| publishDate | 2015 |
| publisher | John Wiley & Sons |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-539212017-10-23T01:46:59Z 3,4-Ethylenedioxythiophene functionalizationed with tetrathiafulvalene: Synthesis and selective esterification Zhang, L. Wu, Changzhi Wang, C. Zuo, H. Shen, Y. 3,4-(Hydroxymethyl-ethylenedioxy)thiophene (4) and 3,4-(2'-hydroxypropylenedioxy)thiophene (4'') were synthesized from dimethyl 3,4-dihydroxythiophene-2,5-dicarboxylate (1), which were isomers and difficult to separate. When they were esterified with tetrathiafulvalene carried carboxylic acid group, only 3,4-(hydroxymethyl-ethylenedioxy)thiophene (4) could be esterified. No such selectivity was observed when the isomers were esterified by lauric acid and benzoic acid, respectively. 2015 Journal Article http://hdl.handle.net/20.500.11937/53921 10.1002/jhet.1834 John Wiley & Sons restricted |
| spellingShingle | Zhang, L. Wu, Changzhi Wang, C. Zuo, H. Shen, Y. 3,4-Ethylenedioxythiophene functionalizationed with tetrathiafulvalene: Synthesis and selective esterification |
| title | 3,4-Ethylenedioxythiophene functionalizationed with tetrathiafulvalene: Synthesis and selective esterification |
| title_full | 3,4-Ethylenedioxythiophene functionalizationed with tetrathiafulvalene: Synthesis and selective esterification |
| title_fullStr | 3,4-Ethylenedioxythiophene functionalizationed with tetrathiafulvalene: Synthesis and selective esterification |
| title_full_unstemmed | 3,4-Ethylenedioxythiophene functionalizationed with tetrathiafulvalene: Synthesis and selective esterification |
| title_short | 3,4-Ethylenedioxythiophene functionalizationed with tetrathiafulvalene: Synthesis and selective esterification |
| title_sort | 3,4-ethylenedioxythiophene functionalizationed with tetrathiafulvalene: synthesis and selective esterification |
| url | http://hdl.handle.net/20.500.11937/53921 |