Recent advances in the 18-electron complex transition metal hydrides of Ni, Fe, Co and Ru
Metal hydrides have received much attention due to the flourishing concept of a hydrogen economy. In addition, recent studies of metal hydride materials have shown that technological implementation of these compounds not only lies in the storage of hydrogen, but for a range of multi-functional appli...
| Main Authors: | , , |
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| Format: | Journal Article |
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2017
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| Online Access: | http://purl.org/au-research/grants/arc/LP150100730 http://hdl.handle.net/20.500.11937/53843 |
| _version_ | 1848759241746153472 |
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| author | Humphries, Terry Sheppard, Drew Buckley, Craig |
| author_facet | Humphries, Terry Sheppard, Drew Buckley, Craig |
| author_sort | Humphries, Terry |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | Metal hydrides have received much attention due to the flourishing concept of a hydrogen economy. In addition, recent studies of metal hydride materials have shown that technological implementation of these compounds not only lies in the storage of hydrogen, but for a range of multi-functional applications; including, smart optical windows, energy storage materials in fuel cells for both stationary and mobile devices, and as thermal energy storage materials for concentrating solar thermal plants. This review concentrates on the molecular structures, thermodynamic properties and other physical properties of the complexes of [NiH4]4-, [FeH6]4-, [CoH5]4- and [RuH6]4-. The synthesized derivatives of these compounds have also been reviewed to give a full overview on the advancement of these systems and will allow for a fresh prospective for future studies to fully understand the physical and chemical nature of these complex transition metal hydrides. |
| first_indexed | 2025-11-14T09:56:46Z |
| format | Journal Article |
| id | curtin-20.500.11937-53843 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T09:56:46Z |
| publishDate | 2017 |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-538432022-11-28T05:03:33Z Recent advances in the 18-electron complex transition metal hydrides of Ni, Fe, Co and Ru Humphries, Terry Sheppard, Drew Buckley, Craig Metal hydrides have received much attention due to the flourishing concept of a hydrogen economy. In addition, recent studies of metal hydride materials have shown that technological implementation of these compounds not only lies in the storage of hydrogen, but for a range of multi-functional applications; including, smart optical windows, energy storage materials in fuel cells for both stationary and mobile devices, and as thermal energy storage materials for concentrating solar thermal plants. This review concentrates on the molecular structures, thermodynamic properties and other physical properties of the complexes of [NiH4]4-, [FeH6]4-, [CoH5]4- and [RuH6]4-. The synthesized derivatives of these compounds have also been reviewed to give a full overview on the advancement of these systems and will allow for a fresh prospective for future studies to fully understand the physical and chemical nature of these complex transition metal hydrides. 2017 Journal Article http://hdl.handle.net/20.500.11937/53843 10.1016/j.ccr.2017.04.001 http://purl.org/au-research/grants/arc/LP150100730 fulltext |
| spellingShingle | Humphries, Terry Sheppard, Drew Buckley, Craig Recent advances in the 18-electron complex transition metal hydrides of Ni, Fe, Co and Ru |
| title | Recent advances in the 18-electron complex transition metal hydrides of Ni, Fe, Co and Ru |
| title_full | Recent advances in the 18-electron complex transition metal hydrides of Ni, Fe, Co and Ru |
| title_fullStr | Recent advances in the 18-electron complex transition metal hydrides of Ni, Fe, Co and Ru |
| title_full_unstemmed | Recent advances in the 18-electron complex transition metal hydrides of Ni, Fe, Co and Ru |
| title_short | Recent advances in the 18-electron complex transition metal hydrides of Ni, Fe, Co and Ru |
| title_sort | recent advances in the 18-electron complex transition metal hydrides of ni, fe, co and ru |
| url | http://purl.org/au-research/grants/arc/LP150100730 http://hdl.handle.net/20.500.11937/53843 |