On the refractory nature of precious metal tellurides

An investigation into the factors inhibiting the leaching of precious metal tellurides in cyanide solutions and initial testing of possible methods to improve leach performance were conducted. Petzite (Ag3AuTe2) was the principle mineral examined, along with calaverite (AuTe2) and hessite (Ag2Te). B...

Full description

Bibliographic Details
Main Authors: Dyer, Laurence, Sauber, M., Dixon, D., Asselin, E.
Format: Journal Article
Published: Elsevier 2017
Online Access:http://hdl.handle.net/20.500.11937/53805
_version_ 1848759232281706496
author Dyer, Laurence
Sauber, M.
Dixon, D.
Asselin, E.
author_facet Dyer, Laurence
Sauber, M.
Dixon, D.
Asselin, E.
author_sort Dyer, Laurence
building Curtin Institutional Repository
collection Online Access
description An investigation into the factors inhibiting the leaching of precious metal tellurides in cyanide solutions and initial testing of possible methods to improve leach performance were conducted. Petzite (Ag3AuTe2) was the principle mineral examined, along with calaverite (AuTe2) and hessite (Ag2Te). Both electrochemical measurements and batch leach experiments were employed to verify findings. It was found that tellurium is not readily oxidised under standard cyanidation conditions and thus was impeding the extraction of the precious metal elements. While this appears to be the primary problem to be overcome in leaching telluride minerals (particularly calaverite and hessite), evidence of passivation (previously noted in multiple studies) by a Te-rich layer was also observed in leach tests. Both established and new approaches to improve the telluride mineral leaching were tested to examine their effectiveness and better understand the fundamental chemistry involved. While elevated pH remains the most effective approach, actually leaching tellurides faster than pure gold, small proportions of citrate improved recovery from the gold-bearing tellurides.
first_indexed 2025-11-14T09:56:36Z
format Journal Article
id curtin-20.500.11937-53805
institution Curtin University Malaysia
institution_category Local University
last_indexed 2025-11-14T09:56:36Z
publishDate 2017
publisher Elsevier
recordtype eprints
repository_type Digital Repository
spelling curtin-20.500.11937-538052017-10-16T08:49:16Z On the refractory nature of precious metal tellurides Dyer, Laurence Sauber, M. Dixon, D. Asselin, E. An investigation into the factors inhibiting the leaching of precious metal tellurides in cyanide solutions and initial testing of possible methods to improve leach performance were conducted. Petzite (Ag3AuTe2) was the principle mineral examined, along with calaverite (AuTe2) and hessite (Ag2Te). Both electrochemical measurements and batch leach experiments were employed to verify findings. It was found that tellurium is not readily oxidised under standard cyanidation conditions and thus was impeding the extraction of the precious metal elements. While this appears to be the primary problem to be overcome in leaching telluride minerals (particularly calaverite and hessite), evidence of passivation (previously noted in multiple studies) by a Te-rich layer was also observed in leach tests. Both established and new approaches to improve the telluride mineral leaching were tested to examine their effectiveness and better understand the fundamental chemistry involved. While elevated pH remains the most effective approach, actually leaching tellurides faster than pure gold, small proportions of citrate improved recovery from the gold-bearing tellurides. 2017 Journal Article http://hdl.handle.net/20.500.11937/53805 10.1016/j.hydromet.2017.03.009 Elsevier restricted
spellingShingle Dyer, Laurence
Sauber, M.
Dixon, D.
Asselin, E.
On the refractory nature of precious metal tellurides
title On the refractory nature of precious metal tellurides
title_full On the refractory nature of precious metal tellurides
title_fullStr On the refractory nature of precious metal tellurides
title_full_unstemmed On the refractory nature of precious metal tellurides
title_short On the refractory nature of precious metal tellurides
title_sort on the refractory nature of precious metal tellurides
url http://hdl.handle.net/20.500.11937/53805