Halogenated Sodium-closo-Dodecaboranes as Solid-State Ion Conductors

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Halogenated Sodium-closo-Dodecaboranes as Solid-State Ion Conductors

Sodium compounds containing large weakly coordinating anions are explored as ion conductors. The halogenated sodium-closo-dodecaboranes (Na2B12Cl12, Na2B12Br12, and Na2B12I12) are all isostructural (Pa3¯) at room temperature. These compounds undergo an order-disorder polymorphic transition to Fm3¯m...

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Bibliographic Details
Main Authors:	Hansen, B., Paskevicius, Mark, Jørgensen, M., Jensen, T.
Format:	Journal Article
Published:	American Chemical Society 2017
Online Access:	http://hdl.handle.net/20.500.11937/53361

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