Calixarene/azolium cyclophane hybrids: Synthesis, structure and conformations
© Springer Science+Business Media Dordrecht 2015.The synthesis, structure, and conformational behaviour of three imidazolium cyclophanes that incorporate one or two 4-tert-butylphenol or 4-tert-butylanisole groups as meta-disubstituted linkers in the macrocycle is described. The cyclophanes containi...
| Main Authors: | , , , , |
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| Format: | Journal Article |
| Published: |
Kluwer Academic Publishers
2015
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| Online Access: | http://hdl.handle.net/20.500.11937/52903 |
| _version_ | 1848759039813484544 |
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| author | Hesler, V. Skelton, B. White, A. Brown, David Baker, M. |
| author_facet | Hesler, V. Skelton, B. White, A. Brown, David Baker, M. |
| author_sort | Hesler, V. |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | © Springer Science+Business Media Dordrecht 2015.The synthesis, structure, and conformational behaviour of three imidazolium cyclophanes that incorporate one or two 4-tert-butylphenol or 4-tert-butylanisole groups as meta-disubstituted linkers in the macrocycle is described. The cyclophanes containing anisole moieties adopt a cone conformation in the solid state, which, in solution, is not labile on the NMR timescale. The cyclophanes containing one or two phenol moieties adopt conformations other than the cone in the solid state and are labile in solution on the NMR timescale. The phenol cyclophanes are readily deprotonated, and structural and conformational studies for a variety of the associated cyclophanes are also reported. |
| first_indexed | 2025-11-14T09:53:33Z |
| format | Journal Article |
| id | curtin-20.500.11937-52903 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T09:53:33Z |
| publishDate | 2015 |
| publisher | Kluwer Academic Publishers |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-529032017-09-13T15:39:43Z Calixarene/azolium cyclophane hybrids: Synthesis, structure and conformations Hesler, V. Skelton, B. White, A. Brown, David Baker, M. © Springer Science+Business Media Dordrecht 2015.The synthesis, structure, and conformational behaviour of three imidazolium cyclophanes that incorporate one or two 4-tert-butylphenol or 4-tert-butylanisole groups as meta-disubstituted linkers in the macrocycle is described. The cyclophanes containing anisole moieties adopt a cone conformation in the solid state, which, in solution, is not labile on the NMR timescale. The cyclophanes containing one or two phenol moieties adopt conformations other than the cone in the solid state and are labile in solution on the NMR timescale. The phenol cyclophanes are readily deprotonated, and structural and conformational studies for a variety of the associated cyclophanes are also reported. 2015 Journal Article http://hdl.handle.net/20.500.11937/52903 10.1007/s10847-015-0491-1 Kluwer Academic Publishers restricted |
| spellingShingle | Hesler, V. Skelton, B. White, A. Brown, David Baker, M. Calixarene/azolium cyclophane hybrids: Synthesis, structure and conformations |
| title | Calixarene/azolium cyclophane hybrids: Synthesis, structure and conformations |
| title_full | Calixarene/azolium cyclophane hybrids: Synthesis, structure and conformations |
| title_fullStr | Calixarene/azolium cyclophane hybrids: Synthesis, structure and conformations |
| title_full_unstemmed | Calixarene/azolium cyclophane hybrids: Synthesis, structure and conformations |
| title_short | Calixarene/azolium cyclophane hybrids: Synthesis, structure and conformations |
| title_sort | calixarene/azolium cyclophane hybrids: synthesis, structure and conformations |
| url | http://hdl.handle.net/20.500.11937/52903 |