Effect of alkali addition on sulfur transformation during low temperature pyrolysis of sewage sludge

© 2016 by The Combustion Institute. Published by Elsevier Inc.Odorous sulfur-containing gases released during sewage sludge processing cause significant environmental pollution. This study investigates the effect of alkali addition on sulfur transformation as well as the release of the sulfur-contai...

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Main Authors: Cheng, S., Qiao, Y., Huang, J., Cao, L., Yang, H., Liu, H., Yu, Yun, Xu, M.
Format: Journal Article
Published: Combustion Institute 2015
Online Access:http://hdl.handle.net/20.500.11937/52881
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author Cheng, S.
Qiao, Y.
Huang, J.
Cao, L.
Yang, H.
Liu, H.
Yu, Yun
Xu, M.
author_facet Cheng, S.
Qiao, Y.
Huang, J.
Cao, L.
Yang, H.
Liu, H.
Yu, Yun
Xu, M.
author_sort Cheng, S.
building Curtin Institutional Repository
collection Online Access
description © 2016 by The Combustion Institute. Published by Elsevier Inc.Odorous sulfur-containing gases released during sewage sludge processing cause significant environmental pollution. This study investigates the effect of alkali addition on sulfur transformation as well as the release of the sulfur-containing gases during sewage sludge pyrolysis at 150-450°C. The presence of alkali can promote the transformation of unstable organic aliphatic and aromatic sulfurs into more stable sulfoxides and sulphonic acid at low temperatures (i.e., 250°C). Alkalis also fix the inorganic sulfide and sulphate in char. Therefore, the release of the sulfur-containing gases can be greatly reduced with alkali addition. Stronger alkalis show more significant effect on the reduction of sulfur-containing gases, likely because of more OH radicals generated for the transformation of organic sulfurs.
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institution Curtin University Malaysia
institution_category Local University
last_indexed 2025-11-14T09:53:28Z
publishDate 2015
publisher Combustion Institute
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spelling curtin-20.500.11937-528812017-09-13T15:40:02Z Effect of alkali addition on sulfur transformation during low temperature pyrolysis of sewage sludge Cheng, S. Qiao, Y. Huang, J. Cao, L. Yang, H. Liu, H. Yu, Yun Xu, M. © 2016 by The Combustion Institute. Published by Elsevier Inc.Odorous sulfur-containing gases released during sewage sludge processing cause significant environmental pollution. This study investigates the effect of alkali addition on sulfur transformation as well as the release of the sulfur-containing gases during sewage sludge pyrolysis at 150-450°C. The presence of alkali can promote the transformation of unstable organic aliphatic and aromatic sulfurs into more stable sulfoxides and sulphonic acid at low temperatures (i.e., 250°C). Alkalis also fix the inorganic sulfide and sulphate in char. Therefore, the release of the sulfur-containing gases can be greatly reduced with alkali addition. Stronger alkalis show more significant effect on the reduction of sulfur-containing gases, likely because of more OH radicals generated for the transformation of organic sulfurs. 2015 Journal Article http://hdl.handle.net/20.500.11937/52881 10.1016/j.proci.2016.06.124 Combustion Institute restricted
spellingShingle Cheng, S.
Qiao, Y.
Huang, J.
Cao, L.
Yang, H.
Liu, H.
Yu, Yun
Xu, M.
Effect of alkali addition on sulfur transformation during low temperature pyrolysis of sewage sludge
title Effect of alkali addition on sulfur transformation during low temperature pyrolysis of sewage sludge
title_full Effect of alkali addition on sulfur transformation during low temperature pyrolysis of sewage sludge
title_fullStr Effect of alkali addition on sulfur transformation during low temperature pyrolysis of sewage sludge
title_full_unstemmed Effect of alkali addition on sulfur transformation during low temperature pyrolysis of sewage sludge
title_short Effect of alkali addition on sulfur transformation during low temperature pyrolysis of sewage sludge
title_sort effect of alkali addition on sulfur transformation during low temperature pyrolysis of sewage sludge
url http://hdl.handle.net/20.500.11937/52881