Monodisperse Co3O4 quantum dots on porous carbon nitride nanosheets for enhanced visible-light-driven water oxidation

Here we report a facile annealing process for homogeneous deposition of Co3O4 quantum dots (Co3O4 QDs) onto porous g-C3N4 nanosheets. It was discovered that pores were catalytically produced around Co3O4 QDs. In the synthesis, annealing temperature was found to be crucial for the textural property,...

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Main Authors: Zhang, H., Tian, W., Zhou, L., Sun, Hongqi, Tade, Moses, Wang, Shaobin
Format: Journal Article
Published: Elsevier BV 2016
Online Access:http://purl.org/au-research/grants/arc/DP150103026
http://hdl.handle.net/20.500.11937/52847
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author Zhang, H.
Tian, W.
Zhou, L.
Sun, Hongqi
Tade, Moses
Wang, Shaobin
author_facet Zhang, H.
Tian, W.
Zhou, L.
Sun, Hongqi
Tade, Moses
Wang, Shaobin
author_sort Zhang, H.
building Curtin Institutional Repository
collection Online Access
description Here we report a facile annealing process for homogeneous deposition of Co3O4 quantum dots (Co3O4 QDs) onto porous g-C3N4 nanosheets. It was discovered that pores were catalytically produced around Co3O4 QDs. In the synthesis, annealing temperature was found to be crucial for the textural property, optical absorption, and the corresponding photocatalytic water oxidation as well as photochemical performances. The highest specific surface area, pore volume and optimal O2 production rate as well as the highest photocurrent were obtained on 0.8wt.% Co3O4 QDs decorated g-C3N4 nanosheets annealed at 300°C (0.8% Co3O4-C3N4-300). These results underline the importance of surface heterojunction and afford us a feasible protocol for rational design of g-C3N4 based photocatalysts for water oxidation.
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institution Curtin University Malaysia
institution_category Local University
last_indexed 2025-11-14T09:53:19Z
publishDate 2016
publisher Elsevier BV
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spelling curtin-20.500.11937-528472022-10-26T07:04:10Z Monodisperse Co3O4 quantum dots on porous carbon nitride nanosheets for enhanced visible-light-driven water oxidation Zhang, H. Tian, W. Zhou, L. Sun, Hongqi Tade, Moses Wang, Shaobin Here we report a facile annealing process for homogeneous deposition of Co3O4 quantum dots (Co3O4 QDs) onto porous g-C3N4 nanosheets. It was discovered that pores were catalytically produced around Co3O4 QDs. In the synthesis, annealing temperature was found to be crucial for the textural property, optical absorption, and the corresponding photocatalytic water oxidation as well as photochemical performances. The highest specific surface area, pore volume and optimal O2 production rate as well as the highest photocurrent were obtained on 0.8wt.% Co3O4 QDs decorated g-C3N4 nanosheets annealed at 300°C (0.8% Co3O4-C3N4-300). These results underline the importance of surface heterojunction and afford us a feasible protocol for rational design of g-C3N4 based photocatalysts for water oxidation. 2016 Journal Article http://hdl.handle.net/20.500.11937/52847 10.1016/j.apcatb.2017.03.028 http://purl.org/au-research/grants/arc/DP150103026 Elsevier BV restricted
spellingShingle Zhang, H.
Tian, W.
Zhou, L.
Sun, Hongqi
Tade, Moses
Wang, Shaobin
Monodisperse Co3O4 quantum dots on porous carbon nitride nanosheets for enhanced visible-light-driven water oxidation
title Monodisperse Co3O4 quantum dots on porous carbon nitride nanosheets for enhanced visible-light-driven water oxidation
title_full Monodisperse Co3O4 quantum dots on porous carbon nitride nanosheets for enhanced visible-light-driven water oxidation
title_fullStr Monodisperse Co3O4 quantum dots on porous carbon nitride nanosheets for enhanced visible-light-driven water oxidation
title_full_unstemmed Monodisperse Co3O4 quantum dots on porous carbon nitride nanosheets for enhanced visible-light-driven water oxidation
title_short Monodisperse Co3O4 quantum dots on porous carbon nitride nanosheets for enhanced visible-light-driven water oxidation
title_sort monodisperse co3o4 quantum dots on porous carbon nitride nanosheets for enhanced visible-light-driven water oxidation
url http://purl.org/au-research/grants/arc/DP150103026
http://hdl.handle.net/20.500.11937/52847