Chitosan extraction from lobster shells and its grafted with functionalized MWCNT for simultaneous removal of Pb(2+) ions and eriochrome cyanine R dye after their complexation.

Chitosan (CS) extracted from lobster shells (Persian Gulf, Iran), was grafted with amino functionalized multiwalled carbon nanotube (MWCNT). This novel material was characterized by FE-SEM and FT-IR and used for the ultrasound-assisted removal of Pb(2+) ions and eriochrome cyanine R (ECR) dye. A cen...

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Main Authors: Kheirandish, S., Ghaedi, M., Dashtian, K., Heidari, F., Pourebrahim, F., Wang, Shaobin
Format: Journal Article
Published: Elsevier BV 2017
Online Access:http://hdl.handle.net/20.500.11937/52739
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author Kheirandish, S.
Ghaedi, M.
Dashtian, K.
Heidari, F.
Pourebrahim, F.
Wang, Shaobin
author_facet Kheirandish, S.
Ghaedi, M.
Dashtian, K.
Heidari, F.
Pourebrahim, F.
Wang, Shaobin
author_sort Kheirandish, S.
building Curtin Institutional Repository
collection Online Access
description Chitosan (CS) extracted from lobster shells (Persian Gulf, Iran), was grafted with amino functionalized multiwalled carbon nanotube (MWCNT). This novel material was characterized by FE-SEM and FT-IR and used for the ultrasound-assisted removal of Pb(2+) ions and eriochrome cyanine R (ECR) dye. A central composite design (SCCD) under response surface methodology was used for studying the influences of important variables in removal process such as initial ECR and Pb(2+) ions concentrations, adsorbent mass and sonication time on the removal efficiency. Linear, 2FI, quadratic and cubic models were performed and a quadratic model was selected for analysis of each response. ANOVA for the quadratic model shows the F-value parameter (820.44 and 537.12 for ECR and Pb(2+) ions removal, respectively) and very low p-value (<0.0001), implying that the model was highly significant for understudy analytes adsorption. To achieve maximum removal, the optimum condition was determined and were set as:19.34 and 18.20mgL(-1),0.018g and 9.35min for initial ECR and Pb(2+) ion concentrations, adsorbent mass and sonication time, respectively. At these optimum conditions, 97.06% of ECR and 99.29% of Pb(2+) ions were removed in a short time.
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institution Curtin University Malaysia
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publishDate 2017
publisher Elsevier BV
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spelling curtin-20.500.11937-527392017-09-13T15:38:23Z Chitosan extraction from lobster shells and its grafted with functionalized MWCNT for simultaneous removal of Pb(2+) ions and eriochrome cyanine R dye after their complexation. Kheirandish, S. Ghaedi, M. Dashtian, K. Heidari, F. Pourebrahim, F. Wang, Shaobin Chitosan (CS) extracted from lobster shells (Persian Gulf, Iran), was grafted with amino functionalized multiwalled carbon nanotube (MWCNT). This novel material was characterized by FE-SEM and FT-IR and used for the ultrasound-assisted removal of Pb(2+) ions and eriochrome cyanine R (ECR) dye. A central composite design (SCCD) under response surface methodology was used for studying the influences of important variables in removal process such as initial ECR and Pb(2+) ions concentrations, adsorbent mass and sonication time on the removal efficiency. Linear, 2FI, quadratic and cubic models were performed and a quadratic model was selected for analysis of each response. ANOVA for the quadratic model shows the F-value parameter (820.44 and 537.12 for ECR and Pb(2+) ions removal, respectively) and very low p-value (<0.0001), implying that the model was highly significant for understudy analytes adsorption. To achieve maximum removal, the optimum condition was determined and were set as:19.34 and 18.20mgL(-1),0.018g and 9.35min for initial ECR and Pb(2+) ion concentrations, adsorbent mass and sonication time, respectively. At these optimum conditions, 97.06% of ECR and 99.29% of Pb(2+) ions were removed in a short time. 2017 Journal Article http://hdl.handle.net/20.500.11937/52739 10.1016/j.ijbiomac.2017.03.035 Elsevier BV restricted
spellingShingle Kheirandish, S.
Ghaedi, M.
Dashtian, K.
Heidari, F.
Pourebrahim, F.
Wang, Shaobin
Chitosan extraction from lobster shells and its grafted with functionalized MWCNT for simultaneous removal of Pb(2+) ions and eriochrome cyanine R dye after their complexation.
title Chitosan extraction from lobster shells and its grafted with functionalized MWCNT for simultaneous removal of Pb(2+) ions and eriochrome cyanine R dye after their complexation.
title_full Chitosan extraction from lobster shells and its grafted with functionalized MWCNT for simultaneous removal of Pb(2+) ions and eriochrome cyanine R dye after their complexation.
title_fullStr Chitosan extraction from lobster shells and its grafted with functionalized MWCNT for simultaneous removal of Pb(2+) ions and eriochrome cyanine R dye after their complexation.
title_full_unstemmed Chitosan extraction from lobster shells and its grafted with functionalized MWCNT for simultaneous removal of Pb(2+) ions and eriochrome cyanine R dye after their complexation.
title_short Chitosan extraction from lobster shells and its grafted with functionalized MWCNT for simultaneous removal of Pb(2+) ions and eriochrome cyanine R dye after their complexation.
title_sort chitosan extraction from lobster shells and its grafted with functionalized mwcnt for simultaneous removal of pb(2+) ions and eriochrome cyanine r dye after their complexation.
url http://hdl.handle.net/20.500.11937/52739