Thermal Conversion of Core-Shell Metal-Organic Frameworks: A New Method for Selectively Functionalized Nanoporous Hybrid Carbon
Core–shell structured ZIF-8@ZIF-67 crystals are well-designed and prepared through a seed-mediated growth method. After thermal treatment of ZIF-8@ZIF-67 crystals, we obtain selectively functionalized nanoporous hybrid carbon materials consisting of nitrogen-doped carbon (NC) as the cores and highly...
| Main Authors: | , , , , , , |
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| Format: | Journal Article |
| Published: |
American Chemical Society
2015
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| Online Access: | http://hdl.handle.net/20.500.11937/5223 |
| _version_ | 1848744735959678976 |
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| author | Tang, J. Salunkhe, R. Liu, Jian Torad, N. Imura, M. Furukawa, S. Yamauchi, Y. |
| author_facet | Tang, J. Salunkhe, R. Liu, Jian Torad, N. Imura, M. Furukawa, S. Yamauchi, Y. |
| author_sort | Tang, J. |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | Core–shell structured ZIF-8@ZIF-67 crystals are well-designed and prepared through a seed-mediated growth method. After thermal treatment of ZIF-8@ZIF-67 crystals, we obtain selectively functionalized nanoporous hybrid carbon materials consisting of nitrogen-doped carbon (NC) as the cores and highly graphitic carbon (GC) as the shells. This is the first example of the integration of NC and GC in one particle at the nanometer level. Electrochemical data strongly demonstrate that this nanoporous hybrid carbon material integrates the advantageous properties of the individual NC and GC, exhibiting a distinguished specific capacitance (270 F·g–1) calculated from the galvanostatic charge–discharge curves at a current density of 2 A·g–1. Our study not only bridges diverse carbon-based materials with infinite metal–organic frameworks but also opens a new avenue for artificially designed nanoarchitectures with target functionalities. |
| first_indexed | 2025-11-14T06:06:12Z |
| format | Journal Article |
| id | curtin-20.500.11937-5223 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T06:06:12Z |
| publishDate | 2015 |
| publisher | American Chemical Society |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-52232017-09-13T14:45:48Z Thermal Conversion of Core-Shell Metal-Organic Frameworks: A New Method for Selectively Functionalized Nanoporous Hybrid Carbon Tang, J. Salunkhe, R. Liu, Jian Torad, N. Imura, M. Furukawa, S. Yamauchi, Y. Core–shell structured ZIF-8@ZIF-67 crystals are well-designed and prepared through a seed-mediated growth method. After thermal treatment of ZIF-8@ZIF-67 crystals, we obtain selectively functionalized nanoporous hybrid carbon materials consisting of nitrogen-doped carbon (NC) as the cores and highly graphitic carbon (GC) as the shells. This is the first example of the integration of NC and GC in one particle at the nanometer level. Electrochemical data strongly demonstrate that this nanoporous hybrid carbon material integrates the advantageous properties of the individual NC and GC, exhibiting a distinguished specific capacitance (270 F·g–1) calculated from the galvanostatic charge–discharge curves at a current density of 2 A·g–1. Our study not only bridges diverse carbon-based materials with infinite metal–organic frameworks but also opens a new avenue for artificially designed nanoarchitectures with target functionalities. 2015 Journal Article http://hdl.handle.net/20.500.11937/5223 10.1021/ja511539a American Chemical Society restricted |
| spellingShingle | Tang, J. Salunkhe, R. Liu, Jian Torad, N. Imura, M. Furukawa, S. Yamauchi, Y. Thermal Conversion of Core-Shell Metal-Organic Frameworks: A New Method for Selectively Functionalized Nanoporous Hybrid Carbon |
| title | Thermal Conversion of Core-Shell Metal-Organic Frameworks: A New Method for Selectively Functionalized Nanoporous Hybrid Carbon |
| title_full | Thermal Conversion of Core-Shell Metal-Organic Frameworks: A New Method for Selectively Functionalized Nanoporous Hybrid Carbon |
| title_fullStr | Thermal Conversion of Core-Shell Metal-Organic Frameworks: A New Method for Selectively Functionalized Nanoporous Hybrid Carbon |
| title_full_unstemmed | Thermal Conversion of Core-Shell Metal-Organic Frameworks: A New Method for Selectively Functionalized Nanoporous Hybrid Carbon |
| title_short | Thermal Conversion of Core-Shell Metal-Organic Frameworks: A New Method for Selectively Functionalized Nanoporous Hybrid Carbon |
| title_sort | thermal conversion of core-shell metal-organic frameworks: a new method for selectively functionalized nanoporous hybrid carbon |
| url | http://hdl.handle.net/20.500.11937/5223 |