Coupled Thermodynamic and Kinetic Changes in the Electrochemistry of Ferrocenyl Monolayers Induced by Light

QR Code

Coupled Thermodynamic and Kinetic Changes in the Electrochemistry of Ferrocenyl Monolayers Induced by Light

© 2017 American Chemical Society.We report on the light-induced systematic changes to the thermodynamics and kinetics of ferrocene units attached to a n-type silicon(100) photoelectrode. Both the reaction rate and the energetics of the charge transfer are simultaneously affected by changes in the in...

Full description

Bibliographic Details
Main Authors:	Yang, Y., Ciampi, Simone, Gooding, J.
Format:	Journal Article
Published:	American Chemical Society 2017
Online Access:	http://purl.org/au-research/grants/arc/DE160100732 http://hdl.handle.net/20.500.11937/51876

Similar Items

Forming Ferrocenyl Self-Assembled Monolayers on Si(100) Electrodes with Different Alkyl Chain Lengths for Electron Transfer Studies
by: Ahmad, S., et al.
Published: (2019)

Forming ferrocenyl self‐assembled monolayers on Si(100) electrodes with different alkyl chain lengths for electron transfer studies
by: A. Ahmad, Shahrul A., et al.
Published: (2019)

Light Activated Electrochemistry: Light Intensity and pH Dependence on Electrochemical Performance of Anthraquinone Derivatized Silicon
by: Yang, Y., et al.
Published: (2016)

Light-activated electrochemistry without surface-bound redox species
by: Kashi, M., et al.
Published: (2017)

Light-Activated Electrochemistry for the Two-Dimensional Interrogation of Electroactive Regions on a Monolithic Surface with Dramatically Improved Spatial Resolution
by: Yang, Y., et al.
Published: (2016)

Direct electrochemistry of cytochrome c at modified Si(100) electrodes
by: Ciampi, Simone, et al.
Published: (2010)

Light-addressable electrochemistry at semiconductor electrodes: Redox imaging, mask-free lithography and spatially resolved chemical and biological sensing
by: Vogel, Yan, et al.
Published: (2019)

Light-activated electrochemistry on alkyne-terminated Si(100) surfaces towards solution-based redox probes
by: Wu, Y., et al.
Published: (2016)

Reversible potential-induced structural changes of alkanethiol monolayers on gold surfaces
by: Darwish, Nadim, et al.
Published: (2011)

The molecular level modification of surfaces: From self-assembled monolayers to complex molecular assemblies
by: Gooding, J., et al.
Published: (2011)

Organic Monolayers on Si(211) for Triboelectricity Generation: Etching Optimization and Relationship between the Electrochemistry and Current Output
by: Hurtado, Carlos, et al.
Published: (2022)

Facet-resolved electrochemistry of monolayer-modified silicon crystals
by: Zhang, Song
Published: (2022)

Tandem "click" reactions at acetylene-terminated Si(100) monolayers
by: Ciampi, Simone, et al.
Published: (2011)

Nanoscale water condensation on click-functionalized self-assembled monolayers
by: James, M., et al.
Published: (2011)

The impact of surface coverage on the kinetics of electron transfer through redox monolayers on a silicon electrode surface
by: Ciampi, S., et al.
Published: (2015)

The impact of surface coverage on the kinetics of electron transfer through redox monolayers on a silicon electrode surface
by: Ciampi, Simone, et al.
Published: (2015)

Nanoscale condensation of water on self-assembled monolayers
by: James, M., et al.
Published: (2011)

Wet chemical routes to the assembly of organic monolayers on silicon surfaces via the formation of Si-C bonds: Surface preparation, passivation and functionalization
by: Ciampi, Simone, et al.
Published: (2010)

Bubbles pinned on electrodes: Friends or foes of aqueous electrochemistry?
by: Ciampi, Simone, et al.
Published: (2022)

Redox-active monolayers in mesoporous silicon
by: Ciampi, S., et al.
Published: (2012)

Antifouling behaviour of silicon surfaces modified with self-assembled monolayers containing both ethylene glycol and charged moieties
by: Ng, C., et al.
Published: (2010)

Facet-resolved electrochemistry: From single particles to macroscopic crystals
by: Zhang, Song, et al.
Published: (2022)

Quantitative Analysis of Cyclic Voltammetry of Redox Monolayers Adsorbed on Semiconductors: Isolating Electrode Kinetics, Lateral Interactions, and Diode Currents
by: Vogel, Yan, et al.
Published: (2019)

Reproducible flaws unveil electrostatic aspects of semiconductor electrochemistry
by: Vogel, Y., et al.
Published: (2017)

Nanoscale Silicon Oxide Reduces Electron Transfer Kinetics of Surface-Bound Ferrocene Monolayers on Silicon
by: Li, Tiexin, et al.
Published: (2021)

Preparation of thiol-terminated monolayers on silicon(100) surfaces using thioacetyl-protected alkynethiol
by: Ng, C., et al.
Published: (2010)

JIK 220 - KINETIC AND ELECTROCHEMISTRY APRIL 08
by: PPJJ, Pusat Pengajian Jarak Jauh
Published: (2008)

Electrostatics and Electrochemistry: Mechanism and Scope of Charge-Transfer Reactions on the Surface of Tribocharged Insulators
by: Zhang, J., et al.
Published: (2021)

The rapid formation of functional monolayers on silicon under mild conditions
by: Ciampi, S., et al.
Published: (2014)

Heterojunctions Based on Amorphous Silicon: A Versatile Surface Engineering Strategy to Tune Peak Position of Redox Monolayers on Photoelectrodes
by: Gonçales, V.R., et al.
Published: (2020)

Hydrogen bonding and covalent coupling in adsorbed molecular monolayers
by: Garfitt, Jason Michael
Published: (2014)

Effect of Electric Fields on Silicon-Based Monolayers
by: Li, Tiexin, et al.
Published: (2022)

The rise of self-assembled monolayers for fabricating electrochemical biosensors-an interfacial perspective
by: Gooding, J., et al.
Published: (2012)

Studies on the effect of solvents on self-assembled monolayers formed from organophosphonic acids on indium tin oxide
by: Chen, X., et al.
Published: (2012)

DNA-hybridisation detection on Si(100) surfaces using lightactivated electrochemistry: a comparative study between bovine serum albumin and hexaethylene glycol as antifouling layers
by: Zarei, L., et al.
Published: (2018)

Electrochemistry on Tribocharged Polymers Is Governed by the Stability of Surface Charges Rather than Charging Magnitude
by: Zhang, Jinyang, et al.
Published: (2019)

TEMPO Monolayers on Si(100) Electrodes: Electrostatic Effects by the Electrolyte and Semiconductor Space-Charge on the Electroactivity of a Persistent Radical.
by: Zhang, L., et al.
Published: (2016)

Connecting electrodes with light: One wire, many electrodes
by: Choudhury, M., et al.
Published: (2015)

Direct-current output of silicon–organic monolayer–platinum Schottky TENGs: Elusive friction-output relationship
by: Lyu, Xin, et al.
Published: (2023)

Surface-bound norbornylogous bridges as molecular rulers for investigating interfacial electrochemistry and as single molecule switches
by: Darwish, Nadim, et al.
Published: (2014)