Convergent Close-Coupling Approach to Electron-Atom Collisions

The convergent close-coupling (CCC) method was developed in order to resolve the long-standing discrepancy between two consistent experiments and all available theories for 2p excitation of atomic hydrogen [1] . The method was unable to resolve this discrepancy, but subsequent experiments [2,3] foun...

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Main Authors: Bray, Igor, Stelbovics, Andris
Format: Book Chapter
Published: 2013
Online Access:http://hdl.handle.net/20.500.11937/51521
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author Bray, Igor
Stelbovics, Andris
author_facet Bray, Igor
Stelbovics, Andris
author_sort Bray, Igor
building Curtin Institutional Repository
collection Online Access
description The convergent close-coupling (CCC) method was developed in order to resolve the long-standing discrepancy between two consistent experiments and all available theories for 2p excitation of atomic hydrogen [1] . The method was unable to resolve this discrepancy, but subsequent experiments [2,3] found much more in favor of theory than the previous experiments. There have been a number of reviews of the applications of the CCC theory with the most recent one being by Bray et al. [4] . The method has been extended to ionization [5], resulting in some controversy [6,7] that required further explanation [8,9]. Our own confidence in the ability of the CCC method to reproduce electron— hydrogen fully differential ionization cross sections was shaken by the less than satisfactory agreement with experiment [10] . However, this turned out to be primarily due to insufficient computational resources available at the time [11]. Consequently, we are now confident that the CCC method is able to solve the e—H, γ—He, and e—He (within the frozen-core model) collision systems at all energies with one or two outgoing electrons. We shall attempt to explain here the underlying foundations as clearly as possible. The example of the S-wave model will be used to demonstrate the method. A published program is available that shows the workings of the method discussed here [12] . We will finish by concentrating on the application of the method to fully differential ionization processes.
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spelling curtin-20.500.11937-515212018-03-29T09:08:38Z Convergent Close-Coupling Approach to Electron-Atom Collisions Bray, Igor Stelbovics, Andris The convergent close-coupling (CCC) method was developed in order to resolve the long-standing discrepancy between two consistent experiments and all available theories for 2p excitation of atomic hydrogen [1] . The method was unable to resolve this discrepancy, but subsequent experiments [2,3] found much more in favor of theory than the previous experiments. There have been a number of reviews of the applications of the CCC theory with the most recent one being by Bray et al. [4] . The method has been extended to ionization [5], resulting in some controversy [6,7] that required further explanation [8,9]. Our own confidence in the ability of the CCC method to reproduce electron— hydrogen fully differential ionization cross sections was shaken by the less than satisfactory agreement with experiment [10] . However, this turned out to be primarily due to insufficient computational resources available at the time [11]. Consequently, we are now confident that the CCC method is able to solve the e—H, γ—He, and e—He (within the frozen-core model) collision systems at all energies with one or two outgoing electrons. We shall attempt to explain here the underlying foundations as clearly as possible. The example of the S-wave model will be used to demonstrate the method. A published program is available that shows the workings of the method discussed here [12] . We will finish by concentrating on the application of the method to fully differential ionization processes. 2013 Book Chapter http://hdl.handle.net/20.500.11937/51521 10.1007/978-3-662-08492-2_7 restricted
spellingShingle Bray, Igor
Stelbovics, Andris
Convergent Close-Coupling Approach to Electron-Atom Collisions
title Convergent Close-Coupling Approach to Electron-Atom Collisions
title_full Convergent Close-Coupling Approach to Electron-Atom Collisions
title_fullStr Convergent Close-Coupling Approach to Electron-Atom Collisions
title_full_unstemmed Convergent Close-Coupling Approach to Electron-Atom Collisions
title_short Convergent Close-Coupling Approach to Electron-Atom Collisions
title_sort convergent close-coupling approach to electron-atom collisions
url http://hdl.handle.net/20.500.11937/51521