Recent Progress in Metal-Organic Frameworks for Applications in Electrocatalytic and Photocatalytic Water Splitting

The development of clean and renewable energy materials as alternatives to fossil fuels is foreseen as a potential solution to the crucial problems of environmental pollution and energy shortages. Hydrogen is an ideal energy material for the future, and water splitting using solar/electrical energy...

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Main Authors: Wang, W., Xu, X., Zhou, W., Shao, Zongping
Format: Journal Article
Published: WILEY-BLACKWELL 2017
Online Access:http://purl.org/au-research/grants/arc/DP150104365
http://hdl.handle.net/20.500.11937/51069
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author Wang, W.
Xu, X.
Zhou, W.
Shao, Zongping
author_facet Wang, W.
Xu, X.
Zhou, W.
Shao, Zongping
author_sort Wang, W.
building Curtin Institutional Repository
collection Online Access
description The development of clean and renewable energy materials as alternatives to fossil fuels is foreseen as a potential solution to the crucial problems of environmental pollution and energy shortages. Hydrogen is an ideal energy material for the future, and water splitting using solar/electrical energy is one way to generate hydrogen. Metal-organic frameworks (MOFs) are a class of porous materials with unique properties that have received rapidly growing attention in recent years for applications in water splitting due to their remarkable design flexibility, ultra-large surface-to-volume ratios and tunable pore channels. This review focuses on recent progress in the application of MOFs in electrocatalytic and photocatalytic water splitting for hydrogen generation, including both oxygen and hydrogen evolution. It starts with the fundamentals of electrocatalytic and photocatalytic water splitting and the related factors to determine the catalytic activity. The recent progress in the exploitation of MOFs for water splitting is then summarized, and strategies for designing MOF-based catalysts for electrocatalytic and photocatalytic water splitting are presented. Finally, major challenges in the field of water splitting are highlighted, and some perspectives of MOF-based catalysts for water splitting are proposed.
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institution Curtin University Malaysia
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spelling curtin-20.500.11937-510692022-10-26T08:00:43Z Recent Progress in Metal-Organic Frameworks for Applications in Electrocatalytic and Photocatalytic Water Splitting Wang, W. Xu, X. Zhou, W. Shao, Zongping The development of clean and renewable energy materials as alternatives to fossil fuels is foreseen as a potential solution to the crucial problems of environmental pollution and energy shortages. Hydrogen is an ideal energy material for the future, and water splitting using solar/electrical energy is one way to generate hydrogen. Metal-organic frameworks (MOFs) are a class of porous materials with unique properties that have received rapidly growing attention in recent years for applications in water splitting due to their remarkable design flexibility, ultra-large surface-to-volume ratios and tunable pore channels. This review focuses on recent progress in the application of MOFs in electrocatalytic and photocatalytic water splitting for hydrogen generation, including both oxygen and hydrogen evolution. It starts with the fundamentals of electrocatalytic and photocatalytic water splitting and the related factors to determine the catalytic activity. The recent progress in the exploitation of MOFs for water splitting is then summarized, and strategies for designing MOF-based catalysts for electrocatalytic and photocatalytic water splitting are presented. Finally, major challenges in the field of water splitting are highlighted, and some perspectives of MOF-based catalysts for water splitting are proposed. 2017 Journal Article http://hdl.handle.net/20.500.11937/51069 10.1002/advs.201600371 http://purl.org/au-research/grants/arc/DP150104365 http://purl.org/au-research/grants/arc/DP160104835 http://creativecommons.org/licenses/by/4.0/ WILEY-BLACKWELL fulltext
spellingShingle Wang, W.
Xu, X.
Zhou, W.
Shao, Zongping
Recent Progress in Metal-Organic Frameworks for Applications in Electrocatalytic and Photocatalytic Water Splitting
title Recent Progress in Metal-Organic Frameworks for Applications in Electrocatalytic and Photocatalytic Water Splitting
title_full Recent Progress in Metal-Organic Frameworks for Applications in Electrocatalytic and Photocatalytic Water Splitting
title_fullStr Recent Progress in Metal-Organic Frameworks for Applications in Electrocatalytic and Photocatalytic Water Splitting
title_full_unstemmed Recent Progress in Metal-Organic Frameworks for Applications in Electrocatalytic and Photocatalytic Water Splitting
title_short Recent Progress in Metal-Organic Frameworks for Applications in Electrocatalytic and Photocatalytic Water Splitting
title_sort recent progress in metal-organic frameworks for applications in electrocatalytic and photocatalytic water splitting
url http://purl.org/au-research/grants/arc/DP150104365
http://purl.org/au-research/grants/arc/DP150104365
http://hdl.handle.net/20.500.11937/51069